Diarylethene modified electrode device. Photoswitching of the electron transfer of a diarylethene with long alkyl chains embedded in a lipid cast film on an electrode

Chemistry Letters

Volumn , Issue 9, 1996, Pages 817-818

  Nakashima, Naotoshi ^b   Deguchi, Yonekazu ^b   Nakanishi, Takashi ^b   Uchida, Kingo ^a   Irie, Masahiro ^a  

^a KYUSHU UNIVERSITY   (Japan)

^b NAGASAKI UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0030355819     PISSN: 03667022     EISSN: None     Source Type: Journal    
DOI: 10.1246/cl.1996.817     Document Type: Article

References (10)

1. M. Irie, O. Miyataka, K. Uchida, and T. Eriguchi, J. Am. Chem. Soc., 116, 9896 (1994).
2. M. Irie, K. Sakemura, M. Okinaka, and K. Uchida, J. Org. Chem., 60, 8305 (1995).
3. S. L. Gilat, S. L. Kawai, and J.-M, Lehn, J. Chem. Soc., Chem. Commun., 1993, 1439.
4. S. L. Gilat, S. H. Kawai, and J.-M. Lehn, Chem. Eur. J., 1, 275 (1995).
5. 2O: C, 58.10; H, 7.44; N, 2.38%.
6. The light source was a 500 W Xenon lamp (Ushio UI-501 C). UV- and visible light were selected by passing the light through a visible absorbing filter (Toshiba R-60) or a UV-absorbing filter (Toshiba UV-D33S), respectively.
7. Pyrolytic graphite( Union Carbide Co.) was sheathed in an epoxy resin (Torr Seal, Barian Co.) to expose a basal-plane and connected to a glass tube. The electrode surface was polished with a 600-grit SiC paper, washed with water and then sonicated in water.
8. - was determined by differential scanning calorimetry.
9. Repeated scan caused the decrease in the redox current.
10. N. Nakashima, K. Masuyama, M. Mochida, M. Kunitake, and O. Manabe, J. Electroanal. Chem., 319, 355 (1991).