Corundum solubility and aluminum speciation in KOH aqueous solutions at 400°C from 0.5 to 2.0 kbar

Geochimica et Cosmochimica Acta

Volumn 60, Issue 23, 1996, Pages 4601-4614

  Azaroual, M ^a,b   Pascal, M L ^a   Roux, J ^a  

^a CRSCM CNRS   (France)

^b BRGM   (France)

Author keywords

[No Author keywords available]

Indexed keywords

CORUNDUM; MASS TRANSFER; SOLUBILITY; SPECIATION; THERMODYNAMICS;

EID: 0030428726     PISSN: 00167037     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0016-7037(96)00269-4     Document Type: Article

References (72)

1. Anderson G. M. (1995) Alkali-aluminum complexing at high temperatures and pressures. Geochim. Cosmochim. Acta 59, 2155-2161.
2. Anderson G. M. and Burnham C. W. (1965) The solubility of quartz in supercritical water. Amer. J. Sci. 263, 494-511.
3. Anderson G. M. and Burnham C. W. (1967) Reactions of quartz and corundum with aqueous chloride and hydroxide solutions at high temperatures and pressures. Amer. J. Sci. 265, 12-27.
4. Anderson G. M. and Burnham C. W. (1983) Feldspar solubility and the transport of aluminum under metamorphic conditions. Amer. J. Sci. 283-A, 283-297.
5. Anderson G. M., Pascal M. L., and Rao J. (1987) Aluminum speciation in metamorphic fluids. In Chemical Transport in Metasomatic Processes (ed. H. Helgeson); NATO ASI Series C 218, 297-321.
6. Anderson G. M., Castet S., Schott J., and Mesmer R. E. (1991) The density model for estimation of thermodynamic parameters of reactions at high temperatures and pressures. Geochim. Cosmochim. Acta 55, 1769-1779.
7. Apps J. A., Neil J. M., and Jun C.-H. (1989) Thermodynamic properties of gibbsite, boehmite, diaspore and the aluminate ion between 0 and 350°C. Lawrence Berkeley Laboratory Rep. 21482.
8. Azaroual M., Fouillac C., and Matray J.-M. (1996) Silica behaviour in sedimentary basins: activity of aqueous silica and solid silica polymorphs in the Dogger-Keuper of the Paris Basin. Chem. Geol. (in press).
9. Barns R. L., Laudise R. A., and Shields R. M. (1963) The solubility of corundum in basic hydrothermal solvents. J. Phys. Chem. 67, 835-839.
10. Becker K. H., Cemic L., and Langer K. E. O. E. (1983) Solubility of corundum in supercritical water. Geochim. Cosmochim. Acta 47, 1573-1578.
11. 2. J. Petrol. 29, 445-522.
12. Bloom P. R. and Weaver R. M. (1982) Effect of the removal of reactive surface material on the solubility of synthetic gibbsites. Clays Clay Mineral. 30, 281-286.
13. Bourcier W. L., Knauss K. G., and Jackson K. J. (1987) Aluminum hydrolysis constants to 250°C determined from boehmite solubility measurements. Abstr. Prog. Geol. Soc. Amer. 19, 596.
14. Bourcier W. L., Knauss K. G., and Jackson K. J. (1993) Aluminum hydrolysis constants to 250°C from boehmite solubility measurements. Geochim. Cosmochim. Acta 57, 747-762.
15. Bryzgalin O. V. (1986) Estimating dissociation constants in the supercritical region for some strong electrolytes from an electrostatic model. Geochim. Intl. 23, 84-95.
16. Burnham S. W., Ryzhenko B. N., and Schitel D. (1973) Water solubility of corundum at 500-800°C and 6 Kbar. Geochim. Intl. 12, 1374.
17. Castet S., Dandurand J.-L., Schott J., and Gout R. (1992) Experimental study of aluminum hydrolysis and complexation with acetate and sodium ions in hydrothermal solutions. In Water-Rock interaction (ed. Y. K. Kharaka and A. S. Maest), pp. 1013-1016. Balkema.
18. Castet S., Dandurand J.-L., Schott J., and Gout R. (1993) Boehmite solubility and aqueous aluminum speciation in hydrothermal solutions (90-350°C): Experimental study and modeling. Geochim. Cosmochim. Acta 57, 4869-4884.
19. Chen X., Oscaron J. L., Gillespie S. E., Cao H., and Izatt R. M. (1994) Determination of enthalpy of ionization of water from 250 to 350°C. J. Soln Chem. 23, 747-768.
20. Couturier Y., Michard G., and Sarazin G. (1984) Constantes de formation des complexes hydroxydés de l'aluminium en solution aqueuse de 20 à 70°C. Geochim. Cosmochim. Acta 48, 649-659.
21. Davis N. F. (1972) Experimental studies in the system sodium-alumina trisilicate-water: Part I. The apparent solubility of albite in supercritical water. Ph.D. dissertation, Penn. State Univ.
