Novel aggregation of fac(S)-[Rh(aet)3] by square-planar palladium(II): Crystal structure of spontaneously resolved RhIII3PdII2 pentanuclear complex [Pd{Pd(aet)}{Rh(aet)2}{Rh(aet)3}2]Br 4 (aet = 2-Aminoethanethiolate)

Chemistry Letters

Volumn , Issue 11, 1996, Pages 977-978

  Konno, Takumi ^a   Sasaki, Chieko ^a   Okamoto, Ken Ichi ^a  

^a UNIVERSITY OF TSUKUBA   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0030369018     PISSN: 03667022     EISSN: None     Source Type: Journal    
DOI: 10.1246/cl.1996.977     Document Type: Article

References (24)

1. D. H. Busch and D. C. Jicha, Inorg. Chem., 1, 884 (1962); G. R. Brubaker and B. E. Douglas, Inorg. Chem., 6, 1562 (1967); R. E. DeSimone, T. Ontko, L. Wardman, and E. L. Blinn, Inorg. Chem., 14, 1313 (1975); M. J. Heeg, E. L. Blinn, and E. Deutsch, Inorg. Chem., 24, 1118 (1985); D. W. Johnson and T. R. Brewer, Inorg. Chim. Acta, 151, 221 (1988); T. Konno, K. Okamoto, and J. Hidaka, Acta Crystallogra., Sect C, 49, 222 (1993).
2. D. H. Busch and D. C. Jicha, Inorg. Chem., 1, 884 (1962); G. R. Brubaker and B. E. Douglas, Inorg. Chem., 6, 1562 (1967); R. E. DeSimone, T. Ontko, L. Wardman, and E. L. Blinn, Inorg. Chem., 14, 1313 (1975); M. J. Heeg, E. L. Blinn, and E. Deutsch, Inorg. Chem., 24, 1118 (1985); D. W. Johnson and T. R. Brewer, Inorg. Chim. Acta, 151, 221 (1988); T. Konno, K. Okamoto, and J. Hidaka, Acta Crystallogra., Sect C, 49, 222 (1993).
3. D. H. Busch and D. C. Jicha, Inorg. Chem., 1, 884 (1962); G. R. Brubaker and B. E. Douglas, Inorg. Chem., 6, 1562 (1967); R. E. DeSimone, T. Ontko, L. Wardman, and E. L. Blinn, Inorg. Chem., 14, 1313 (1975); M. J. Heeg, E. L. Blinn, and E. Deutsch, Inorg. Chem., 24, 1118 (1985); D. W. Johnson and T. R. Brewer, Inorg. Chim. Acta, 151, 221 (1988); T. Konno, K. Okamoto, and J. Hidaka, Acta Crystallogra., Sect C, 49, 222 (1993).
4. D. H. Busch and D. C. Jicha, Inorg. Chem., 1, 884 (1962); G. R. Brubaker and B. E. Douglas, Inorg. Chem., 6, 1562 (1967); R. E. DeSimone, T. Ontko, L. Wardman, and E. L. Blinn, Inorg. Chem., 14, 1313 (1975); M. J. Heeg, E. L. Blinn, and E. Deutsch, Inorg. Chem., 24, 1118 (1985); D. W. Johnson and T. R. Brewer, Inorg. Chim. Acta, 151, 221 (1988); T. Konno, K. Okamoto, and J. Hidaka, Acta Crystallogra., Sect C, 49, 222 (1993).
5. D. H. Busch and D. C. Jicha, Inorg. Chem., 1, 884 (1962); G. R. Brubaker and B. E. Douglas, Inorg. Chem., 6, 1562 (1967); R. E. DeSimone, T. Ontko, L. Wardman, and E. L. Blinn, Inorg. Chem., 14, 1313 (1975); M. J. Heeg, E. L. Blinn, and E. Deutsch, Inorg. Chem., 24, 1118 (1985); D. W. Johnson and T. R. Brewer, Inorg. Chim. Acta, 151, 221 (1988); T. Konno, K. Okamoto, and J. Hidaka, Acta Crystallogra., Sect C, 49, 222 (1993).
