Quantitative determination of chelators and their degradation products in mixed hazardous wastes from tank 241-SY-101 using derivatization GC/MS

Journal of Radioanalytical and Nuclear Chemistry

Volumn 211, Issue 2, 1996, Pages 383-402

  Grant, K E ^a,b   Mong, G M ^a   Lucke, R B ^a   Campbell, J A ^a  

^a PACIFIC NORTHWEST NATIONAL LABORATORY   (United States)

^b Columbia Basin College   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CHELATING AGENT; DRUG METABOLITE; EDETIC ACID; HEAVY METAL; N (2 HYDROXYETHYL)ETHYLENEDIAMINETRIACETIC ACID; NITRILOTRIACETIC ACID; UNCLASSIFIED DRUG;

ARTICLE; DERIVATIZATION; DRUG DEGRADATION; GAS CHROMATOGRAPHY; MASS SPECTROMETRY; WASTE MANAGEMENT; WATER ANALYSIS;

EID: 0030438261     PISSN: 02365731     EISSN: None     Source Type: Journal    
DOI: 10.1007/BF02039706     Document Type: Article

References (25)

1. S. C. METCALF, Determination of EDTA and HEDTA in Hanford Defense Waste by High Performance Liquid Chromatography, RHO-SA-218, 1991, Rockwell Hanford Operations, Richland, Washington, p 1.
2. J. L. MEANS, D. A. CRERAR, J. O. DUGID, Science, 200 (1978) 1477.
3. A. P. TOSTE, R. B. MYERS, The Relation Contributions of Natural and Waste-Derived Organics to the Subsurface Transport of Radionuclide, in: The Effects of Natural Organic Compounds and of Microorganisms on Radionuclide Transport, RWM-6, Radioactive Waste Management Committee, OECD Nuclear Energy Agency, Paris, France, 1986, p. 57.
4. A. P. TOSTE, J. Radioanal. Nucl. Chem., 161 (1992) 549.
5. D. M. STRACHAN, Minutes of the Tank Waste Science Panel, PNL-8278, March 25-27, Denver, Colorado, p. K.1.
6. S. A. BRYAN, L. R. PEDERSON, R. D. SCHEELE, Synthetic Waste Studies Final Report. 1992, PNL-8169, Pacific Northwest Laboratory, Richland, Washington, p. 1.
7. L. RUDLING, Water Res., 6 (1972) 871.
8. D. R. KNAPP, in: Handbook of Analytical Derivatization Reactions, John Wiley & Sons, Inc., New York, 1979, p. 21.
9. ORGANIC CHEMICAL DIVISION, General Procedure for the Determination of NTA, HEDTA, EDTA, and DTPA in Chelate and Metal Chetate Mixtures, RDSAP Number 0021, 1988, W. R. Grace and Company, Nashua, New Hampshire, p. 1.
10. J. BAUER, D. HEATCOTE, S. KROGH, J. Chromatogr. 369 (1986) 422.
11. M. E. UNGER, E. MAINKA, W. KNONIG, Fresen. Anal. Chem., 329 (1987) 50.
12. J. DAI, G. R. HELZ, Anal. Chem., 60 (1988) 301.
13. J. A. CAMPBELL, R. B. LUCKE, S. A. CLAUSS, Applications of LC/MS to the Study of Chelators in Mixed Hazardous Wastes, in: Proc. 39th ASMS Conf. on Mass Spectrometry and Allied Topics, Nashville, Tennessee, May 19-24, 1991, p. 1334.
14. J. A. CAMPBELL, H. R. UDSETH, R. B. LUCKE, Application of Electrospray Mass Spectrometry to the Analysis of Chelator and Chelator Fragments in Mixed Hazardous Wastes, in: Proc. 40th ASMS Conf. on Mass Spectrometry and Allied Topics, Washington, D. C., May 24-June 2, 1992.
15. A. P. TOSTE, R. B. LUCKE, T. J. LECHNER-FISH, D. J. HENDREN, in: Proc. Waste Management '87, Vol. 3" March 1-5, 1987, Tucson, Arizona, p. 323.
16. R. B. LUCKE, J. A. CAMPBELL, K. L. MCKEETA, S. A. CLAUSS, Analysis of Chelator and Chelator Fragments in Mixed Hazardous Wastes by Derivatization GC/MS, in: Proc. 39th ASMS Conference on Mass Spectrometry and Allied Topics, Nashville, Tennessee, 1991, p. 720.
17. A. P. TOSTE, F. T. HARA, D. J. HENDREN, T. J. LECHNER-FISH, Chemical and Radiochemical Analysis of Hanford Radioactive Wastes, 1987, PNL-6360, Pacific Northwest Laboratory, Richland, Washington.
18. R. O. LOKKEN, R. D. SCHEELE, D. M. STRACHAN, A. P. TOSTE, Complex Concentrate Pretreatment, FY1986 Progress Report, PNL-7687, 1986, Pacific Northwest Laboratory, Richland, Washington.
19. J. A. CAMPBELL, R. W. STROMATT, M. R. SMITH, D. W. KOPPENAAL, R. M. BEAN, T. E. JONES, D. M. STRACHAN, H. BABAD, Anal. Chem., 66 (1994) 1207A.
20. G. M. MONG, J. A. CAMPBELL, R. B. LUCKE, B. D. LERNER, K. L. WAHL, S. A. CLAUSS, K. E. GRANT, Progress in the Analysis and Speciation of Organic Chelator Compounds in Hanford Waste Tanks, in: Waste Management 95, February 27-March 3, 1995, Tucson, Arizona, in press.
21. J. A. CAMPBELL, S. A. CLAUSS, K. E. GRANT, V. HOOPES, B. D. LERNER, R. B. LUCKE, G. M. MONG, J. RAU, R. STEELE, Flammable Gas Safety Program, Analytical Methods Development: FY 1994 Progress Report, PNL-10127, Pacific Northwest Laboratory, Richland, Washington.
22. J. A. CAMPBELL, S. A. CLAUSS, K. E. GRANT, V. HOOPES, B. D. LERNER, R. B. LUCKE, G. M. MONG, J. RAU, R. STEELE, Flammable Gas Safety Program, Analytical Methods Development: FY 1993 Progess Report, PNL-9062, Pacific Northwest Laboratory, Richland, Washington.
23. A. VÁNYÓLOS, Rev. Chim. (Bucharest), 6 (1955) 378.
24. D. L. BALDWIN, R. W. STROMATT, W. I. WINTERS, Comparative Study of Total Organic Carbon Methods for High-Level Waste, PNL-SA-23718, Pacific Northwest National Laboratory, Richland, Wa, June 1994.
25. E.. C. ASHBY, E. K. BAREFIELD, C. L. LIOTTA, H. M. NEUMANN, D. BOATRIGHT, F. DOCTORVICH, A. DESHPANDE, C. F. YAO, Mechanisms of the Chemical Decomposition of Complexants in Hanford HLW Simulants, presented at the 208th American Chemical Society National Meeting, Washington, D. C., August 21-25, 1994.