A study of nighttime nitrogen oxide oxidation in a large reaction chamber - The fate of NO2, N2O5, HNO3, and O3 at different humidities

Atmospheric Environment

Volumn 30, Issue 23, 1996, Pages 4007-4020

  Mentel, Th F ^a   Bleilebens, D ^a   Wahner, A ^a  

^a FORSCHUNGSZENTRUM JÜLICH   (Germany)

Author keywords

Dinitrogen pentoxide; Kinetic study; Nitrate radical; Rate coefficients; Smog chamber

Indexed keywords

DINITROGEN PENTOXIDE; NITROGEN OXIDE; OZONE;

ABSORPTION SPECTROSCOPY; AMBIENT AIR; ARTICLE; CALCULATION; CHEMICAL REACTION KINETICS; CHEMOLUMINESCENCE; HUMIDITY; OXIDATION; PHOTOCHEMISTRY; PRIORITY JOURNAL; SMOG;

DINITROGEN PENTOXIDE; DIURNAL CHANGE; HUMIDITY; KINETIC STUDY; NITRATE RADICAL; NITROGEN OXIDE; OXIDATION;

ABSORPTION SPECTROSCOPY; ATMOSPHERIC HUMIDITY; CHEMILUMINESCENCE; DECOMPOSITION; FOURIER TRANSFORM INFRARED SPECTROSCOPY; MATHEMATICAL MODELS; NITRIC ACID; NITROGEN OXIDES; OXIDATION; OZONE; REACTION KINETICS; TROPOSPHERE;

DINITROGEN PENTOXIDE; MIXING RATIO; RATE COEFFICIENTS; REACTION CHAMBER; UNIMOLECULAR DECOMPOSITION; VOLUME RATIO;

ATMOSPHERIC CHEMISTRY;

EID: 0030303632     PISSN: 13522310     EISSN: None     Source Type: Journal    
DOI: 10.1016/1352-2310(96)00117-3     Document Type: Article

References (42)

