The effect of aqueous metal-chlorophenolate complexation on contaminant transport in groundwater systems

Applied Geochemistry

Volumn 11, Issue 6, 1996, Pages 735-744

  Fein, Jeremy B ^a  

^a University of Notre Dame   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

AQUEOUS ENVIRONMENT; CHLOROPHENOLATE; COMPLEXATION; CONTAMINANT TRANSPORT; GROUNDWATER;

EID: 0030274226     PISSN: 08832927     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0883-2927(96)00005-4     Document Type: Article

References (32)

1. Baes C. F. Jr. and Mesmer R. E. (1976) The Hydrolysis of Cations. John Wiley and Sons, New York.
2. 3. Geochim. Cosmochim. Acta 60, 2929-2938.
3. Cirelli D. P. (1978) In Pentachlorophenol. Chemistry, Pharmacology and Environmental Toxicology (ed. K. R. Rao), pp. 13-18, Plenum, New York.
4. Davis A., Campbell J., Gilbert C. Ruby M. V., Bennett M. and Tobin S. (1994) Attenuation and biodegradation of chlorophenols in ground water at a former wood treating facility. Ground Water 32, 248-257.
5. Davis J. A. and Gloor R. (1981) Adsorption of dissolved organics in lake water by aluminum oxide. ffect of molecular weight. Environ. Sci. Technol. 15, 1223-1229.
6. Desai A. G. and Milburn R. M. (1969) Iron(III)-phenol complexes. IV. Further thermodynamic studies of iron(III)-phenolate and proton-phenolate associations. J. Amer. Chem. Soc. 91, 1958-1961.
7. Fein J. B. and Hestrin J. E. (1994) Experimental studies of oxalate complexation at 80°C: Gibbsite, amorphous silica, and quartz solubilities in oxalate-bearing fluids. Geochim. Cosmochim. Acta 58, 4817-4829,
8. Fein J. B., Yane L. and Handa T. (1994) The effect of aqueous complexation on the decarboxylation rate of oxalate. Geochim. Cosmochim. Acta 58, 3975-3981.
9. Fein J. B., Gore N., Marshall D., Yassa L., Loch A., and Brantley S. L. (1995) The effect of aqueous complexation and mineral surfaces on the decarboxylation rate of malonate. Geochim. Cosmochim. Acta 59, 5071-5080.
10. Helgeson H. C., Kirkham D. H. and Flowers G. C. (1981) Theoretical prediction of the thermodynamic behavior of aqueous electrolytes at high pressures and temperatures. IV. Calculation of activity coefficients, osmotic coefficients and apparent molal and standard and relative partial moral properties to 600°C and 5 Kb. Amer. J. Sci. 281, 1249-1516.
11. 3. J. Colloid Interface Sci. 43, 409-420.
12. Hunter K. A. and Liss P. S. (1979) The surface charge of suspended particles in estuarine and coastal waters. Nature 282, 823-825.
13. Keith L. H. and Telliard W. A. (1979) Priority pollutants: i-a perspective view. Environ. Sci. Tech. 13, 416-423.
14. 3. J. Colloid Interface Sci. 75, 373-385.
15. Kung K. M. S. and McBride M. B. (1991) Bonding of chlorophenols on iron and aluminum oxides. Environ. Sci. Tech. 25, 702-709.
16. Langmuir D. (1979) Techniques of estimating thermodynamic properties for some aqueous complexes of geochemical interest. In Chemical Modeling in Aqueous Systems (ed. E. A. Jenne) pp. 353-387. Amer. Chem. Soc., Washington, DC.
17. Lee L. S., Rao P. S. C. and Brusseau M. L. (1991) Nonequilibrium sorption and transport of neutral and ionized chlorophenols. Environ. Sci. Tech. 25, 722-729.
18. Lee L. S., Rao P. S., Nkedi-Kizza P. and Delfino J. J. (1990) Influence of solvent and sorbent characteristics on distribution of pentachlorophenol in octanol-water and soil-water systems. Environ. Sci. Tech. 24, 654-661.
19. Ma K.-C., Shiu W.-Y. and Mackay D. (1993) Aqueous solubilities of chlorinated phenols at 25 °C. J. Chem. Eng. Data 38, 364-366.
20. Martell A. E. and Smith R. M. (1977) Critical Stability Constants. V. 3. Other Organic Ligands. Plenum Press, New York.
21. Martell A. E. and Smith R. M. (1982) Critical Stability Constants. V. 5. First Supplement. Plenum Press, New York.
22. Parsons R. (1974) Statistical Analysis: A Decision-Making Approach. Harper and Row, New York.
23. Schellenberg K., Leuenberger C. and Schwarzenbach R. P. (1984) Sorption of chlorinated phenols by natural sediments and aquifer materials. Environ. Sci. Tech. 18, 652-657.
24. 2+. J. Colloid Interface Sci. 55, 469-475.
25. Smith R. M. and Martell A. E. (1976) Critical Stability Constants.V. 4.Inorganic Complexes. Plenum Press, New York.
26. Stapleton M. G., Sparks D. L. and Dentel S. K. (1994) Sorption of pentachlorophenol to HDTMA-clay as a function of ionic strength and pH. Environ. Sci. Tech. 28, 2330-2335.
27. Suntio L. R., Shiu W. Y. and Mackay D. (1988) A review of the nature and properties of chemicals present in pulp mill effluents. Chemosphere 17, 1249-1290.
28. Tipping E. and Cooke D. (1982) The effects of adsorbed humic substances on the surface charge of goethite (α-FeOOH) in freshwaters. Geochim. Cosmochim. Acta 46, 75-80.
29. U.S. Environmental Protection Agency (1987) Soil attenuation of chemicals. Draft technical resource document for public comment. USEPA, Hazardous Waste Engineering Research Laboratory, Cincinnati, OH. EPA/530-SW-87-006.
30. Wesolowski D. J. and Palmer D. A. (1994) Aluminum speciation and equilibria in aqueous solution. V. Gibbsite solubility at 50°C and pH 3-9 in 0. 1 molal NaCl solutions (a general model for aluminum speciation; analytical methods). Geochim. Cosmochim. Acta 58, 2947-2969.
31. Westall J. C. (1982) FITEQL, A Computer Program for Determination of Chemical Equilibrium Constants from Experimental Data (Version 2. 0). Technical Report 82-02, Oregon State University, Dept. of Chemistry, Corvallis, OR.
32. Wolery T. J. (1992) EQ3NR, A Computer Program for Geochemical Aqueous Speciation-solubility Calculations: Theoretical Manual, User's Guide, and Related Documentation (Version 7. 0). UCRL-MA-110662-PT-III, Lawrence Livermore National Laboratory.