Kinetics of the N2 + O → NO + N reaction under thermodynamic nonequilibrium

Journal of Thermophysics and Heat Transfer

Volumn 10, Issue 1, 1996, Pages 148-154

  Bose, Deepak ^a,b   Candler, Graham V ^a,b  

^a UNIVERSITY OF MINNESOTA   (United States)

^b Dept of Aerosp Eng and Mechanics ^*

Author keywords

[No Author keywords available]

Indexed keywords

COMBUSTION; COMPUTER SIMULATION; FLOW OF FLUIDS; HIGH TEMPERATURE EFFECTS; MATHEMATICAL MODELS; MOLECULAR VIBRATIONS; NITROGEN OXIDES; REACTION KINETICS;

REACTANT ENERGY MODES; ROTATIONAL TEMPERATURE; THERMODYNAMIC NONEQUILIBRIUM; ZELDOVICH REACTION;

THERMODYNAMICS;

EID: 0030300909     PISSN: 08878722     EISSN: 15336808     Source Type: Journal    
DOI: 10.2514/3.765     Document Type: Article

References (38)

1. Park, C., Thermal Design of Aeroassisted Orbital Transfer Vehicles, edited by H. F. Nelson, Vol. 96, Progress in Astronautics and Aeronautics, AIAA, New York, 1985, pp. 511-537.
2. Jaffe, R. L., Thermophysical Aspects of Re-Entry Flows, edited by J. N. Moss and C. D. Scott, Vol. 96, Progress in Astronautics and Aeronautics, AIAA, New York, 1986, pp. 123-151.
3. Levin, D. A., Candler, G. V., Collins, R. J., Erdman, P. W., Zipf, E. C., and Howlett, C., "Examination of Theory for Bow Shock Ultraviolet Rocket Experiments - I," Journal of Thermophysics and Heat Transfer, Vol. 8, No. 3, 1994, pp. 447-452.
4. Levin, D. A., Braunstein, M., Candler, G. V., Collins, R. J., and Smith, G., "Examination of Theory for Bow Shock Ultraviolet Rocket Experiments - II," Journal of Thermophysics and Heat Transfer, Vol. 8, No. 3, 1994, pp. 453-459.
5. Levin, D. A., Candler, G. V., Collins, R. J., Erdman, P. W., Zipf, E. C., Espy, P., and Howlett, C., "Comparison of Theory with Experiment for the Bow Shock Ultraviolet Rocket Flight," Journal of Thermophysics and Heat Transfer, Vol. 7, No. 1, 1993, pp. 30-36.
6. Erdman, P. W., Zipf, E. C., Espy, P., Howlett, C., Levin, D. A., Collins, R. J., and Candler, G. V., "Measurements of Ultraviolet Radiation from a 5 km/s Bow Shock," Journal of Thermophysics and Heat Transfer, Vol. 8, No. 3, 1994, pp. 441-446.
7. Boyd, I. D., Candler, G. V., and Levin, D. A., "Dissociation Modeling in Low Density Hypersonic Flows of Air," Physics of Fluids, Vol. 7, No. 7, 1995, pp. 1757-1763.
8. Zeldovich, Ya. B., Sadovnikov, P. Ya., and Frank-Kamenetskii, D. A., Oxidation of Nitrogen in Combustion, Academy of Sciences of USSR, Inst. of Chemical Physics, Moscow-Leningrad (translated by M. Shelef), 1947.
9. Macheret, S. O., and Rich, J. W., "Nonequilibrium Dissociation Rates Behind Strong Shock Waves: Classical Model," Chemical Physics, Vol. 174, 1993, pp. 25-43.
10. Macheret, S. O., Fridman, A. A., Adarnovich, I. V., Rich, J. W., and Treanor, C. E., "Mechanisms of Nonequilibrium Dissociation of Diatomic Molecules," AIAA Paper 94-1984, June 1994.
11. Park, C., Nonequilibrium Hypersonic Aerothermodynamics, Wiley, New York, 1990.
12. Park, C., "Assessment of Two-Temperature Kinetic Model for Dissociating and Weakly Ionizing Nitrogen," Journal of Thermophysics and Heat Transfer, Vol. 2, No. 1, 1988, pp. 8-16.
13. Hammerling, P., Teare, J. D., and Kivel, B., "Theory of Radiation from Luminous Shock Waves in Nitrogen," Physics of Fluids, Vol. 2, No. 4, 1959, pp. 422-426.
14. Treanor, C. E., and Marrone, P. V., "Effect of Dissociation on the Rate of Vibrational Relaxation," Physics of Fluids, Vol. 5, No. 9, 1962, pp. 1022-1026.
15. Truhlar, D. G., and Muckerman, J. T., "Reactive Scattering Cross Sections III: Quasiclassical and Semiclassical Methods," Atom Molecule Collision Theory, edited by R. B. Bernstein, Plenum, New York, 1979, pp. 505-561.