22. Diakonov I., Pokrovski G., Schott J., Castet S., and Gout R. (1996) An experimental and computational study of sodium-aluminium complexing in crustal fluids. Geochim. Cosmochim. Acta 60, 197-211.
23. 2O-Lösungen bis 750°C. Z. Phys. Chem. 8, 92-106.
24. Fuoss R. M. and Kraus C. A. (1933) Properties of electrolytic solutions. III. The dissociation constants. J. Amer. Chem. Soc. 55, 2387-2399.
25. Ganeyev I. G. and Rumyantsev V. N. (1974) Solubility of corundum in water at elevated temperatures and pressures. Geokhimyia 9, 1402-1403 (in Russian).
26. Helgeson H. C., Delaney J. M., Nesbitt H. W., and Bird D. K. (1978) Summary and critique of the thermodynamic properties of rock forming minerals. Amer. J. Sci. 278-A, 1-229.
27. Helgeson H. C., Kirkham D. H., and Flowers G. C. (1981) Theoretical prediction of the thermodynamic behaviour of aqueous electrolytes at high pressures and temperatures. IV. Calculation of activity coefficients, osmotic coefficients, and apparent molal and standard and relative partial molal properties to 600°C and 5 kb. Amer. J. Sci. 281, 1249-1516.
28. 4(aq)], diaspore, boehmite, and bayerite at 298.15 K and 1 bar, and the heats of solution of several gibbsite samples. Geochim. Cosmochim. Acta 42, 1533-1543.
29. Hemingway B. S., Robie R. A., and Apps J. A. (1991) Revised values for the thermodynamic properties of boehmite, AlO(OH), and related species and phases in the system Al-H-O. Amer. Mineral. 76, 445-457.
30. Johnson J. W., Oelkers E. H., and Helgeson H. C. (1992) SUPCRT92 - A software package for calculating the standard molal thermodynamic properties of minerals, gases, aqueous species and reactions from 1 to 5000 bars and 0° to 1000°C. Computers Geosci. 18, 899-947.
31. 4 from solubility measurements. Soil Sci. Soc. Proc. 30, 595-598.
32. Korzhinskiy (1987) The solubility of corundum in an HCl fluid and forms taken by Al. Geochem. Intl. 25, 105-110.
33. Lippincott E. R., Psellos J. A., and Tobin M. C. (1952) The Raman spectra and structures of aluminate and zincate ions. J. Phys. Chem. 20, 536.
34. May H. M., Helmke P. A., and Jackson M. L. (1979) Gibbsite solubility and thermodynamic properties of hydroxy-aluminum ions in aqueous solution at 25°C. Geochim. Cosmochim. Acta 43, 861-868.
35. Michard G. (1990) Equilibres chimiques dans les eaux naturelles. Publisud.
36. Moine B., Fortuné J. P., Moreau P., and Viguier F. (1989) Comparative mineralogy, geochemistry and conditions of formation of two metasomatic talc and chlorite deposits: Trimouns (Pyrénées, France) and Rabenwald (Eastern Alps, Austria). Econ. Geol. 84, 1398-1416.
37. Moolenaar R. J., Evans J. C., and McKeener L. D. (1970) The structure of the aluminate ion in solutions at high pH. J. Phys. Chem. 74, 3629-3636.
38. Morey G. W. (1957) The solubility of solids in gases. Econ. Geol. 52, 225-251.
39. Oelkers E. H. and Helgeson H. C. (1988) Calculation of the thermodynamic and transport properties of aqueous species at high pressures and temperatures: dissociation constants for supercritical alkali and metal halides at temperatures from 400 to 800°C and pressures from 500 to 4000 bars. J. Phys. Chem. 92, 1631-1639.
40. 5 polymorphs in HCl at high T and P. Geochem. Intl. 25, 83-88.
41. Palmer D. A. and Wesolowski D. J. (1992) Aluminum speciation and equilibria in aqueous solution: II. The solubility of gibbsite in acidic sodium chloride solutions from 30 to 70°C. Geochim. Cosmochim. Acta 56, 1093-1111.
42. Palmer D. A. and Wesolowski D. J. (1993) Aluminum speciation and equilibria in aqueous solution: II. Potentiometric determination of the first hydrolysis constant of aluminum (III) in sodium chloride solutions to 125°C. Geochim. Cosmochim. Acta 57, 2929-2938.
43. Pascal M.-L. (1979) Les albitites du Massif de l'Agly (Pyrénées-Orientales). Thèse de l'Ecole Nationale Supérieure des Mines de Paris.
44. 2O-HCl: contribution expérimentale. Thèse de Doctorat, Univ. Pierre et Marie Curie.
45. Pascal M.-L. and Anderson G. M. (1989) Speciation of Al, Si, and K in supercritical solutions: experimental study and interpretation. Geochim. Cosmochim. Acta 53, 1843-1855.
46. Pearson R. G. (1969) Hard and Soft Acids and Bases. Surv. Prog. Cem. 5, 1-52.
