Phase rejection as a factor in the kinetics of atropisomerization of 1,1′-binaphthyl conducted in liquid crystal and solid phases

Molecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals

Volumn 289, Issue , 1996, Pages 1-10

  Yarovoy, Y ^a   Nunez, A ^a   Luo, X ^a   Labes, M M ^a  

^a Temple University   (United States)

Author keywords

1,1 binaphthyl; Atropisomerization; Kinetics; Liquid crystals; Phase separation

Indexed keywords

CHEMICAL REACTIONS; ENTHALPY; ENTROPY; MIXTURES; ORGANIC COMPOUNDS; PHASE SEPARATION; PHASE TRANSITIONS; REACTION KINETICS; SOLVENTS; THERMAL EFFECTS; ISOMERIZATION; LIQUID CRYSTALS;

ALKYLCYANOBIPHENYLS; ALKYLCYANOTERPHENYL; ATROPISOMERIZATION; BINAPHTHYL; PHASE HETEROGENEITY; PHASE REJECTION; ANTI ARRHENIUS BEHAVIOR; PHASE ORDER;

LIQUID CRYSTALS; ORGANIC COMPOUNDS;

EID: 0030300777     PISSN: 1058725X     EISSN: None     Source Type: Journal    
DOI: 10.1080/10587259608042308     Document Type: Article

References (22)

1. S. I. Torgova, E. I. Kovshov and V. V. Titov, Zhourn. Organ. Khimii (Russian J. Organic Chemistry), 12, 1593 (1976).
2. W. J. Leigh, D. T. Frendo and P. J. Klawunn, Can. J. Chem., 63, 2131 (1985).
3. J. M. Nerbonne and R. G. Weiss, J. Amer. Chem. Soc., 100, 5953 (1978).
4. J. P. Otruba and R. G. Weiss, J. Org. Chem., 48, 3448 (1983).
5. E. G. Casis and R. G. Weiss, Photochem. Photobiol., 35, 439 (1982).
6. J. P. Otruba and R. G. Weiss, Mol. Cryst. Liq. Cryst., 80, 165 (1982).
7. S. Ganapathy, R. G. Zimmermann and R. G. Weiss, J. Org. Chem., 51, 2529 (1986).
8. J. Naciri, G. P. Spada, G. Gottarelli and R. G. Weiss, J. Am. Chem. Soc., 109, 4352 (1987).
9. A. Nunez, T. Hollebeek and M. M. Labes, J. Am. Chem. Soc., 114, 4925 (1992).
10. (a) R. E. Pincock and T. E. Kiovsky, J. Am. Chem. Soc., 87, 4100 (1965),
11. (b) 88, 51 (1966).
12. T. C. Bruice and A. R. Butler, Fed. Proc., 24, Suppl. No 15, 45 (1965).
13. K. R. Wilson and R. E. Pincock, J. Am. Chem. Soc., 97, 1474 (1975).
14. K. R. Wilson and R. E. Pincock, Can. J. Chem., 55, 889 (1977).
15. B. F. Fahie, D. S. Mitchell, M. S. Workenstein and W. J. Leigh, J. Am. Chem. Soc., 111, 2916 (1989).
16. B. R. Fahie, D. S. Mitchell and W. J. Leigh, Can. J. Chem., 67, 148 (1989).
17. B. Samori, S. Masiero, G. R. Luckhurst, S. K. Heeks, B. A. Timimi and P. Mariani, Liq. Cryst., 15(2), 217 (1993).
18. J. Stumpe, S. Grande, K. Wolf and G. Hempel. Liq. Cryst., 11(2), 175(1992).
19. A. Nunez, G. S. Hammond and R. G. Weiss, J. Am. Chem. Soc., 114, 10258 (1992).
20. (a) R. L. Treanor and R. G. Weiss, Tetrahedron, 43, 1371 (1987),
21. (b) J. Phys. Chem., 91, 5552 (1987).
22. V. Batyuk, T. Shabatina, Y. Morozov and G. Sergeev, Kinetika i Kataliz (Kinetics and Catalysis), 30, 618 (1989).