Reaction kinetics of ozone at low concentrations with n-hexane soot

Journal of Geophysical Research Atmospheres

Volumn 101, Issue 14, 1996, Pages 19607-19620

  Smith, D M ^a   Chughtai, A R ^a  

^a UNIVERSITY OF DENVER   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

AEROSOL; BLACK CARBON; HEXANE; OZONE;

EID: 0030440306     PISSN: 01480227     EISSN: None     Source Type: Journal    
DOI: 10.1029/95jd03032     Document Type: Article

References (34)

1. 4, J. Phys. Chem., 88, 5334-5342, 1984.
2. Akhter, M. S., A. R. Chughtai, and D. M. Smith, The structure of hexane soot, I, Spectroscopic studies, Appl. Spectrosc., 39 (1), 143-153, 1985a.
3. Akhter, M. S., A. R. Chughtai, and D. M. Smith, The structure of hexane soot, II, Extraction studies, Appl. Spectrosc., 39 (1), 154-167, 1985b.
4. Akhter, M. S., A. R. Chughtai, and D. M. Smith, Spectroscopic studies of oxidized soots, Appl. Spectrosc., 45(4), 653-665, 1991.
5. Benson, S. W., and A. E. Axworthy, Mechanism of gas phase thermal decomposition of ozone, J. Chem. Phys., 26, 1718-1726, 1957.
6. Cass, G. R., P. M. Boone, and E. S. Macias, Emission and air quality relationships for atmospheric carbon participates in Los Angeles, in Particulate Carbon: Atmospheric Life Cycle, edited by G. T. Wolff and R. L. Klimisch, pp. 207-243, Plenum, New York, 1982.
7. Chughtai, A. R., and D. M. Smith, Long optical path cell for photochemical kinetics in heterogeneous systems of low concentration, Appl. Spectrosc., 45 (7), 1204-1207, 1991.
8. Chughtai, A. R., J. E. Peterson, J. A. Jassim, D. H. Stedman, and D. M. Smith, Spectroscopic and solubility characteristics of oxidized soots, Aerosol Sci. Technol., 15 (2), 112-126, 1991.
9. 4 at low concentration, Carbon, 32, 405-416, 1994.
10. Criegee, R., Products of ozonation of some olefins, in Ozone Chemistry and Technology, Adv. Chem. Ser. 21, pp. 133-135, Am. Chem. Soc., Washington, D. C., 1959.
11. Cuddihy, R. G., W. C. Griffith, and R. O. McClellan, Health risks from light duty diesel vehicles, Environ. Sci. Technol., 18, 14A-21A, 1984.
12. Dietz, V. R., and J. L. Bitner, The reaction of ozone with adsorbent charcoal, Carbon, 10, 145-154, 1972.
13. Dietz, V. R., and J. L. Bitner, Interaction of ozone with adsorbent charcoal, Carbon, 11, 393-401, 1973.
14. Goldberg, E. D., Black Carbon in the Environment, p.18, Wiley-Interecience, New York, 1985.
15. Griffin, J. J., and E. D. Goldberg, Impact of fossil fuel combustion on sediments of Lake Michigan: A reprise, Environ. Sci. Technol., 17, 244-245, 1983.
16. Hansen, A. D. A., and H. Rosen, Vertical distribution of particulate carbon, sulfur, and bromine in the Arctic haze and comparison with ground level measurements at Barrow, Alaska, Geophys. Res. Lett., 11, 381-384, 1984.
17. Hayward, D. O., and B. M. W. Trapnell, Chemisorption, p.93, Butterworths, London, 1964.
18. Kinney, C. R., and L. D. Friedman, Ozonation studies of coal constitution, J. Am. Chem. Soc., 74, 57-59, 1952.
19. Lynch, R. T., A. R. Chughtai, and D. M. Smith, Computer upgrade in older FT-IR spectrometer systems, Am. Lab. ,Shelton, CT, in press, 1995.
20. Muhlbaier, J. L., and R. L. Williams, Fireplaces, furnaces and vehicles as emission sources of particulate carbon, in Particulate Carbon: Atmospheric Life Cycle, edited by G. T. Wolff and R. L. Klimisch, pp. 185-205, Plenum, New York, 1982.
21. Novakov, T., The role of soot and primary oxidants in atmo spheric chemistry, Sci. Total Environ., 36, 1-10, 1984.
22. Papirer, E., J. B. Donnet, and A. Schutz, Etude cinetique de l'oxidation des noirs carbone par l'ozone, Carbon, 5, 113, 1967.
23. Penner, J. E., H. Eddleman, and T. Novakov, Toward the development of a global inventory for black carbon emission, Atmos. Environ., Part A, 27, 1277-1295, 1993.
24. Puri, B. P., and V. M. Arora, Interaction of carbons with dry ozonized oxygen, Indian J. Chem., 16A, 471-474, 1978.
25. Rosen, H. T., T. Novakov, and B. A. Bodhaine, Soot in the Arctic, Atmos. Environ., 15, 1371-1374, 1981.
26. Seiler, W., and P. J. Crutzen, Estimate of gross and net fluxes of carbon between the biosphere and the atmosphere from biomass burning, Clim. Change, 2, 207-247, 1980.
27. Sergides, C. A., J. A. Jassim, A. R. Chughtai, and D. M. Smith, The structure of hexane soot, III, Ozonation studies, Appl. Spectrosc., 41 (3), 482-492, 1987.
28. Smith, D. M., J. J. Griffin, and E. D. Goldberg, Elemental carbon in marine sediments: A baseline for burning, Nature, 241, 268-270, 1973.
29. Smith, D. M., W. F. Welch, J. A. Jassim, A. R. Chughtai, and D. H. Stedman, Soot-ozone reaction kinetics: Spectroscopic and gravimetric studies, Appl. Spectrosc., 42 (8), 1473-1482, 1988.
30. Steckel, P. R., and R.B. Engdahl, Air Pollution, in Encyclopedia of Chemical Technology, vol. 1, 3rd ed., pp. 624-649, Wiley-Interscience, New York, 1978.
31. Stephens, S., M. J. Rossi, and D. M. Golden, The heteroge neous reaction of ozone on carbonaceous surfaces, Int. J. Chem. Kinet., 18, 1133-1149, 1986.
32. Sturrock, M. G., B. J. Garvy, and T. A. Wing, Ozonation of naphthalene with water as participating solvent; preparation of o-phthalaldehyde, Can. J. Chem., 49, 3047-3057, 1971.
33. Watson, J. G., and J. C. Chow, The 1987-88 Metro Denver Brown Cloud Study, vol. III, Univ. of Denver, Denver, Colo., 1988.
34. Wolff, G. T., P. T. Groblicki, S. H. Cadle, and R. T. Count ess, Particulate carbon at various locations in the United States, in Particulate Carbon: Atmospheric Life Cycle, edited by G. T. Wolff and R. L. Klimisch, pp. 297-314, Plenum, New York, 1982.