Ferriferous and vanadiferous kaolinites from the hydrothermal alteration halo of the cigar lake uranium deposit (Canada)

Clay Minerals

Volumn 31, Issue 3, 1996, Pages 291-299

  Mosser, C ^a   Boudeulle, M ^b   Weber, F ^a   Pacquet, A ^c  

^a UMR 7063   (France)

^b UNIVERSITÉ LYON 1   (France)

^c Groupe des Sciences de la Terre   (France)

Author keywords

[No Author keywords available]

Indexed keywords

CRYSTAL GROWTH; CRYSTAL ORIENTATION; ELECTRON SPIN RESONANCE SPECTROSCOPY; IRON; SCANNING ELECTRON MICROSCOPY; TRANSMISSION ELECTRON MICROSCOPY; URANIUM DEPOSITS; VANADIUM; X RAY CRYSTALLOGRAPHY; X RAY DIFFRACTION ANALYSIS;

ANTERIOR PHYLLOSILICATES; ELECTRON DISPERSIVE X RAY SPECTROSCOPY; FERRIFEROUS KAOLINITES; HYDROTHERMAL ALTERATION HALO; TITANOMAGNETITES; VANADIFEROUS KAOLINITES;

CLAY MINERALS;

HYDROTHERMAL ALTERATION; IRON; KAOLINITE; VANADIUM;

CANADA, SASKATCHEWAN, CIGAR LAKE;

EID: 0030300938     PISSN: 00098558     EISSN: None     Source Type: Journal    
DOI: 10.1180/claymin.1996.031.3.01     Document Type: Article

References (33)

