Correlation and Prediction of the Solubility of CO2 and H2S in Aqueous Solutions of Triethanolamine

Industrial and Engineering Chemistry Research

Volumn 35, Issue 12, 1996, Pages 4804-4809

  Li, Yi Gui ^a,b   Mather, Alan E ^a  

^a UNIVERSITY OF ALBERTA   (Canada)

^b TSINGHUA UNIVERSITY   (China)

Author keywords

[No Author keywords available]

Indexed keywords

CARBON DIOXIDE; COMPOSITION EFFECTS; CORRELATION METHODS; HYDROGEN SULFIDE; MATHEMATICAL MODELS; PRESSURE EFFECTS; SOLUBILITY; SOLUTIONS; SOLVENTS; THERMAL EFFECTS; THERMODYNAMICS;

ACID GAS LOADINGS; CLEGG PITZER EQUATIONS; TRIETHANOLAMINES;

AMINES;

EID: 0030386953     PISSN: 08885885     EISSN: None     Source Type: Journal    
DOI: 10.1021/ie960244l     Document Type: Article

References (24)

1. Bates, R. G.; Allen, G. F. Acid Dissociation Constant and Related Thermodynamic Quantities for Triethanolammonium Ion in Water from 0 to 50 °C . J. Res. Natl. Bur. Stand. 1960, 64A, 343.
2. Bhattacharyya, S. K.; Nakhate, S. N. Conductance of salts in Non-Aqueous Solvents. Part I. Conductance of salts in triethanolamine. J. Indian Chem. Soc. 1947, 24, 1.
3. Chang, H.-T.; Posey, M.; Rochelle, G. T. Thermodynamics of Alkanolamine-Water Solutions from Freezing Point Measurements. Ind. Eng. Chem. Res. 1993, 32, 2324.
4. Chen, C.-C.; Britt, H. I.; Boston, J. F.; Evans, L. B. Extension and Application of the Pitzer Equation for Vapor-Liquid Equilibrium of Aqueous Electrolyte Systems with Molecular Solutes. AIChE J. 1979, 25, 820.
5. Clegg, S. L.; Brimblecombe, P. Equilibrium Partial Pressures and Mean Activity and Osmotic coefficients of 0-100% Nitric Acid as a Function of Temperature. J. Phys. Chem. 1990, 94, 5369.
6. Clegg, S. L.; Pitzer, K. S. Thermodynamics of Multicomponent, Miscible, Ionic Solutions: Generalized Equations for Symmetrical Electrolytes. J. Phys. Chem. 1992, 96, 3513.
7. Clegg, S. L.; Brimblecombe, P. Application of a Multicomponent Thermodynamic Model to Activities and Thermal Properties of 0-40 mol/kg Aqueous Sulfuric Acid from <200 to 328 K. J. Chem. Eng. Data 1995, 40, 43.
8. Dow Chemical Company, The Alkanolamines Handbook; The Dow Chemical Co.: Houston, TX, 1981.
9. Edwards, T. J.; Maurer, G.; Newman, J.; Prausnitz, J. M. Vapor Liquid Equilibria in Multicomponent Aqueous Solutions of Volatile Weak Electrolytes. AIChE J. 1978, 24, 966.
10. Ikada, E.; Hida, Y.; Okamoto, H.; Hagino, J.; Koizumi, N. Dielectric Properties of Ethanolamines. Bull. Inst. Chem. Res., Kyoto Univ. 1968, 46, 239.
11. 2 in Triethanolamine Solutions. Can. J. Chem. Eng. 1985, 63, 122.
12. Jou, F.-Y.; Otto, F. D.; Mather, A. E. Solubility of Mixtures of Hydrogen Sulfide and Carbon Dioxide in Aqueous Solutions of Triethanolamine. J. Chem. Eng. Data 1996, 41, 1181.
13. Kent, R. L.; Eisenberg, B. Better Data for Amine Treating. Hydrocarbon Process. 1976, 55 (2), 87.
14. Kim, J.-H.; Dobrogowska, C.; Hepler, L. G. Thermodynamics of Ionization of Aqueous Alkanolamines. Can. J. Chem. 1987, 65, 1726.
15. Leibush, A. G.; Shorina, E. D. Physico-Chemical Properties of Ethanolamines. Zh. Prik. Khim. 1947, 20, 69.
16. Li, Y.-G.; Mather, A. E. The Correlation and Prediction of the Solubility of Carbon Dioxide in a Mixed Alkanolamine Solution. Ind. Eng. Chem. Res. 1994, 33, 2006.
17. Lyudkovskaya, M. A.; Leibush, A. G. Solubility of Carbon Dioxide in Solutions of Ethanolamines under Pressure. Zh. Prik. Khim. 1949, 22, 558.
18. Maham, Y.; Teng, T. T.; Hepler, L. G.; Mather, A. E. Densities, Excess Molar Volumes and Partial Molar Volumes for Binary Mixtures of Water with Monoethanolamine, Diethanolamine and Triethanolamine from 25 to 80 °C . J. Soln. Chem. 1994, 23, 195.
19. Maryott, A. A.; Smith, E. R. Table of Dielectric Constants of Pure Liquids; NBS Circular 514; U.S. Government Printing Office: Washington, DC, 1951.
20. Mason, J. W.; Dodge, B. F. Equilibrium Absorption of Carbon Dioxide by Solutions of the Ethanolamines. Trans. AIChE 1936, 32, 27.
21. Pitzer, K. S. Thermodynamics of Electrolytes. I. Theoretical Basis and General Equations. J. Phys. Chem. 1973, 77, 268.
22. Pitzer, K. S.; Simonson, J. M. Thermodynamics of Multicomponent, Miscible, Ionic Systems: Theory and Equations. J. Phys. Chem. 1986, 90, 3005.
23. 2S in an Aqueous Solution of Methyldiethanolamine and Sulfolane. Ind. Eng. Chem. Res. 1995, 34, 2545.
24. Xu, S.; Otto, F. D.; Mather, A. E. Dissociation Constants of Some Alkanolamines. Can. J. Chem. 1993, 71, 1048.