16. Porter, R. N., and Raff, L. M., "Classical Trajectory Methods in Molecular Collisions," Dynamics of Molecular Collisions Part B, edited by W. H. Miller, Plenum, New York, 1976, pp. 1-50.
17. Karplus, M., Porter, R. N., and Sharma, R. D., "Exchange Reactions with Activation Energy," Journal of Chemical Physics, Vol. 43, No. 9, 1965, pp. 3259-3287.
18. 2 → NO + O," Journal of Chemical Physics, Vol. 86, No. 12, 1987, pp. 6946-6956.
19. Walch, S. P., and Jaffe, R. L., American Inst. of Physics Document PAPS JCPSA-86-6946-10.
20. 2A′ Ground Potential Energy Surface Employing an Analytical Sorbie-Murrell Potential," Chemical Physics, Vol. 172, 1993, pp. 99-115.
21. 3A″ ground potential energy surface. II. Analytical potential energy surface and preliminary quasiclassical trajectory calculations," Journal of Chemical Physics, Vol. 99, No. 3, 1993, pp. 1719-1733.
22. 3A″ Ground Potential Energy Surface. I. Analytical Potential Energy Surface and Preliminary Quasiclassical Trajectory Calculations," Journal of Chemical Physics, Vol. 97, No. 8, 1992, pp. 5542-5553.
23. Donovan, R. J., and Hussain, D., "Recent Advances in the Chemistry of Electronically Excited Atoms," Chemical Reviews, Vol. 70, No. 4, 1970, pp. 489-516.
24. 2O," Journal of Chemical Physics, Vol. 80, No. 9, 1984, pp. 4290-4316.
25. Sorbie, K. S., and Murrell, J. N., "Analytical Potentials for Triatomic Molecules from Spectroscopic Data," Molecular Physics, Vol. 29, No. 5, 1975, pp. 1387-1407.
26. Murrell, J. N., Carter, S., Farantos, S. C., Huxley, P., and Varandas, A. C. J., Molecular Potential Energy Functions, Wiley, London, 1984.
27. Hirst, D. M., Potential Energy Surfaces: Molecular Structure and Reaction Dynamics, Taylor and Francis, London, 1985.
28. Burden, R. L., and Faires, J. D., Numerical Analysis, PWS - Kent Publishing Co., Boston, MA, 1989.
29. Faist, M. B., Muckerman, J. T., and Schubert, F. E., "Importance Sampling and Histogrammic Representations of Reactivity Functions and Product Distributions in Monte Carlo Quasiclassical Trajectory Calculations," Journal of Chemical Physics, Vol. 69, No. 9, 1978, pp. 4087-4096.
30. Jaffe, R. L., Pattengill, M. D., and Schwenke, D. W., "Classical Trajectory Studies of Gas Phase Reaction Dynamics and Kinetics Using Ab Initio Potential Energy Surfaces," Supercomputer Algorithms for Reactivity, Dynamics and Kinetics of Small Molecules, edited by A. Lagná, Kluwer, Dordrecht, The Netherlands, 1989.
31. 2 ⇌ 2NO Between 2000-3000°K," Journal of Chemical Physics, Vol. 27, No. 4, 1957, pp. 850-857.
32. Wray, K. L., and Teare, J. D., "Shock-Tube Study of the Kinetics of Nitric Oxide at High Temperatures," Journal of Chemical Physics, Vol. 36, No. 10, 1962, pp. 2582-2596.
33. Duff, R. E., and Davidson, N., "Calculation of Reaction Profiles Behind Steady State Shock Waves II. The Dissociation of Air," Journal of Chemical Physics, Vol. 31, No. 4, 1959, p. 1018.
34. Baulch, D. L., Drysdale, D. D., and Haine, D. G., Evaluated Kinetic Data for High Temperature Reactions, Vol. 2, Butterworths, London, 1973.
35. 2 + O → NO + N," Proceedings of the 17th Symposium (International) on Combustion, The Combustion Inst., Pittsburgh, PA, 1978, p. 543.
36. Park, C., Howe, J. T., Jaffe, R. L., and Candler, G. V., "Review of Chemical-Kinetic Problems of Future NASA Missions, II: Mars Entries," Journal of Themophysics and Heat Transfer, Vol. 8, No. 1, 1994, pp. 9-23.
37. Levine, R. D., and Bernstein, R. B., Molecular Reaction Dynamics and Chemical Reactivity, Oxford Univ. Press, New York, 1987.
38. Duff, J. W., and Truhlar, D. G., "Effect of Curvature of the Reaction Path on Dynamic Effects in Endothermic Chemical Reactions and Product Energies in Exothermic Reactions," Journal of Chemical Physics, Vol. 62, No. 6, 1975, pp. 2477-2491.