47. Peryea F. J. and Kittrick J. A. (1988) Relative solubility of corundum, gibbsite, boehmite and diaspore at standard state conditions. Clays Clay Mineral. 36, 391-396.
48. Pitzer K. S. (1973) Thermodynamics of electrolytes: I. Theoretical basis and general equations. J. Phys. Chem. 77, 268-277.
49. Pokrovskii V. A. and Helgeson H. C. (1991) Unified description of incongruent reactions and mineral solubilities as a function of bulk composition and solution pH in hydrothermal systems. Canadian Mineral. 29, 909-942.
50. 2O-NaCl at temperatures to 1000°C and pressures to 5 kb. In Water-Rock interaction (ed. Y. K. Kharaka and A. S. Maest), pp. 1021-1024. Balkema.
51. 4 formation on the solubility of corundum at high pressures and temperatures. Goldschmidt Conf. Edinburgh-1994, Min. Mag. 58A, 736-737.
52. 2O-NaCl. Amer. J. Sci. 295, 1255-1342.
53. Ragnarsdottir K. V. and Walther J. V. (1985) Experimental determination of corundum solubilities in pure water between 400-700°C and 1-3 kbar. Geochim. Cosmochim. Acta 49, 2109-2116.
54. Roberson C. E. and Hem J. D. (1969) Solubility of aluminum in the presence of hydroxide, fluoride, and sulfate. U.S. Geol. Survey Water-Supply Paper 1827-C.
55. 5 pascals) pressure and at high temperatures. U.S. Geol. Survey Bull. 1452.
56. Roux J. and Lefèvre A. (1992) A fast-quench device for internally heated pressure vessels. European J. Mineral. 4, 279-281.
57. Roux J., Holtz F., Lefèvre A., and Schulze F. (1994) A reliable high-temperature setup for internally heated pressure vessels: Applications to silicate melt studies. Amer. Mineral. 79, 1145-1149.
58. Sanjuan B. and Michard G. (1987) Aluminum hydroxide solubility in aqueous solutions containing fluoride ions at 50°C. Geochim. Cosmochim. Acta 51, 1823-1831.
59. Sanjuan B. and Michard G. (1990) Reply to comment by M. A. A. Schoonen and H. A. van Straten on "Aluminum hydroxide solubility in aqueous solutions containing fluoride ions at 50°C". Geochim. Cosmochim. Acta 54, 2887-2888.
60. Seward T. M. (1974) Determination of the first ionization constant of silicic acid from quartz solubility in borate buffer solutions to 350°C. Geochim. Cosmochim. Acta 38, 1651-1664.
61. Shock E. L. and Helgeson H. C. (1988) Calculation of the thermodynamic and transport properties of aqueous species at high pressures and temperatures: correlation algorithms for ionic species and equation of state prediction to 5 kb and 1000°C. Geochim. Cosmochim. Acta 52, 2009-236.
62. Shock E. L., Oelkers E. H., Johnson J. W., Sverjensky D. A., and Helgeson H. C. (1992) Calculation of the thermodynamic properties of aqueous species at high pressures and temperatures. Effective electrostatic radii, dissociation constants and standard partial molal properties to 100°C and 5 kbar. J. Chem. Soc. Faraday Trans. 88, 803-826.
63. Sillèn L. G. and Martell A. E. (1971) Stability constants of metal ion complexes. Chem. Soc. (Lond.) Spec. Pub. 17.
64. Sverjensky D. A., Hemley J. J., and D'Angelo W. M. (1991) Thermodynamic assessment of hydrothermal alkali feldspar-mica-aluminosilicate equilibria. Geochim. Cosmochim. Acta 55, 989-1004.
65. Tanger J. C. and Helgeson H. C. (1988) Calculation of the thermodynamic and transport properties of aqueous species at high pressures and temperatures: revised equations of state for the standard partial molal properties of ions and electrolytes. Amer. J. Sci. 288, 19-98.
66. 2O. Thèse de l'Univ. Paul Sabatier.
67. Verdes G. and Gout R. (1987) Réhydration d'oxydes d'aluminium amorphe. Application à l'étude de l'équilibre boehmite-bayérite. Bull. Mineral. 110, 579-587.
68. 2O. Geochim. Cosmochim. Acta 57, 2431-2439.
69. 4 from 0 to 100°C. Geochim. Cosmochim. Acta 56, 1065-1091.
70. Wesolowski D. J. and Palmer D. A. (1994) Aluminum speciation and equilibria in aqueous solution: V. Gibbsite solubility at 50°C and pH 3-9 in 0.1 molal NaCl solutions (a general model for aluminum speciation; analytical methods). Geochim. Cosmochim. Acta 56, 1065-1091.
71. 2O. Geochim. Cosmochim. Acta 51, 365-372.
72. Xie Z. and Walther J. V. (1993) Quartz solubilities in NaCl solutions with and without wollastonite at elevated temperatures and pressures. Geochim. Cosmochim. Acta 57, 1947-1955.