A comparison of the reactivity and efficiency of ozone, chlorine dioxide, dimethyldioxirane and hydrogen peroxide with residual kraft lignin

Holzforschung

Volumn 50, Issue 2, 1996, Pages 175-182

  Sun, Yujun ^a   Argyropoulos, Dimitris S ^a  

^a MCGILL UNIVERSITY   (Canada)

Author keywords

Alkaline hydrogen peroxide; Bleaching; Chlorine dioxide; Delignification; Dimethyldioxirane; Kraft lignins; Kraft pulps; Nuclear magnetic resonance (NMR); Ozone; Phenols; Phosphorus pre bleaching; Softwood; Spectroscopy Structures

Indexed keywords

PICEA MARIANA;

BLEACHING; LIGNIN; MANUFACTURE; OZONE; PULP; SULFATE PULP;

CHEMICAL REACTIVITY; CHLORINE DIOXIDE; HYDROGEN PEROXIDES;

KRAFT PULP;

EID: 0030352160     PISSN: 00183830     EISSN: None     Source Type: Journal    
DOI: 10.1515/hfsg.1996.50.2.175     Document Type: Review

References (28)

1. Argyropoulos, D.S., Y. Sun, R.M. Berry and J. Bouchard. 1994. Reactions of dimethyldioxirane with lignin model compounds. 1994 International Pulp Bleaching Conference, Vancouver, B.C., June 13-16, Posters vol., pp. 83-91.
2. Argyropoulos, D.S. 1994. Quantitative phosphorus-31 NMR analysis of lignins; A new tool for the Lignin Chemist. J. Wood Chem. Technol. 14 (1): 45-63.
3. Balousek, P.J., T.J. McDonough, R.D. McHelvey and D.C. Johnson. 1981. The effects of ozone upon a lignin model containing the β-aryl ether linkage. Svensk Papperstidn. 9: R49-54.
4. Brage, C., T. Eriksson and J. Gierer. 1991. Reactions of chlorine dioxide with lignins in unbleached pulps. Part I. Holzforschung 45: 23-30.
5. Eriksson, T. and J. Gierer. 1985. Studies on the ozonation of structural elements in residual kraft lignins. J. Wood Chem. Technol. 5 (1): 53-84.
6. Gellerstedt, G., K. Gustafsson and E. Lindfors. 1986. Structural changes in lignin during oxygen bleaching. Nordic Pulp and Paper Res. J. 3: 14-17.
7. Gellerstedt, G., E. L. Lindfors, M. Pettersson, E. Sjoholm and D. Robert. 1991. Chemical aspects on chlorine dioxide as a bleaching agent for chemical pulps. 6th Int. Symposium on Wood & Pulping Chemistry, Appita Proceedings, Melbourne, pp. 331-336.
8. Gellerstedt, G. and I. Pettersson. 1982. Chemical aspects of hydrogen peroxide bleaching. Part II. The bleaching of kraft pulps. J. Wood Chem. Technol. 2 (3): 150-231.
9. Gellerstedt, G. and D. Robert. 1989. The structural modification of lignin in bleaching. Int. Symposium on Wood and Pulping Chemistry, Tappi Press, Raleigh, N.C., pp. 211-215.
10. Germgard, U. and S. Nordén. 1994. OZP-bleaching of kraft pulps to full brightness. Int. Pulp Bleaching Conference, Vancouver, B.C., pp. 53-58.
11. Gierer, J. 1987. Mechanisms of bleaching with oxygen-containing Species. Int. Symposium on Wood and Pulping Chemistry, Tappi Press, Paris, pp. 279-288.
12. Gierer, J. and F. Imsgard. 1977. The reactions of lignins with oxygen and hydrogen peroxide in alkaline media. Svensk Papperstidn. 80 (16): 510-517
13. Gierer, J. 1982. Chemistry of delignification. A general concept. Part II. Holzforschung 36 (1): 55-64.
14. Granata, A. and D.S. Argyropoulos. 1995. 2-Chloro-4,4,5,5-Tetramethyl-1,3,2-Dioxaphospholane a reagent for the accurate determination of the uncondensed and condensed phenolic moieties in lignins. J. Agricultural and Food Chemistry. Volume 43, (6).
15. Hosoya, S. 1992. Nonchlorine bleaching in view of structures and reactions of residual lignin in kraft pulp. Japan Tappi J. 46 (11): 2-19.
16. Jiang, Z. and D.S. Argyropoulos. 1994. The stereoselective degradation of argyl-glycerol beta-aryl ethers during kraft pulping. J.Pulp Paper Sci. 20 (7): 183-188.
17. 31P NMR chemical shifts with substituent effects of phenols. Magnetic Resonance in Chemistry 33: 375-382.
18. Kanfko, H., S. Hosoya and J. Nakano. 1981. Degradation of lignin with ozone. Mokuzai Gakkaishi 27 (9): 678-683.
19. Lee, C.-L., H. Hunt and R. W. Murray. 1992. A novel non-chlorine agent for chemical pulp bleaching. In: Proceedings, Tappi Pulping Conf., Tappi Press 3, p. 1237.
20. Lee, C.-L. 1991. Bleaching of lignocellulosic material with dioxirane. PCT Patent Application, Int. Publication No. W091/12369, Aug. 22.
21. Matsumoto, Y., N. Habu, K. Minami, A. Isizu and J. Nakano. 1989. Quantitative estimation of side-chain structure of lignin by ozonation. Wood and Pulping Chemistry, Tappi Proceedings, pp. 365-368.
22. McDonough, T.J., A. Marquis and A.J. Ragauskas. 1994. Totally chlorine free bleaching with dimethyldioxirane. Int. Pulp Bleaching Conference, Tappi Press, Vancouver, B.C., pp. 47-52.
23. Pepper, J.M., P.E.T. Baylis and E. Alder. 1959. The isolation and properties of lignin obtained by the acidolysis of spruce and aspen wood in dioxane-water medium. Can. J. Chem. 37: 1241
24. Ragauskas, A.J. 1993. Investigation of dimethyldioxirane as a bleaching agent. Tappi 76 (7): 87-90.
25. Singh, A. 1990. Delignification mechanisms using oxygen and hydrogen peroxide. Oxygen Delignification Symposium, Tappi Proceedings, pp. 53-59.
26. Stromberg, B. and R. Szopinski. 1994. Pressurized hydrogen peroxide bleaching for improved TCF bleaching. Int. Pulp Bleaching Conference, Tappi Press, Vancouver, B.C. pp. 199-209.
27. Strumila, G. B. and W. H. Rapson, 1976. Chlorine dioxide oxidation of lignin model phenols. Canadian Wood Chemistry Symp., Tappi Press, Mont Gabriel, pp. 119-126.
28. Sun, Y. and D.S. Argyropoulos. 1995. Fundamentals of high pressure oxygen and low pressure oxygen-peroxide (EOP) delignification of softwood and hardwood kraft pulps: A comparison. J. Pulp Paper Sci. 21 (6), J185-J190.