A Unified and Predictive Model for Mixed-Electrolyte, Aqueous Mixed-Solvent Systems Using Parameters for Ions and Solvents

Industrial and Engineering Chemistry Research

Volumn 35, Issue 12, 1996, Pages 4772-4780

  Lee, Chul Soo ^a   Park, Sung Bin ^a   Shim, Yon Sik ^a  

^a Korea University   (South Korea)

Author keywords

[No Author keywords available]

Indexed keywords

ELECTROSTATICS; FREE ENERGY; GIBBS FREE ENERGY; IONS; MATHEMATICAL MODELS; PHASE EQUILIBRIA; SOLVENTS;

GIBBS FUNCTION MODELS; MIXED ELECTROLYTE MIXED SOLVENT SYSTEMS;

ELECTROLYTES;

EID: 0030401874     PISSN: 08885885     EISSN: None     Source Type: Journal    
DOI: 10.1021/ie960294q     Document Type: Article

References (55)

1. Achard, C.; Dussap, C. G.; Gros, J. B. Representation of Water-Alcohol-Electrolyte Mixtures with a Modified UNIFAC Group-Contribution Method. Fluid Phase Equilib. 1994, 98, 71.
2. Bezboruah, C. P.; Covington, A. K.; Robinson, R. A. Excess Gibbs Energies of Aqueous Mixtures of Alkali Metal Chlorides and Nitrates. J. Chem. Thermodyn. 1970, 2, 431.
3. Bromley, L. A. Thermodynamic Properties of Strong Electrolytes in Aqueous Solutions. AIChE J. 1973, 19, 313.
4. Burgess, J. Metal Ions in Solution; Ellis Horwood: New York, 1978.
5. Chen, C. C.; Evans, L. B. A Local Composition Model for the Excess Gibbs Energy of Aqueous Electrolyte Systems. AIChE J. 1986, 32, 444.
6. Chen, C.-C.; Britt, H. I.; Boston, J. F.; Evans, L. B. Local Composition Model for Excess Gibbs Energy of Electrolyte Systems. Part I. Single Solvent, Single Completely Dissociated Electrolyte Systems. AIChE J. 1982, 28, 588.
7. Ciparis, J. N. Data of Salt Effect in Vapor-Liquid Equilibrium; Lituanian Agricultural Academy: Kaunas, Lithuania, 1966.
8. Conway, B. E. Electrochemical Data; Green Wood: New York, 1952.
9. Covington, A. K.; Lilley, T. H.; Robinson, R. A. Excess Free Energies of Aqueous Mixtures of Some Alkali Metal Halide Salt Pairs. J. Phys. Chem. 1968, 72, 2759.
10. Cruz, J. L.; Renon, H. A New Thermodynamic Representation of Binary Electrolyte Solutions Nonideality in the Whole Range of Concentrations. AIChE J. 1978, 24, 817.
11. De M. Cardoso, M. J. E.; O'Connell, J. P. Activity Coefficients in Mixed Solvent Electrolyte Solutions. Fluid Phase Equilib. 1987, 33, 315.
12. Esval, O. E.; Tyree, S. Y., Jr. The Activity Coefficients of Ammonium Perchlorate in Water at 25 °C. J. Phys. Chem. 1962, 66, 940.
13. Feakins, D.; Voice, P. J. Studies in Ion Solvation in Non-aqueous Solvents and Their Aqueous Mixtures, Part 14-Free Energies of Transfer of the Alkali-metal Chlorides from Water to 10-99% (w/w) Methanol-Water Mixtures at 25 °C. J. Chem. Soc., Faraday Trans. 1972, 68, 1390.
14. Filippov, V. K.; Kalinkin, A. M.; Vasin, S. K. Thermodynamics of Phase Equilibria of Aqueous (Lithium Sulfate + Cesium Sulfate), (Sodium Sulfate + Cesium Sulfate), and (Potassium Sulfate + Cesium Sulfate) at 298.15 K Using Pitzer's Model. J. Chem. Thermodyn. 1987, 19, 185.
15. Filippov, V. K.; Kalinkin, A. M.; Vasin, S. K. Thermodynamics of Phase Equilibria of Aqueous (Lithium Sulfate + Alkali-Metal Sulfate) (Alkali Metal: Na, K, and Rb), and (Sodium Sulfate + Rubidium Sulfate), at 298.15 K Using Pitzer's Model J. Chem. Thermodyn. 1989, 21, 935.
