A novel trinuclear platinum(II) complex with C, N, S donor ligands containing ferrocenyl groups

Chemistry Letters

Volumn , Issue 11, 1996, Pages 921-922

  Nagasawa, Isoroku ^a   Kawamoto, Tatsuya ^a   Kuma, Hiro ^a   Kushi, Yoshihiko ^a  

^a OSAKA UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0030351006     PISSN: 03667022     EISSN: None     Source Type: Journal    
DOI: 10.1246/cl.1996.921     Document Type: Article

References (13)

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2. L. F. Lindoy and S. E. Livingstone, Inorg. Chim. Acta, 1, 365 (1967); L. F. Lindoy and S. E. Livingstone, Inorg. Chem., 7, 1149 (1968); A. P. Koley, R. Nirmala, L. S. Prasad, S. Ghosh, and P. T. Manoharan, Inorg. Chem., 31, 1764 (1992).
3. L. F. Lindoy and S. E. Livingstone, Inorg. Chim. Acta, 1, 365 (1967); L. F. Lindoy and S. E. Livingstone, Inorg. Chem., 7, 1149 (1968); A. P. Koley, R. Nirmala, L. S. Prasad, S. Ghosh, and P. T. Manoharan, Inorg. Chem., 31, 1764 (1992).
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7. 3, space group P2,/n, Z = 4, F(000) = 3136, Μο-Κα radiation, Graphite monochromator, room temperature. All crystallographic measurements were made using a MAC science MXC3 diffractometer. Empirical absorption corrections (ψ-scan) were applied. Lattice parameters were determined by application of the automatic diffractometer indexing routine to the positions of 22 reflections. Data were measured in the range 3≤2θ≤50° in the ω-2θ scan with three check reflections being measured every 100 data. The structure was solved by direct methods(SIR92) and refined by full-matrix least squares analysis using 2596 unique reflections to final R factor = 0.0705, Rw = 0.0902. Refinement was anisotropic only for the platinum, iron, chlorine, and sulfur atoms.
8. J. -H. Chou and M. G. Kanatzidis, Inorg. Chem., 33, 5372 (1994). (chair form); M. Capdevila, W. Clegg, P. Gonzalez-Duarte, and I. Mira, J. Chem. Soc., Dalton Trans., 1992, 173. (twist-boat form).
9. J. -H. Chou and M. G. Kanatzidis, Inorg. Chem., 33, 5372 (1994). (chair form); M. Capdevila, W. Clegg, P. Gonzalez-Duarte, and I. Mira, J. Chem. Soc., Dalton Trans., 1992, 173. (twist-boat form).
10. S. Chattopadhyay, C. Sinha, P. Basu, and A. Chakravorty, J. Organomet. Chem., 414, 421 (1991); C. Arien, M. Pfeffer, O. Bars, and D. Grandjeam, J. Chem. Soc., Dalton Trans., 1983, 1535; W. de Greaf, J. Boersma, W. J. J. Smeets, A. L. Spek, and G. von Koten, Organometallics, 8, 2907 (1989).
11. S. Chattopadhyay, C. Sinha, P. Basu, and A. Chakravorty, J. Organomet. Chem., 414, 421 (1991); C. Arien, M. Pfeffer, O. Bars, and D. Grandjeam, J. Chem. Soc., Dalton Trans., 1983, 1535; W. de Greaf, J. Boersma, W. J. J. Smeets, A. L. Spek, and G. von Koten, Organometallics, 8, 2907 (1989).
12. S. Chattopadhyay, C. Sinha, P. Basu, and A. Chakravorty, J. Organomet. Chem., 414, 421 (1991); C. Arien, M. Pfeffer, O. Bars, and D. Grandjeam, J. Chem. Soc., Dalton Trans., 1983, 1535; W. de Greaf, J. Boersma, W. J. J. Smeets, A. L. Spek, and G. von Koten, Organometallics, 8, 2907 (1989).
13. 3) δ 4.09, 4.11, 4.21 (s, 15H, free-Cp), 4.35-4.50 (m, 9H, substituted-Cp), 7.10-7.90 (m, 12H, phenyl ring), 8.63, 8.67, 8.74 (s, 3H, N=CH).