1. 3 radical with organic compounds, J. phys. chem. Ref. Data 20, 459-507.
2. Atkinson R., Tuazon E. C., MacLeod H., Aschmann S. M. and Winer A. M. (1986) The gas-phase reaction of chlorine nitrate with water vapor. Geophys. Res. Lett. 13, 117-120.
3. Atkinson R., Baulch D. L., Cox R. A., Hampson Jr. R. F., Kerr J. A. and Troe J. (1992) Evaluated kinetic and photochemical data for atmospheric chemistry. Supplement IV. J. phys. chem. Ref. Data 21, 1125-1568.
4. Camy-Peyret C., Flaud J.-M., Lechuga-Fossat L., Laverdet G. and Le Bras G. (1987) The absorption of gaseous dinitrogen pentoxide in the 8.1 and 5.7 μm spectral regions. Chem. Phys. Lett. 139, 345-349.
5. 5. Chem. Phys. Lett. 148, 358-363.
6. 2 from 273 to 313 K. J. geophys. Res. 95, 20,531-20,537.
7. 3 radical decomposition and scavenging in the troposphere. J. geophys. Res. 95, 13,963-13,969.
8. DeMore W. B., Sander S. P., Golden D. M., Hampson R. F., Kurylo M. J., Howard C. J., Ravishankara A. R., Kolb C. E. and Molina M. J. (1994) Chemical kinetics and photochemical data for use in stratospheric modeling. JPL Publication 94-26.
9. Giver L. P., Valero F. P. J. and Goorvitch D. (1984) Nitric acid band intensities and band model parameters from 610 to 1760cm-1. J. Opt. Soc. Am. B5, 715-722.
10. 3 vapor. Appl. Opt. 10, 65-73.
11. 3 system. J. phys. Chem. 82, 254-268.
12. Hanst P. L. and Hanst S. T. (1992) Infrared spectra for quantitative analysis of gases. Infrared Analysis, Potomac.
13. 3. J. phys. Chem. 91, 1565-1568.
14. 2 rate constant by infrared diode laser and Fourier transform spectroscopy, J. phys. Chem. 93, 5458-5461.
15. Johnston H. S. (1951) Four mechanisms involving nitrogen pentoxide. J. Am. Chem. Soc. 73, 4542-4546.
16. 3 kinetics. J. geophys. Res. 91, 5159-5172.
17. Kaiser E. W. and Wu C. H. (1977) A kinetic study of the gas-phase formation and decomposition reactions of nitrous acid. J. phys. Chem. 81, 1701-1706.
18. Kolb C. E., Jayne J. T., Worsnop D. R., Molina M. J., Meads R. F. and Viggiano A. A. (1994) Gas-phase reaction of sulfur trioxide with water. J. Am. Chem. Soc. 116, 10,314-10,315.
19. 5. Appl. Opt. 19, 744-748.
20. Mallard W. G., Westley F., Herron J. T. and Hampson R. F. (1994) NIST Chemical Kinetics Database, Version 6.0. NIST Standard Reference Data, Gaithersburg, MD.
21. 4. Appl. Opt. 24, 3426-3427.
22. Mentel Th. F. and Wahner A. (1994) A large aerosol chamber for investigating heterogeneous chemistry of the atmosphere. Physico-chemical Behaviour of Atmospheric Pollutants (edited by Angeletti G. and Restelli G.), Proc. Sixth European Symposium in Varese (Italy), 18-22 October 1993, pp. 805-810 Report EUR 15609/2, European Commission, Luxembourg.
23. Mentel Th. F. and Wahner A. (1996) A large reaction chamber for nighttime atmospheric chemistry: design and characteristics of the chamber. Jül-Report 3196.
24. 2O: importance of the second water molecule. J. Am. Chem. Soc. 116, 10,316-10,317.
25. 5 on aqueous aerosols. J. geophys. Res. 93, 15,889-15,896.
26. Newnham D., Ballard J. and Page M. (1993) Infrared absorbance cross-sections for dinitrogen pentoxide vapour. J. Quant. Spectrosc. Radiat. Transfer 50, 571-577.
27. 3. Geophys. Res. Lett. 5, 675-678.
28. 3 in the troposphere. Geophys. Res. Lett. 7, 125-128.
29. 3 line positions and line intensities. Mol. Phys. 67, 249-270.
30. Platt U. (1986) The origin of nitrous and nitric acid in the atmosphere. In Chemistry of Multiphase Atmospheric Systems (edited by Jaeschke W.), pp. 299-319. Springer, Berlin.
31. 3. J. geophys. Res. 86, 11,965-11,970.
32. Platt U., Winer A. M., Biermann H. W., Atkinson R. and Pitts J. N. (1984) Measurement of nitrate radical concentrations in continental air. Envir. Sci. Technol. 18, 365-369.
33. Pugh L. A. and Rao K. N. (1976) Intensities from infrared spectra. In Molecular Spectroscopy: Modern Research (edited by Rao K. N.), Vol. 2, Chap. 4, pp. 165-227. Academic Press, New York.
34. Russell A. G., Cass G. R. and Seinfeld J. H. (1986) On some aspects of nighttime atmospheric chemistry. Envir. Sci. Technol. 20, 1167-1172.
35. 5 at high temperatures. J. Am. Chem. Soc. 80, 1841-1853.
36. Slanina Z. and Crifo J.-F. (1991) A computational evaluation of the gas-phase water dimerisation equilibrium constant in the low temperature region with particular attention to the interpretation of Giotto and Vega flyby observations of the Coma of Comet Halley. Thermochim. Acta 181, 109-118.
37. Smith M. A. H., Rinsland C. P., Fridovich B. and Rao K. N. (1985) Intensities and collision broadening parameters from infrared spectra. In Molecular Spectroscopy: Modern Research (edited by Rao K. N.), Vol. 2, Chap. 3, pp. 111-249. Academic Press, New York.
38. 3 and its reaction with NO. Int. J. Chem. Kinet. 20, 857-866.
39. Sverdrup G. M., Spicer C. W. and Ward G. F. (1987) Investigation of the gas-phase reaction of dinitrogen pentoxide with water vapor. Int. J. Chem. Kinet. 19, 191-205.
40. 5 with water vapor. Geophys. Res. Lett. 10, 953-956.
41. 2 in the range from 296 to 332 K. J. phys. Chem. 96, 7640-7645.
42. Wayne R. P., Barnes I., Biggs P., Burrows J. P., Canosa-Mas C. E., Hjorth J., Le Bras G., Moortgat G. K., Perner D., Poulet G., Restelli G. and Sidebottom H. (1990) The nitrate radical: physics, chemistry and the atmosphere. Air pollution research report 31, Commission of European Communities.