A unique NiII complex with three different azido bridges: Magneto-structural correlations in the first triply alternating S = 1 chain

Angewandte Chemie (International Edition in English)

Volumn 35, Issue 21, 1996, Pages 2520-2522

  Ribas, Joan ^a   Monfort, Montserrat ^a   Resino, Immaculada ^a   Solans, Xavier ^a   Rabu, Pierre ^b   Maingot, Fabrice ^b   Drillon, Marc ^b  

^a UNIVERSITY OF BARCELONA   (Spain)

^b INSTITUT DE PHYSIQUE ET CHIMIE DES MATÉRIAUX DE STRASBOURG   (France)

Author keywords

Azides; Complexes with nitrogen ligands; Magnetic properties; Nickel compounds

Indexed keywords

EID: 0030445495     PISSN: 05700833     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.199625201     Document Type: Article

References (41)

1. a) F. Wagner, M. T. Mocella, M. J. D'Aniello, A. H. J. Wang, E. K. Barefield, J. Am. Chem. Soc. 1974, 96, 2625;
2. b) C. G. Pierpont, D. N. Hendrickson, D. M. Duggan, F. Wagner, E. K. Barfield, Inorg. Chem. 1975, 14, 604;
3. c) P. Chaudhuri, M. Guttmann, D. Ventur, K. Wieghardt, B. Nuber, J. Weiss, J. Chem. Soc. Chem. Commun. 1985, 1618;
4. d) M. I. Arriortua, R. Cortés, L. Lezama, T. Rojo, X. Solans, M. Font-Bardia, Inorg. Chim. Acta 1990, 174, 263;
5. e) R. Cortés, J. I. Ruiz de Larramendi, L. Lezama, T. Rojo, K. Urtiaga, M. I. Arriortua, J. Chem. Soc. Dalton Trans. 1992, 2723;
6. f) P. D. Beer, M. G. B. Drew, P. B. Lesson, K. Lyssenko, M. I. Ogden, J. Chem. Soc. Chem. Commun. 1995, 929;
7. g) M. A. Halcrow, J. S. Sun, J. C. Huffman, G. Christou, Inorg. Chem. 1995, 34, 4167.
8. J. Ribas, M. Monfort, C. Diaz, C. Bastos, X. Solans, Inorg. Chem. 1993, 32, 3557.
9. a) R. Vicente, A. Escuer, J. Ribas, X. Solans, Inorg. Chem. 1992, 31, 1726;
10. b) A. Escuer, R. Vicente, J. Ribas, M. S. El Fallah, X. Solans, ibid. 1993, 32, 1013;
11. e) A. Escuer, R. Vicente, J. Ribas, M. S. El Fallah, X. Solans, M. Font-Bardia, ibid. 1993, 32, 3727;
12. d) A. Escuer, R. Vicente, J. Ribas, M. S. El Fallah, X. Solans, M. Font-Bardía, ibid. 1994, 33, 1842;
13. e) J. Ribas, M. Monfort, C. Diaz, C. Bastos, C. Mer, X. Solans, ibid. 1995, 34, 4986;
14. f) A. Escuer, R. Vicente, M. S. El Fallah, J. Ribas, X. Solans, M. Font-Bardía, J. Chem. Soc. Dalton Trans. 1993, 2975.
15. a) R. Vicente, A. Escuer, J. Ribas, M. S. El Fallah, X. Solans, M. Font-Bardía, Inorg. Chem. 1993, 32, 1920;
16. b) A. Escuer, R. Vicente, J. Ribas, X. Solans, ibid. 1995, 34, 1793;
17. c) J. Ribas, M. Monfort, C. Diaz, C. Bastos, X. Solans, ibid. 1994, 33, 484;
18. d) J. Ribas, M. Monfort, R. Costa, X. Solans, ibid. 1993, 32, 695.
19. a) M. Monfort, J. Ribas, X. Solans, J. Chem. Soc. Chem. Commun. 1993, 350;
