Reactions of sulfur dioxide with ammonia: Dependence on oxygen and nitric oxide

Industrial and Engineering Chemistry Research

Volumn 35, Issue 10, 1996, Pages 3362-3368

  Hirota, Koichi ^b   Mäkelä, Jyrki ^a,c   Tokunaga, Okihiro ^b  

^a Dept Radiat Res Environ Rsrc ^*  (Japan)

^b JAPAN ATOMIC ENERGY AGENCY   (Japan)

^c UNIVERSITY OF HELSINKI   (Finland)

Author keywords

[No Author keywords available]

Indexed keywords

AMMONIA; AMMONIUM COMPOUNDS; CHARACTERIZATION; CHEMICAL REACTORS; FLUE GASES; FOURIER TRANSFORM INFRARED SPECTROSCOPY; NITRIC ACID; OXIDATION; OXYGEN; SULFAMIC ACID; SULFUR DIOXIDE; TEMPERATURE;

AMMONIUM SULFAMATE; AMMONIUM SULFATE; NITRIC OXIDE; SIMULATED FLUE GAS;

CHEMICAL REACTIONS;

CHEMICAL REACTIONS; SEPARATION-GAS/GAS; SULPHUR DIOXIDE;

EID: 0030267075     PISSN: 08885885     EISSN: None     Source Type: Journal    
DOI: 10.1021/ie950560k     Document Type: Article

References (21)

1. Ackermann, M. N.; Powell, R. E. Air Oxidation of Hydroxylamine-N-sulfonate. Inorg. Chem. 1967, 6, 1718-1720.
2. 2 Reactions at Trace Water Conditions. Ind. Eng. Chem. Res. 1992, 31, 88-94.
3. 3 Gas Injection: Effects of Temperature and Moisture Content. Ind. Eng. Chem. Res. 1994, 33, 1231-1236.
4. x from Flue Gas. Environ. Prog. 1992, 11, 66-73.
5. 3 in Humid Air. J. Aerosol Sci. 1992, 23, S261-S264.
6. Hartley, E. M.; Matteson, M. J. Sulfur Dioxide Reactions with Ammonia in Humid Air. Ind. Eng. Chem. Fundam. 1975, 14, 67-72.
7. Hirota, K.; Niina, T.; Anwar, E.; Namba, H.; Tokunaga, O.; Tabata, Y. Reactions of Sulfur Dioxide with Ammonia. J. Environ. Sci. 1993, 6, 143-150.
8. Hirota, K.; Tokunaga, O.; Miyata, T.; Sato, S.; Osada, Y.; Sudo, M.; Doi, T.; Shibuya, E.; Baba, S.; Hatomi, T.; Komiya, M.; Miyajima, K. Pilot-scale Test for Electron Beam Purification of Flue Gas from a Municipal Waste Incinerator with Slaked-Lime. Radiat. Phys. Chem. 1995, 46, 1089-1092.
9. Hjuler, K.; Dam-Johansen, K. Mechanism and Kinetics of the Reaction between Sulfur Dioxide and Ammonia in Flue Gas. Ind. Eng. Chem. Res. 1992, 31, 2110-2118.
10. Kawamura, K.; Aoki, S.; Kimura, H.; Adachi, K.; Kawamura, K.; Katayama, T.; Kengaku, K.; Sawada, Y. Pilot Plant Experiment on the Treatment of Exhaust Gas from a Sintering Machine by Electron Beam Irradiation. Environ. Sci. Technol. 1980, 14, 288-293.
11. 3. Nature Phys. Sci. 1973, 244, 53-54.
12. Landreth, R.; de Pena, R. G.; Heicklen, J. Thermodynamics of the Reaction of Ammonia and Sulfur Dioxide in the Presence of Water Vapor. J. Phys. Chem. 1975, 79, 1785-1788.
13. Littlejohn, D.; Chang, S. G. Modeling of the Chemistry of Wet Limestone Flue Gas Desulfurization Systems. Energy Fuels 1991, 5, 249-254.
14. Littlejohn, D.; Hu, K. Y.; Chang, S. G. Kinetics of the Reaction of Nitric Oxide with Sulfite and Bisulfite Ions in Aqueous Solution. Inorg. Chem. 1986, 25, 3131-3135.
15. Namba, H.; Tokunaga, O.; Hashimoto, S.; Tanaka, T.; Ogura, Y.; Doi, Y.; Aoki, S.; Izutsu, M. Pilot-scale Test for Electron Beam Purification of Flue Gas from Coal-combustion Boiler. Radiat. Phys. Chem. 1995, 46, 1103-1106.
16. Nunes, T. L.; Powell, R. E. Kinetics of the Reaction of Nitric Oxide with Sulfite. Inorg. Chem. 1970, 9, 1916-1917.
17. Osada, Y.; Hirota, K.; Sudo, M.; Baba, S.; Shibuya, E.; Doi, T.; Nakajima, M.; Komiya, M.; Miyajima, K.; Miyata, T.; Tokunaga, O. Pilot-scale Test on Electron Beam Treatment of Municipal Solid Waste Flue Gas with Spraying Slaked-Lime Slurry. Radiat. Phys. Chem. 1995, 45, 1021-1027.
18. Scargill, D. Dissociation Constants of Anhydrous Ammonium Sulphite and Ammonium Pyrosulphite Prepared by Gas-phase Reactions. J. Chem. Soc. A 1971, 2461-2466.
19. 2 in Aqueous Solutions. Atmos. Environ. 1981, 15, 1129-1144.
20. Scott, W. D.; Lamb, D. The Solid Compounds Which Decompose into a Common Vapor. Anhydrous Reactions of Ammonia and Sulfur Dioxide. J. Am. Chem. Soc. 1970, 92, 3943-3946.
21. 2 Removal. In Non-Thermal Plasma Techniques for Pollution Control; NATO ASI Series Vol. 34, Part B; Penetrante, B. M., Schultheis, S. E., Eds.; Springer-Verlag: Berlin, Heidelberg, 1993; pp 55-62.