16. Gmehling, J.; Onken, U.; Arlt, W. Vapor-Liquid Equilibrium Data Collection. In Chemistry Data Series; Behrens, D., Eckermann, R., Eds.; DECHEMA: Frankfurt, 1977; Vol. 1, Part 1.
17. Goldberg, R. N. Evaluated Activity and Osmotic Coefficients for Aqueous Solutions: Thirty Six Uni-Bivalent Electrolytes. J. Phys. Chem. Ref. Data 1981, 10, 671.
18. Hamer, W. J.; Wu, Y. Osmotic Coefficients and Mean Activity Coefficients of Uni-univalent Electrolytes in Water at 25 °C. J. Phys. Chem. Ref. Data 1972, 1, 1047.
19. Harned, H. S.; Owen, B. B. Physical Chemistry of Electrolyte Solutions, 2nd ed.; Butterworth: London, 1968.
20. Kikic, I.; Fenneglia, M.; Rasmussen, P. UNIFAC Prediction of Vapor-Liquid Equilibria in Mixed Solvent Salt Systems. Chem. Eng. Sci. 1991, 46, 2775.
21. Lanier, R. D. Properties of Organic-Water Mixtures. III. Activity Coefficients of Sodium Chloride by Cation-Sensitive Glass Electrodes. J. Phys. Chem. 1965, 69, 2697.
22. E Model for Single and Mixed Solvent Electrolyte Systems. 1. Model and Results for Strong Electrolytes. Fluid Phase Equilib. 1994, 94, 89.
23. Lindenbaum, S.; Rush, R. M.; Robinson, R. A. Osmotic and Activity Coefficients for Mixtures of Lithium Chloride with Barium Chloride and Cesium Chloride with Barium Chloride in Water at 298.15 K. J. Chem. Thermodyn. 1972, 4, 381.
24. Link, W. F.; Seidell, A. Solubilities of Inorganic and Metal Organic Compounds. 4th ed.; American Chemical Society: Washington, DC, 1965; Vol. II.
25. Macedo, E. A.; Skovborg, P.; Rasmussen, P. Calcium of Phase Equilibria for Solutions of Strong Electrolytes in Solvent-Water Mixtures. Chem. Eng. Sci. 1990, 45, 875.
26. Meissner, H. P.; Kusik, C. L. Activity Coefficients of Strong Electrolytes in Multicomponent Aqueous Solutions. AIChE J. 1972, 18, 294.
27. Meissner, H. P.; Tester, J. W. Activity Coefficients of Strong Electrolytes in Aqueous Solutions. Ind. Eng. Chem. Proc. Des. Dev. 1972, 11, 128.
28. Mock, B.; Evans, L. B.; Chen, C. C. Thermodynamic Representation of Phase Equilibria of Mixed-Solvent Electrolyte Systems. AIChE J. 1986, 32, 1655.
29. Pitzer, K. S. Thermodynamics of Electrolytes. I. Theoretical Basis and General Equations. J. Chem. Phys. 1973, 77, 268.
30. Pitzer, K. S.; Mayorga, G. Thermodynamics of Electrolytes. II. Activity and Osmotic Coefficients for Electrolytes with One or Both Ions Univalent. J. Chem. Phys. 1973, 77, 2300.
31. Pitzer, K. S.; Kim, J. J. Thermodynamics of Electrolytes. IV. Activity and Osmotic Coefficients for Mixed Electrolytes. J. Am. Chem. Soc. 1974, 96, 5701.
32. 2 at 25 °C. J. Chem. Thermodyn. 1971, 3, 319.
33. E Model for Single and Mixed Solvent Electrolyte Systems. 2. Results and Comparison with Other Models. Fluid Phase Equilib. 1994, 94, 115.
34. Popovich, O. J. Chem. Eng. Data 1982, 27, 105.
35. Rafal, M.; Berthold, J. W.; Scrivner, N. C.; Grise, S. L. Models for Electrolyte Solutions. In Models for Thermodynamic and Phase Equilibria Calculations; Sandler, S. I., Ed.: Marcel Dekker: New York, 1993.