20. b) J. Ribas, M. Monfort, X. Solans, M. Drillon, Inorg. Chem. 1994, 33, 742.
21. J. Ribas, M. Monfort, B. K. Ghosh, X. Solans, Angew. Chem. 1994, 106, 2177; Angew. Chem. Int. Ed. Engl. 1994, 33, 2087.
22. J. Ribas, M. Monfort, B. K. Ghosh, X. Solans, Angew. Chem. 1994, 106, 2177; Angew. Chem. Int. Ed. Engl. 1994, 33, 2087.
23. J. Ribas, M. Monfort, B. K. Ghosh, X. Solans, M. Font-Bardia, J. Chem. Soc. Chem. Commun. 1995, 2375.
24. a) J. P. Costes, F. Dahan, J. Ruiz, J. P. Laurent, Inorg. Chim. Acta 1995, 239, 53 and references therein;
25. b) G. A. Albada, M. T. Lakin, N. Veldman, A. L. Spek, J. Reedijk, Inorg. Chem. 1995, 34, 4910.
26. a) R. Cortés, J. L. Pizarro, L. Lezama, M. I. Arriortua, T. Rojo, Inorg. Chem. 1994, 33, 2697;
27. b) R. Cortés, L. Lezama, J. L. Pizarro, M. I. Arriortua, X. Solans, T. Rojo, Angew. Chem. 1994, 106, 2520; Angew. Chem. Int. Ed. Engl. 1994, 33, 2488.
28. b) R. Cortés, L. Lezama, J. L. Pizarro, M. I. Arriortua, X. Solans, T. Rojo, Angew. Chem. 1994, 106, 2520; Angew. Chem. Int. Ed. Engl. 1994, 33, 2488.
29. B. R. Stults, R. S. Marianell, V. W. Day, Inorg. Chem. 1975, 14, 722;
30. b) A. K. Gregson, N. T. Moxon, ibid. 1982, 21, 586.
31. A. Bencini, C. A. Ghilardi, S. Midollini, A. Orlandini, Inorg. Chem. 1989, 28, 1958.
32. K. Pohl, K. Wieghardt, B. Nuber, J. Weiss, J. Chem. Soc. Dalton Trans. 1987, 187.
33. 2 = 0.1025 and S = 0.966. Crystallographic data (excluding structure factors) for the structure reported in this paper have been deposited with the Cambridge Crystallographic Data Centre as supplementary publication no. CCDC-179-97. Copies of the data can be obtained free of charge on application to The Director, CCDC, 12 Union Road, Cambridge CB2 1EZ, UK (fax: Int. code +(1223) 336-033; e-mail: teched@chemcrys.cam.ac.uk).
34. M. Drillon, R. Georges, J. Chem. Soc. Farad. Trans. 1974, 75, 810;
35. b) M. Drillon, R. Georges, Phys. Rer. B 1981, 24, 1278.
36. a) M. Drillon, J. C. Granduzzio, R. Georges, Phys. Rev. Lett. A 1983, 96, 41;
37. b) M. Drillon, E. Coronado, R. Georges, J. C. Granduzzio, J. Curely, Phys. Rev. B 1989, 40, 10992.
38. The fit was carried out by using the MINUIT function minimization program of the CERN program library (v.92.1), CERN, Geneva, Switzerland; the C98 vectorial computer of IDRIS, Orsay, France, was used for the fitting procedure involving up to 1107×1107 matrices.
39. R. L. Carlin, Magnetochemistry, Springer, Berlin, 1986, p. 67.
40. J. Commarmond, P. Plumeré, J. M. Lehn, Y. Agnus, R. Louis, R. Weiss, O. Kahn, I. Morgenstern-Badarau, J. Am. Chem. Soc. 1982, 104, 6330.
41. M. F. Charlot, O. Kahn, M. Chaillet, C. Larrieu, J. Am. Chem. Soc. 1986, 108, 2574.