Decakis(dichloromethyl)-1,12-dicarba-closo-dodecaborane(12): Camouflage of an Icosahedral carborane by using bulky functional substituents

Angewandte Chemie (International Edition in English)

Volumn 35, Issue 21, 1996, Pages 2536-2537

  Jiang, Wei ^a   Knobler, Carolyn B ^a   Hawthorne, M Frederick ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

Carboranes; Chlorinations; Radical reactions

Indexed keywords

EID: 0030445496     PISSN: 05700833     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.199625361     Document Type: Article

References (13)

1. a) V. I. Bregadze, Chem. Rev. 1992, 92, 209-223;
2. b) V. V. Grushin, V. I. Bregadze, V. N. Kalinin, J. Organomet. Chem. Lib. 1988, 20, 1-68, and references therein.
3. R. N. Grimes, Carborancs, Academic Press, New York, 1970, pp. 54-180, and references therein.
4. J. Plešek, Z. Plzák, J. Stuchlik, S. Heřmánek, Coll. Czech. Chem. Commun. 1981, 46, 1748-1763.
5. R. R. Srivastava, D. S. Wilbur, Abstracts of Papers, 208th National Meeting of the American Chemical Society, American Chemical Society, Washington D. C., 1994, p. 208.
6. W. Jiang, C. B. Knobler, M. D. Mortimer, M. F. Hawthorne, Angew: Chem. 1995, 107, 1470-1473; Angew: Chem. Int. Ed. Engl. 1995, 34, 1332-1334.
7. W. Jiang, C. B. Knobler, M. D. Mortimer, M. F. Hawthorne, Angew: Chem. 1995, 107, 1470-1473; Angew: Chem. Int. Ed. Engl. 1995, 34, 1332-1334.
8. a) A. D. N. Vaz, G. Schoellmann, J. Org. Chem. 1984, 49, 1286;
9. b) R. S. Neale, R. G. Schepers, M. R. Walsh, ibid. 1964, 29, 3390;
10. c) K. Ohkata, Y. Ohyama, K. Akiba, Heterocycles 1994, 37, 859.
11. L. I. Zakharkin, V. I. Stanko, A. I. Klimova, Izv. Akad. Nauk SSSR Ser. Khim. 1964, 771.
12. w = 0.062. The largest peak on a final difference electron density map was 0.57 eÅ3. Crystallographic data (excluding structure factors) for the structure reported in this paper have been deposited with the Cambridge Crystallographic Data Centre as supplementary publication no. CCDC-179-104. Copies of the data can be obtained free of charge on application to The Director, CCDC, 12 Union Road, Cambridge CB2 1EZ, UK (fax: Int. code +(1223) 336-033; e-mail: teched@chemcrys.cam.ac.uk).
13. W. Jiang, C. B. Knobler, C. E. Curtis, M. D. Mortimer, M. F. Hawthorne, Inorg. Chem. 1995, 34, 3491.