36. Rard, J. A.; Miller, D. G. Isopiestic Determination of the Osmotic and Activity Coefficients of Aqueous CsCl, SrCl, and Mixtures of NaCl and CsCl at 25 °C. J. Chem. Eng. Data 1982, 27, 169.
37. Rastogi, A.; Tassios, D. Thermodynamics of a Single Electrolyte in a Mixture of Two Solvents. Ind. Eng. Chem. Res. 1987, 26, 1344.
38. Robinson, R. A. The Osmotic Properties of Aqueous Sodium Chloride-Cesium Chloride Mixtures at 25 °C. J. Am. Chem. Soc. 1952, 74, 6035.
39. Robinson, R. A. Activity Coefficients of Sodium Chloride and Potassium Chloride in Mixed Aqueous Solutions at 25 °C. J. Phys. Chem. 1961, 65, 662.
40. Robinson, R. A.; Lim, C. K. The Osmotic Properties of Some Aqueous Salt Mixtures at 25 °C. Trans. Faraday Soc. 1953, 49, 1144.
41. Robinson, R. A.; Stokes, R. H. Electrolyte Solutions; Butterworth: London, 1955.
42. Robinson, R. A.; Bower, V. E. Properties of Aqueous Mixtures of Pure Salts: Thermodynamics of the Ternary System Water-Potassium Chloride-Barium Chloride at 25 °C. J. Res. Natl. Bur. Stand., Set A 1965, 69, 439.
43. Robinson, R. A.; Bower, V. E. Properties of Aqueous Mixtures of Pure Salts. Thermodynamics of the Ternary System: Water-Calcium Chloride-Magnesium Chloride at 25 °C. J. Res. Natl. Bur. Stand., Set A 1966a, 70, 305.
44. Robinson, R. A.; Bower, V. E. Properties of Aqueous Mixtures of Pure Salts. Thermodynamics of the Ternary System: Water-Sodium Chloride-Calcium Chloride at 25 °C. J. Res. Natl. Bur. Stand., Set A 1966b, 70, 313.
45. Robinson, R. A.; Wood, R. H.; Reilly, P. J. Calculation of Excess Gibbs Energies and Activity Coefficients from Isopiestic Measurements on Mixtures of Lithium and Sodium Salts. J. Chem. Thermodyn. 1971, 3, 461.
46. Robinson, R. A.; Platford, R. F.; Childs, C. W. Thermodynamics of Aqueous Mixtures of Sodium Chloride, Potassium Chloride, Sodium Sulfate, and Potassium Sulfate at 25 °C. J. Solution Chem. 1972, 1, 167.
47. 2O. J. Phys. Chem. 1968, 72, 767.
48. Sander, B.; Fredenslund, Aa.; Rasmussen, P. Calculation of Vapor-Liquid Equilibria in Mixed Solvent/Salt Systems Using an Extended UNIQUAC Equation. Chem. Eng. Sci. 1986, 41, 1171.
49. Sandler, S. I. Chemical and Engineering Thermodynamics, 2nd ed.; Wiley: New York, 1989.
50. Shim, Y. S.; Lee, C. S. Solubilities of Mixed Strong 1:1 Electrolytes in Water and Water-Methanol Mixtures. Kor. J. Chem. Eng. 1991, 8, 227.
51. Shim, Y. S.; Kim, H. D.; Lee, C. S. Experimental Activity Coefficient of NaCl in NaCl-KCl-Methanol-Water System. Hwahak Konghak 1991, 29, 630.
52. Shin, M. S.; Yoo, K. P.; You, S. S.; Lee, C. S. A New Nonrandom Lattice Fluid Model and Its Simplification by Two-Liquid Theory for Phase Equilibria of Complex Mixtures. Int. J. Thermophys. 1995, 16, 723.
53. Wong, D. S. H.; Sandler, S. I. A Theoretically Correct Mixing Rule for Cubic Equations of States. AIChE J. 1992, 38, 671.
54. Yoo, K. P.; Shin, M. S., Yoo, S. J.; You, S. S.; Lee, C. S. A New Equation of State Based on Nonrandom Two-Fluid Lattice Theory for Complex Mixtures. Fluid Phase Equilib. 1995, 111, 175.
55. Zemaitis, J. F.; Clark, D. M.; Rafa, M.; Scrivner, N. C. Handbook of Aqueous Electrolyte Thermodynamics; DIPPR: New York, 1986.