Homogeneous catalysts for claus chemistry: The preparation and structure of cis-[(PPh3)2PtS3O], a catalytically active intermediate

Angewandte Chemie (International Edition in English)

Volumn 35, Issue 20, 1996, Pages 2362-2363

  Shaver, Alan ^a   El khateeb, Mohammad ^a   Lebuis, Anne Marie ^a  

^a MCGILL UNIVERSITY   (Canada)

Author keywords

Catalysis; Claus process; Complexes with sulfur ligands; Platinum compounds; Sulfur compounds

Indexed keywords

EID: 0030445093     PISSN: 05700833     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.199623621     Document Type: Article

References (21)

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10. 2 solvent is also disorded over two sites at 0.66 and 0.33 occupancies. All non-H atoms except S2a and the two solvent carbon atoms CS1 and CS2 were refined anisotropically, H-atoms were introduced in idealized positions. Final agreement factors: R = 0.040, Rw = 0.037 (418 parameters), S = 1.04. Crystallographic data (excluding structure factors) for the structure reported in this paper have been deposited with the Cambridge Crystallographic Data Centre as supplementary publication No. CCDC-179-94. Copies of the data can be obtained free of charge on application to the Director, CCDC, 12 Union Road, Cambridge CB2 1EZ, UK (fax: int. code +(1223)336-033; e-mail: techedfa chemcrys.cam.ac.uk).
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