6. D. H. Busch and D. C. Jicha, Inorg. Chem., 1, 884 (1962); G. R. Brubaker and B. E. Douglas, Inorg. Chem., 6, 1562 (1967); R. E. DeSimone, T. Ontko, L. Wardman, and E. L. Blinn, Inorg. Chem., 14, 1313 (1975); M. J. Heeg, E. L. Blinn, and E. Deutsch, Inorg. Chem., 24, 1118 (1985); D. W. Johnson and T. R. Brewer, Inorg. Chim. Acta, 151, 221 (1988); T. Konno, K. Okamoto, and J. Hidaka, Acta Crystallogra., Sect C, 49, 222 (1993).
7. T. Konno, S. Aizawa, K. Okamoto, and J. Hidaka, Bull. Chem. Soc. Jpn., 63, 792 (1990); T. Konno and K. Okamoto, Bull. Chem. Soc. Jpn., 68, 610 (1995).
8. T. Konno, S. Aizawa, K. Okamoto, and J. Hidaka, Bull. Chem. Soc. Jpn., 63, 792 (1990); T. Konno and K. Okamoto, Bull. Chem. Soc. Jpn., 68, 610 (1995).
9. T. Konno, K. Nakamura, K. Okamoto, and J. Hidaka, Bull. Chem. Soc. Jpn., 66, 2582 (1993).
10. K. Okamoto, T. Konno, Y. Kageyama, and J. Hidaka, Chem. Lett., 1992, 1105; K. Okamoto, K. Kageyama, and T. Konno, Bull. Chem. Soc. Jpn., 68, 2573 (1995).
11. K. Okamoto, T. Konno, Y. Kageyama, and J. Hidaka, Chem. Lett., 1992, 1105; K. Okamoto, K. Kageyama, and T. Konno, Bull. Chem. Soc. Jpn., 68, 2573 (1995).
12. T. Konno and K. Okamoto, presented at the 30th International Conference on Coordination Chemistry, Kyoto, 1994, Abstr., 196.
13. T. Konno, T. Nagashio, K. Okamoto, and J. Hidaka, Inorg. Chem., 31, 1160 (1992).
14. a) T. Konno, K. Okamoto, and J. Hidaka, Inorg. Chem., 30, 2253 (1991);
15. b) T. Konno, K. Okamoto, and J. Hidaka, Inorg. Chem., 33, 538 (1994).
16. K. Okamoto, T. Konno, and J. Hidaka, J. Chem. Soc., Dalton Trans., 1994, 533.
17. T. Konno, K. Okamoto, and J. Hidaka, Chem. Lett., 1990, 1043; T. Konno, K. Okamoto, and J. Hidaka, Bull. Chem. Soc. Jpn., 67, 101 (1994).
18. T. Konno, K. Okamoto, and J. Hidaka, Chem. Lett., 1990, 1043; T. Konno, K. Okamoto, and J. Hidaka, Bull. Chem. Soc. Jpn., 67, 101 (1994).
19. T. Konno, K. Okamoto, and J. Hidaka, Inorg. Chem., 31, 3875 (1992).
20. 2.
21. -3, R(Rw) = 0.039 (0.044) for 4138 reflections. Selected bond distances (Å) and angles (°): av. Pd1-S = 2.346(4), av. Pd2-S = 2.344(4), Pd-N41 = 2.08(1), av. Rh1-S = 2.313(4), av. Rh1-N = 2.13(1), av. Rh2-S = 2.311(4), av. Rh2-N = 2.13(1), Rh3-S23 = 2.378(3), Rh3-S31 = 2.300(4), RH3-S32 = 2.355(4), Rh3-S41 = 2.359(4), av. Rh3-N = 2.12(1), S12-Pd1-S13 = 80.2(1), S12-Pd1-S21 = 102.1(1), S13-Pd1-S31 = 84.9(1), S21-Pd1-S31 = 92.0(1), S11-Pd2-S22 = 86.5(1), S11-Pd2-N41 = 93.4(3), S22-Pd2-S41 = 93.4(1), S41-Pd2-N41 = 86.0(3), av. S-Rh1-S = 89.0(1), av. N-Rh1-N = 92.0(5), av. S-Rh2-S = 95.2(1), av. N-Rh2-N = 90.0(5), S31-Rh3-S41 = 93.0(1), S31-Rh3-S32 = 86.6(1), S32-Rh3-S41 = 96.9(1), S23-Rh3-N31 = 95.6(3), S23-Rh3-N32 = 82.1(3), N31-Rh3-N32 = 91.2(4).
22. It was found from this column chromatography that 1 was formed in a 95% yield.
23. Refinement in the enantiomeric parameters gave the values of R(Rw) = 0.052 (0.057), indicating that the enantiomer selected is correct with greater than 99.5% certainty (W. C. Hamilton, Acta Crystallogra, 18, 502 (1965)).
24. 2.