Stereoselective route to the highly oxidated sidechain moiety of terpentecin and related antibiotics

Chemistry Letters

Volumn , Issue 11, 1996, Pages 931-932

  Takao, Ken Ichi ^a   Aiba, Yasuyuki ^b   Ito, Hisanaka ^b   Kobayashi, Susumu ^a  

^a TOKYO UNIVERSITY OF SCIENCE   (Japan)

^b SAGAMI CHEMICAL RESEARCH CENTER   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0030351673     PISSN: 03667022     EISSN: None     Source Type: Journal    
DOI: 10.1246/cl.1996.931     Document Type: Article

References (20)

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15. 2: C, 73.95; H, 5.52; N, 9.58%.
16. 1,2=3.9 Hz) in NOESY spectrum.
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20. When the reaction was carried out with other conditions such as (NaHMDS or LiHMDS, THF, -78 °C), and (DBU, toluene, rt), a mixture of 12 and 10α was obtained (12:10α = ca. 1:1 - 1:2).