Direct kinetic evidence for the formation of an acylpyridinium intermediate in synthetic p-nitrophenyl esterase-catalyzed hydrolysis reactions

Macromolecules

Volumn 29, Issue 27, 1996, Pages 8587-8590

  Wang, Guang Jia ^a   Fife, Wilmer K ^a  

^a INDIANA UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ACYLATION; CATALYSIS; COMPOSITION EFFECTS; ENZYME KINETICS; ENZYMES; ESTERS; HYDROLYSIS; NITROGEN COMPOUNDS; REACTION KINETICS; SUBSTRATES; SYNTHESIS (CHEMICAL);

ACYLPYRIDINIUM; NITROPHENYL ALKANOATES; NITROPHENYL ESTERASE;

CATALYSTS;

EID: 0030412276     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma961070m     Document Type: Article

References (5)

1. Scriven, E. F. V. Chem. Soc. Rev. 1983, 12, 129.
2. Hofle, G.; Steglich, W.; Vorbruggen, H. Angew. Chem., Int. Ed. Engl. 1978, 17, 569.
3. Delaney, E. J.; Wood, L. E.; Klotz, I. M. J. Am. Chem. Soc. 1982, 104, 799.
4. Hirl, M. A.; Gamson, E. P.; Klotz, I. M. J. Am. Chem. Soc. 1979, 101, 6020.
5. Cei, G.; Mathias, L. J. Macromolecules 1990, 23, 4127.