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Volumn 29, Issue 22, 1996, Pages 6990-6993

Syndiotactic-specific polymerization of propene with nickel-based catalysts. 2. Regiochemistry and stereochemistry of the initiation steps

Author keywords

[No Author keywords available]

Indexed keywords

CATALYSIS; CATALYSTS; CHEMICAL BONDS; CHEMISTRY; DERIVATIVES; MICROSTRUCTURE; NICKEL; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; POLYMERIZATION;

EID: 0030263983     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma9606723     Document Type: Article
Times cited : (60)

References (26)
  • 21
    • 0001686581 scopus 로고
    • Use of a simple Bernoullian statistical model is a first approximation, owing to the presence of regioirregularly arranged monomer units. A more complete statistical analysis taking into account both stereospecificity and regiospecificity was developed for V-promoted polymerization: Ammendola, P.; Shijing, X.; Grassi, A.; Zambelli, A. Gazz. Chim. Ital. 1988, 118, 769.
    • (1988) Gazz. Chim. Ital. , vol.118 , pp. 769
    • Ammendola, P.1    Shijing, X.2    Grassi, A.3    Zambelli, A.4
  • 23
    • 85033850155 scopus 로고    scopus 로고
    • note
    • 9 and was explained on the basis of a reaction mechanism involving β-hydride elimination of growing polymer chains ending with a 2,1 propene unit followed by reinsertion of the resulting α-olefin with opposite regiochemistry.
  • 24
    • 85033839772 scopus 로고    scopus 로고
    • note
    • 12a


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.