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Use of a simple Bernoullian statistical model is a first approximation, owing to the presence of regioirregularly arranged monomer units. A more complete statistical analysis taking into account both stereospecificity and regiospecificity was developed for V-promoted polymerization: Ammendola, P.; Shijing, X.; Grassi, A.; Zambelli, A. Gazz. Chim. Ital. 1988, 118, 769.
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85033850155
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note
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9 and was explained on the basis of a reaction mechanism involving β-hydride elimination of growing polymer chains ending with a 2,1 propene unit followed by reinsertion of the resulting α-olefin with opposite regiochemistry.
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24
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85033839772
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note
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