Characterization of solution and solid state properties of undoped and doped polyanilines processed from hexafluoro-2-propanol

Macromolecules

Volumn 29, Issue 24, 1996, Pages 7838-7846

  Hopkins, Alan R ^a   Rasmussen, Paul G ^a   Basheer, Rafil A ^b  

^a UNIVERSITY OF MICHIGAN   (United States)

^b GENERAL MOTORS CORPORATION   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

COMPOSITION EFFECTS; CONFORMATIONS; DOPING (ADDITIVES); ELECTRIC CONDUCTIVITY OF SOLIDS; MOLECULAR STRUCTURE; MORPHOLOGY;

POLYANILINE; SOLID STATE PROPERTIES;

COPOLYMERS;

EID: 0030288135     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma9606519     Document Type: Article

References (39)

1. Zheng, W.-Y.; Levon, K.; Laakso, J.; Osterholm, J. E. Macromolecules 1994, 27, 7754, 7768.
2. Avlyanov, J. K.; Min, Y. MacDiarmid, A. G; Epstein, A. J. Synth. Met. 1995, 72, 65-71.
3. (a) Min, Y; MacDiarmid, A. G.; Epstein, A. J. Polym. Prepr. (Am. Chem. Soc., Div. Polym. Chem.) 1993, 35, 231-232.
4. (b) MacDiarmid, A. G.; Epstein, A. J. Macromol. Symp. 1995, 98, 835-842.
5. Xia, Y.; Wiesinger, J. M.; MacDiarmid, A. G.; Epstein A. J. Chem. Mater. 1995, 7, 443-445.
6. To see PANI-EB and PANI-ES respective solution colors, visit our web site (under Alan Hopkins) at the following address: http://www.engin.umich.edu/prog/macro.
7. Pouget, J. P.; Jozefowicz, M. E.; Epstein, A. J; Tang, X. MacDiarmid, A. G. Macromolecules 1991, 24, 779-789.
8. Yasuda, A.; Shimidzu, T. Synth. Met. 1993, 61, 239-245.
9. Polyaniline, in the emeraldine base form, has been previously observed to form irreversible cross-links at ≈ 250 °C and will subsequently lose solubility. Conklin, J. A.; Juang, S.-C.; Huang, S-M.; Wen, T.; Kaner, R. B. Macromolecules 1995, 28, 6522-6527.
10. (a) Matveeva, E. S.; Diaz Calleja, R.; Parkhutik, V. P. Synth. Met. 1995, 72, 105-110.
11. (b) Wan, M. J. Polym. Sci.: Part A: Polym. Chem. 1992, 30, 543-549.
12. Cao, Y.; Smith, P.; Heeger, A. J. Synth. Met. 1992, 48, 91.
13. HFIP vapors are considered corrosive to membranes and the skin. Strong ventilation should be used along with gloves and goggles.
14. Smits, F. M. Bell System Tech. J. 1957, 711-718.
15. Uhlir, A. 1954, Aug, 105-128.
16. Kahol, P. K.; Pinto, N. J.; Berndtson, E. J.; McCormick, B. J. J. Solid State Phys. Condens. Matter 1994, 6, 5631-5638.
17. Kou-Tai, T. Ph.D. thesis, Clemson University, 1993; p 103.
18. Ghosh, S. Chem. Phys. Lett. 1994, 226, 344-348.
19. Wudl, F. J. Polym. Sci.: Part B: Polym. Phys. 1987, 5, 1071-1078.
20. Lu, F. L.; Wudl, F.; Nowak, M.; Heeger, A. J. J. Am. Chem. Soc. 1986, 108, 8311-8313.
21. Huang, W. S.; MacDiarmid A. G. Polymer 1993, 34, No. 9, 1833-1843.
22. Roux, C.; Bergeron, J. Y.; Leclerc, M. Polym. Prepr. (Am Chem. Soc., Div. Polym. Chem.) 1992, 33, No. 2, 406-407.
23. Wan, M. J. Polym. Sci.: Part A: Polym. Chem. 1992, 30, 543-549.
24. (a) Gettinger, C. L.; Heeger, A. J.; Pine, D. J.; Cao, Y. Synth. Met. 1995, 74, 81-88.
25. (b) Liao, Y. H.; Kang, T.; Levon, K. Macromol. Chem. Phys. 1995, 196, 3107-3116.
26. (c) Jain, R.; Gregory, R. V. Synth. Met. 1995, 74, 263-266.
27. MacDiarmid, A. G.; Chiang, J. C.; Richter, A. F.; Epstein, A. J. Synth. Met. 1987, 18, 285.
28. Li. S.; Cao, Y.; Xue, Z. Synth. Met. 1987, 20, 141.
29. Baird, D. G.; Smith, J. K. J. Polym. Sci.: Polym. Chem. Ed. 1978, 16, 61-70.
30. (a) Shacklette, L. W.; Baughman, R. H. Mol. Cryst. Liq. Cryst. 1990, 189, 193.
31. (b) Shacklette, L. W.; Wolf, J. F.; Gould, S.; Baughman, R. H. J. Chem Phys. 1988, 88, 3955.
32. Irena, K. B. Macromolecules 1995, 28, 610-613.
33. We find that PANI-EB, cast from NMP and subsequently heated on a hot plate for 100 °C, contains 10-12% (wt/wt) residual solvent. Using m-cresol to dissolve PANI-HCSA, MacDiarmid and Epstein (ref 7b within) report 12-14% tightly bound residual m-cresol in the salt after drying.
34. Chan, H. S. O.; Ng, S. C.; Ho, P. K. H. Macromolecules 1994, 27, 2159-2164.
35. Wang, F.; Tang, J.; Wang, L.; Zhang, H.; Mo, Z. Mol. Cryst. Liq. Cryst. 1988, 60, 175.
36. Young, R. J.; Lovell, P. A. Introd. Polym., 1991, 265-266.
37. Shacklette, L. W. Synth. Met. 1994, 65, 123-130.
38. Bredas, J. L.; Street, G. B. Acc. Chem. Res. 1985, 18, 309-315.
39. Scott, J. C.; Pflunger. P.; Krounbi, M. T.; Street, G. B. Phys. Rev. B 1983, 28, No. 4. 2140-2145.