Redox characterization of the surfaces of seven iron-bearing minerals: Use of molecular probes and uv-visible spectroscopy

Clays and Clay Minerals

Volumn 44, Issue 5, 1996, Pages 573-586

  Yu, Y Shane ^a,c   Bailey, George W ^b  

^a DynCorp Technol Applications Inc   (United States)

^b U S ENVIRONMENTAL PROTECTION AGENCY   (United States)

^c Equifax Inc   (United States)

Author keywords

Electron activity; Indicators; Iron bearing minerals; Redox potential; Surface acidity; UV visible spectroscopy

Indexed keywords

IRON; MINERAL SURFACE; REDOX POTENTIAL; UV VISIBLE SPECTROSCOPY;

EID: 0030428368     PISSN: 00098604     EISSN: None     Source Type: Journal    
DOI: 10.1346/CCMN.1996.0440501     Document Type: Article

References (31)

1. Bailey GW, Karickhoff SW. 1973. An ultraviolet spectrescopic method for monitoring Surface acidity of clay minerals under varying water content. Clays Clay Miner 21: 471-477.
2. Bartlett RJ. 1986. Soil redox behavior. In: Sparks DL, editor. Soil physical chemistry. Boca Raton, FL: CRC Press. p 179-207.
3. Bates RG. 1959. Electrode potentials: Treatise on analytical chemistry, Part 1. In: Kolthoff IM, Elving PJ, editors. New York: Interscience, p 319-359.
4. Bohn HL, McNeal BL, O'Connor GA. 1979. Soil chemistry. New York: John Wiley and Sons. p 247-271.
5. Brown G, Newman ACD, Rayner JH, Weir AH. 1978. The structures and chemistry of soil clay minerals. In: Greenland DJ, Hayes MHB, editors. The chemistry of soil constituents. New York: John Wiley and Sons, p 29-178.
6. Cenens J, Schoonheydt RA. 1988. Visible spectroscopy of methylene blue on hectorite, laponite B, and barasym in aqueous suspension. Clays Clay Miner 36:214-224.
7. Clark WM. 1960. Oxidation-reduction potentials of organic systems. Baltimore, MD: Williams and Wilkins. p 1-106.
8. Conant JB. 1926. The electrochemical formulation of the irreversible reduction and oxidation of organic compounds. Chem Rev 3:1-40.
9. Goldhaber MB. 1983. Experimental study of metastable sulfur oxyanion formation during pyrite oxidation. Am J Sci 283:193-217.
10. Guenther WB. 1975. Chemical equilibrium. New York: Plenum Press, p 207-228.
11. Hewitt LF. 1950. Oxidation-reduction potentials in bacteriology and biochemistry. Edinburgh, UK: Livingstone. p 19-36.
12. Jackson ML. 1956. Soil chemical analysis - Advanced course. Published by the author, Dept. of Soils, Univ. of Wisconsin, Madison, WI. p 100-115.
13. Karickhoff SW, Bailey GW. 1976. Protonation of organic bases in clay-water systems. Clays Clay Miner 24:170-176.
14. Light TS. 1972. Standard solution for redox potential measurements. Anal Chem 44:1038-1039.
15. Lindsay W. 1988. Solubility and redox equilibria of iron compounds in soils. In: Stucki JW, Goodman BA, Schwertmann U, editors. Iron in soil and clay minerals. Nor well, MA: Kluwer Academic Publishers, p 37-61.
16. Liu Z. 1985. Oxidation-reduction potential. In: Yu T, editor. Physical chemistry of paddy soils. Beijing: Science Press, p 1-26.
17. Ljungdahl LG, Andreesen JR. 1978. Formate dehydrogenase, a selenium-tungsten enzyme from Clostridium thermoaceticum, Meth in Enzymol 53:360-372.
18. Loughnan FC. 1969. Chemical weathering of the silicate minerals. New York: American Elsevier. p 4-26.
19. Luther GW. 1987. Pyrite oxidation and reduction: Molecular orbital theory considerations. Geochim Cosmochim Acta 51:3193-3199.
20. Moses CO, Nordstrom DK, Herman JS, Mills AL. 1987. Aqueous pyrite oxidation by dissolved oxygen and by ferric iron. Geochim Cosmochim Acta 51:1561-1571.
21. Murad E, Fischer WR. 1988. The geobiochemical cycle of iron. In: Stucki JW, Goodman BA, Schwertmann U, editors. Iron in soils and clay minerals. Norwell, MA: Kluwer Academic Publishers, p 1-18.
22. Patrick WH, Jr. 1980. The role of inorganic redox systems in controlling reduction in paddy soils. In: Editor, China. Inst Soil Sci, Proc. Symposium on Paddy Soil. Nanjing, China: Academia Sinica. p 107-117.
23. Perrin DD, Dempsey B, Serjeant EP. 1981. Prediction of pKa for phenols, aromatic carboxylic acids and aromatic amines. In: Perrin DD, Dempsey B, Serjeant EP, editors. pKa prediction for organic acids and bases. Norwell, MA: Chapman and Hall, p 44-52.
24. Ponnamperuma FN, Tianco EM, Loy T. 1967. Redox equilibria in flooded soils. I. The iron hydroxide system. Soil Sci 103:374-382.
25. Ponnamperuma FN. 1972. The chemistry of submerged soils. In: Brady NC, editor. Advances in agronomy. New York: Academic Press. p 29-96.
26. Schwertmann U. 1971. Transformation of hematite to goethite in soils. Nature 232:624-625.
27. Schwertmann U, Taylor RM. 1989. Iron oxide. In: Dixon JB, Weed SB, editor. Minerals in soil environments. Madison, WI: Soil Sci Soc Am. p 379-438.
28. Stumm W, Morgan JJ. 1985. The conceptual significance of pe. A comment on J.D. Hostettler's paper, electrode electrons, aqueous electrons and redox potentials in natural waters. Am J Sci 285:856-859.
29. Wolfe NL, Mingelgrin U, Miller GC. 1990. Abiotic transformations in water, sediment, and soil. In: Cheng HH, editor. Pesticides in the soil environment: Processes, impact, and modeling. SSSA Book Series 2, Madison, WI: Soil Sci Soc Am. p 103-168.
30. Wurmser R, Banerjee R. 1964. Oxidation-reduction potentials. Compr Biochem 12:62-88.
31. Zobell CE. 1946. Studies on redox potential of marine sediments. Am Assoc Pet Geol Bull 30:477-513.