Equivalence between microelectrodes of different shapes: Between myth and reality

Analytical Chemistry

Volumn 68, Issue 24, 1996, Pages 4377-4388

  Amatore, Christian ^a  

^a ECOLE NORMALE SUPÉRIEURE   (France)

Author keywords

[No Author keywords available]

Indexed keywords

DIFFUSION; PHYSICAL CHEMISTRY; REACTION KINETICS;

DISK ELECTRODES; ELECTRODE SHAPES; EQUIVALENCE RELATIONSHIPS; HEMISPHERE ELECTRODES;

MICROELECTRODES;

EID: 0030410635     PISSN: 00032700     EISSN: None     Source Type: Journal    
DOI: 10.1021/ac960421s     Document Type: Article

References (7)

1. For reviews, see: (a) Amatore, C. In Physical Electrochemistry, Rubinstein, I., Ed.; M. Dekker: New York, 1995; Chapter 4, pp 136-208.
2. (b) Wightman, R. M.; Wipf, D. O. In Electroanalytical Chemistry, Bard, A. J., Ed.; M. Dekker: New York, 1989; Vol. 15, pp 267-353.
3. Microelectrodes: Theory and Applications; Montenegro, M. I., Queiros, M. A., Daschbach, J. L., Eds.; NATO ASI Series E, 197; Kluwer Academic Press: Dordrecht, 1991.
4. See, e.g.: Varco Shea, T.; Bard, A. J. Anal. Chem. 1987, 59, 2102.
5. Speiser, B. In Electroanalytical Chemistry, Bard, A. J., Rubinstein, I., Eds.; M. Dekker: New York, 1996; Vol. 19, pp 1-108.
6. See, e.g.: DigiSim from Bioanalytical Systems, Inc., based on the Fast Implicit Finite Difference method introduced by M. Rudolph, which proposes simulations at spherical and cylindrical electrodes virtually for all possible electrochemical mechanisms. For a description of the simulator, see: Rudolph, M.; Reddy, D. P.; Feldberg, S.W. Anal. Chem. 1994, 66, 589A and references therein.
7. See, e.g.: Amatore, C. A.; Fosset, B.; Deakin, M. R.; Wightman, R. M. J. Electroanal Chem. 1987, 225, 33.