Transient and Resonant Behavior for NO Reduction by CO over a Pt/Al2O3 Catalyst during Forced Composition Cycling

Canadian Journal of Chemical Engineering

Volumn 74, Issue 5, 1996, Pages 674-682

  Sadhankar, Ramakant R ^a,b   Lynch, David T ^a  

^a UNIVERSITY OF ALBERTA   (Canada)

^b ATOMIC ENERGY OF CANADA LIMITED   (Canada)

Author keywords

Forced composition cycling; Forced oscillations; NO reduction by CO

Indexed keywords

ALUMINA; CARBON MONOXIDE; CATALYSTS; CHEMICAL REACTORS; NITROGEN OXIDES; OSCILLATIONS; PLATINUM; RESONANCE; THERMAL CYCLING;

FORCED COMPOSITION CYCLING; FORCED OSCILLATIONS; ISOTHERMAL RECYCLE REACTOR;

REDUCTION;

EID: 0030262593     PISSN: 00084034     EISSN: None     Source Type: Journal    
DOI: 10.1002/cjce.5450740518     Document Type: Article

References (23)

1. Bailey, J. E., "Periodic Phenomena", in "Chemical Reactor Theory: A Review", L. Lapidus and N. R. Amundson, Eds., Prentice-Hall, Engelwood Cliffs, NJ (1977), pp. 758-813.
2. 2O+CO Reaction in Overall NO+CO Reaction System: Further Analysis and Experimental Observations", J. Catal. 148, 697-708 (1994).
3. Cho, B. K., B. H. Shanks, and J. E. Bailey, "Kinetics of NO Reduction by CO over Supported Rhodium Catalysts: Isotopic Cycling Experiments", J. Catal. 115, 486-499 (1989).
4. Dath, J.-P., Th. Fink, R. Imbihl and G. Ertl, "Periodic and Random Perturbation of a System Exhibiting Damped Kinetic Oscillations - Pt(100)/NO+CO", J. Chem. Phys. 96, 1582-1589 (1992).
5. Fink, Th., J.-P. Dath, M. R. Bassett, R. Imbihl and G. Ertl, "A New Model for the "Explosive" NO+CO Reaction on Pt(100), Vacuum 41, 301-303 (1990).
6. Fink, Th., J.-P. Dath, M.R. Bassett, R. Imbihl and G. Ertl, "The Mechanism of the "Explosive" NO+CO Reaction on Pt(100): Experiments and Mathematical Modelling", Surf. Sci. 245, 96-110 (1991).
7. Graham, W. R. C. and D. T. Lynch, "CO Oxidation on Pt: Variable Phasing of Inputs During Forced Composition Cycling", AIChE J. 36, 1796-1806 (1990).
8. 2 System over Pt-Alumina", Ind. Eng. Chem. Fundam. 19, 367-373 (1980).
9. Hugo, A. J., D. M. Jakelski, G. Stanistas, G. R. Sullivan, R. R. Hudgins and P. L. Silveston, "Long-Term Transients in a Reactor Under Forced Concentration Cycling", Can. J. Chem. Eng. 64, 349-351 (1986).
10. Lambert, R. M. and C. M. Comrie, "The Oxidation of CO by NO on Pt(111) and Pt(110)", Surf. Sci. 46, 61-80 (1974).
11. Lesley, M. W. and L. D. Schmidt, "Chemical Autocatalysis in the NO+CO Reaction on pt(100)", Chem. Phys. Lett. 102, 459-463 (1983).
12. Lesley, M. W. and L. D. Schmidt, "The NO+CO Reaction on Pt(100)", Surf. Sci. 155, 215-240 (1985).
13. Lööf, P., B. Kasemo, S. Andersson and A. Frestad, "Influence of Ceria on the Interaction of CO and NO with Highly Dispersed Pt and Rh", J. Catal. 130, 181-191 (1991).
14. Lynch, D. T., "Modelling of Resonant Behavior During Forced Composition Cycling of Catalytic Reactors", Can. J. Chem. Eng. 61, 183-188 (1983).
15. Lynch, D. T., "Use of Elementary Step Mechanism to Explain Resonant Behavior for CO Oxidation on Platinum", Can. J. Chem. Eng. 62, 691-698 (1984).
16. Lynch, D. T., "Forced Cycling of Catalytic Reactors: Number of Cycles to Reach Cycle Invariance", Can. J. Chem. Eng. 64, 1035-1038 (1986).
17. Morrow, B. A., J. P. Chevrier and L. E. Moran, "An Infrared Study of the Adsorption of NO on Silica-Supported Platinum over a Wide Temperature Range", J. Catal. 91, 208-215 (1985).
18. Muraki, H. and Y. Fujitani, "NO Reduction by CO over Noble-Metal Catalysts under Cycled Feed-Streams", Ind. Eng. Chem. Prod. Res. Dev. 25, 414-419 (1986).
19. Muraki, H., H. Shinjoh and Y. Fujitani, "Reduction of NO by CO over Alumina-Supported Palladium Catalyst", Ind. Eng. Chem. Prod. Res. Dev. 25, 419-424 (1986).
20. 2O Reduction by CO over an Alumina-Supported Pt Catalyst: Steady-State Multiplicity", J. Catal. 146, 511-522 (1994).
21. 2O Reduction by CO over an Alumina-Supported Pt Catalyst: Forced Composition Cycling", J. Catal. 149, 278-291 (1994).
22. 2O in the Catalytic Reduction of NO by CO", J. Catal. 10, 408-412 (1968).
23. Taylor, K. C., "Automobile Catalytic Converters", in "Catalysis Science and Technology" Vol. 5, J. R. Anderson and M. Boudart, Eds., Springer-Verlag, Berlin (1984), pp. 119-170.