1. ANGEL B.R. & HALL P.L. (1972) Electron spin resonance studies or kaolins. Proc.: Int. Clay Conf. Madrid, 47-60.
2. ANGEL B.R., JONES J.P.E. & HALL P.L. (1974) Electron spin resonance studies of doped synthetic kaolinitcs. Clay Miner. 10, 247-255.
3. 3+ ions. Clays Clay Miner. 25, 381-383.
4. BRUNETON P. (1987) Geology of the Cigar Lake uranium deposit (Saskatchewan, Canada). Economic Minerals of Saskatchewan, Spec. publ. 8, 99-119.
5. COTTON F.A. & WILKINSON G. (1986) Basic Inorganic Chemistry. John Wiley & Son, Chichester and New York.
6. 57Fe doped kaolin: Mössbauer and electron paramagnetic resonance studies. Clay Miner. 15, 429-444.
7. CUTTLER A.H. (1981) Further studies of a ferrous iron doped synthetic kaolin : dosimetry of X-ray induced defects. Clay Miner. 16, 69-80.
8. DRITS V.A., WEBER F., SALYN A.L. & TSIPURSKY I. (1993) X-ray identification of one-layer illite varieties: application to the study of illites around uranium deposits of Canada. Clays Clay Miner. 41, 389-398.
9. FOUQUES J.P., FONLER M., KNIPPING H.D. & SCHIMANN K. (1986) Le gisement d'uranium de Cigar Lake: découverte et caractéristiques générales. Can. Min. Metall. Bull. 79-886, 70-82.
10. 3+ EPR spectra in kaolinite. Phys. Chem. Min. 20, 242-247.
11. GEHRING A.U., FRY I.V., LUSTER J. & SPOSTRO G. (1993) The chemical form of vanadium (IV) in kaolinite. Clays Clay Miner. 41, 662-667.
12. GRAHAM W.R.M. (1987) Analysis of metal species in petroleum and sand using the electron paramagnetic resonance and Fourier transform infrared techniques. ACS Symp. Ser. 344 (Met. complexes Fossil Fuels), 358-367.
13. HALL P.L. (1980) The application of electron spin resonance spectroscopy to studies of clay minerals: I. Isomorphous substitutions and external surface properties. Clay Miner. 15, 321-335.
14. HALL P.L., ANGEL B.R. & BRAVEN J. (1974) Electron spin resonance and related studies of lignite and ball clay from south Devon, England. Chem. Geol 13, 97-113.
15. HERBILLON A.J., MESTDAGH M.M., VIELVOYE L. & DEROUANE E.G. (1976) Iron in kaolinite with special reference to kaolinite from tropical soil. Clay Miner. 11, 201-220.
16. JAIN V.K., SETH V.P. & MALHORTA R.K. (1984) Electron paramagnetic resonance of vanadyl ion impurities in crystalline solids. J. Phys. Chem. Solids, 45, 529-545.
17. JONES J.P., ANGEL B.R. & HALL P.L. (1974) Electron spin resonance studies of doped synthetic kaolinite. Clay Miner. 10, 257-269.
18. 2+ on hydrated smectite surfaces. Clays Clay Miner. 27, 91-96.
19. 3+ and other transition metal ions. Clay Miner. 10, 313-345.
20. MESTDAGH M.M., VIELVOYE L. & HERHILLON A. (1980) Iron in kaotinite: II. The relationship between kaolinite crystallinity and iron content. Clay Miner. 15, 1-13.
21. MESTDAGH M., HERBILLON A., RODRIQUE L. & ROUXHET P. G. (1982) Evaluation du rôle du fer structural sur la cristallinité des kaolinites. Bull. Minéral. 105, 457-466.
22. MONSEF-MIRZAI P. & MCWHINNIE W.R. (1982) Spectroscopic studies of metal ions sorbed onto kaolinite. Inorg. Chim. Acta, 58, 142-148.
23. MULLER J.P. & CALLAS G. (1989) Genetic significance of paramagnetic centers in kaolinites. Pp. 261-289 in: Kaolin Genesis and Utilization (H.H. Murray, W.M. Bundy & C.C. Harvey, editors). The Keller 90 Kaolin Symposium, The Clay Minerals Society, Colorado.
24. MULLER J.P. & CALLAS G. (1993) Tracing kaolinites through their defect centers: kaolinite paragenesis in a laterite (Cameroon). Econ, Geol. 84, 694-707.
25. MULLER J.P., CLOZEL B., ILDEFONSE P. & CALLAS G. (1992) Radiation-induced defects in kaolinites: indirect assessment of radionuclide migration in the geosphere. Appl. Geochem. Suppl. Issue, 1, 205-216.
26. MULLER J.P., ILDEFONSE P. & CALLAS G. (1990) Paramagnetic defect centers in hydrothermal kaolinite from an altered tuff in the Nopal uranium deposit, Chihuahua, Mexico. Clays Clay Miner. 38, 600-608.
27. MULLER J.P., MANCEAU A., CALLAS G., ALLARD T., ILDEFONSE P. & HAZEMANN J.L. (1995) Crystal chemistry of kaolinite an Fe-Mn oxide: relation with formation conditions of low temperature systems. Am. J. Sci. 295, 1115-1155.
28. 3+ dans les smectites. Bull. Groupe franç. Argiles XXVII, 153-165.
29. PACQUET A. & WEBER F. (1993) Pétrographie et minéralogie des halos d'altération autour du gisement de Cigar Lake et leurs relations avec les minéralisations. Can. J. Earth Sci. 30, 674-688.
30. PHILIPPE S., LANCELOT J.R., CLAUER N. & PATQUET A. (1993) Formation and evolution of the Cigar Lake uranium deposit based on U-Pb and K-Ar isotope systematics. Rev. Can. Sci. Terre, 30, 720-730.
31. PINNAVAIA T.J., HALL P.L., CADY S.S. & MORTLAND M.M. (1974) Aromatic radical cation formation on the intracrystal surfaces of transition metal layer lattice silicates. J. Phys. Chem. 78, 994-999.
32. SAMUEL J. & ROUAULT R. (1983) Les méthodes d'analyses des matériaux géologiques pratiquées au laboratoire d'analyses spectrochimiques. Nouvelle éd. 1990. Notes techniques de l'Institut de Géologie, Université Louis Pasteur Strasbourg, 16, 46 pp.
33. SYMONS M. (1978) Chemical and Biochemical Aspects of Electron-spin Resonance Spectroscopy. Van Nostrand Reinhold Company Publ.