Swelling Equilibrium Properties of Partially Charged Gels: The Effect of Salt on the Shear Modulus

Polymer Gels and Networks

Volumn 4, Issue 5-6, 1996, Pages 481-498

  Nisato, G ^a   Schosseler, F ^a   Candau, S J ^a  

^a UNIVERSITÉ DE STRASBOURG   (France)

Author keywords

[No Author keywords available]

Indexed keywords

COMPRESSION TESTING; CROSSLINKING; GELS; OSMOSIS; POLYACRYLATES; SHEAR DEFORMATION; SWELLING;

CHARGED GELS; INTERNAL OSMOTIC PRESSURE; POLYACRYLIC ACID;

POLYELECTROLYTES;

EID: 0030261434     PISSN: 09667822     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0966-7822(96)00024-X     Document Type: Article

References (31)

1. Katchalsky, A. & Michaëli, I., Polyelectrolyte gels in salt solutions. J. Polym. Sci., 15 (1955) 69.
2. Silberberg, A., Gel structural heterogeneity, gel permeability, and mechanical response. In Polyelectrolyte Gels (Harland, R.S. & Prud'homme, R.K., eds). ACS Symposium Series 480, Washington, DC, 1992, p. 146.
3. Schosseler, F., Skouri, R., Munch, J.P. & Candau, S.J., Swelling and cross-linking effects on the structure of partially ionized gels. J. Phys. II Fr., 4 (1994) 1221.
4. Skouri, R., Schosseler, F., Munch, J.P. & Candau, S.J., Frozen-in intensity fluctuations of light scattered by partially ionized gels. Europhys. Lett., 23 (1993) 635.
5. Moussaid, A., Candau, S.J. & Joosten, J.G.H., Structural and dynamic properties of partially charged poly(acrylic acid) gels: nonergodicity and inhomogeneities. Macromolecules, 27 (1994) 2102.
6. Bastide, J. & Candau, S.J., Structure of gels as investigated by means of static scattering techniques. In Physical Properties of Polymeric Gels (Cohen Addad, J.P., ed.). Wiley, Chichester, 1996.
7. Schosseler, F., Ilmain, F. & Candau, S.J., Structure and properties of partially neutralized poly(acrylic acid) gels. Macromolecules, 24 (1991) 225.
8. Skouri, R., Schosseler, F., Munch, J.P. & Candau, S.J., Swelling and elastic properties of polyelectrolyte gels. Macromolecules, 28 (1995) 197.
9. Nisato, G., Skouri, R., Schosseler, F., Munch, J.P. & Candau, S.J., Elastic behaviour of salt-free polyelectrolyte gels. Faraday Discuss., 101 (1995) 133.
10. Schröder, U.P. & Opperman, W., Properties of polyelectrolyte gels. In Physical Properties of Polymeric Gels (Cohen Addad, J.P., ed.). Wiley, Chichester, 1996, and references therein.
11. Moussaid, A., Munch, J.P., Schosseler, F. & Candau, S.J., Light scattering study of partially ionized poly(acrylic acid) systems: comparison between gels and solutions. J. Phys. II Fr., 1 (1995) 637.
12. de Gennes, P.G., Pincus, P., Velasco, R.M. & Brochard, F., Remarks on polyelectrolyte conformation. J. Phys. Fr., 37 (1976) 1461.
13. Cates, M.E., The anomalous Kerr effect: implications for polyelectrolyte structure. J. Phys. II Fr., 2 (1992) 1109.
14. Rubinstein, M., Colby, R.H., Dobrynin, A.V. & Joanny, J.F., Elastic modulus and equilibrium swelling of polyelectrolyte gels. Macromolecules, 29 (1995) 398.
15. Panyukov, S.V., Scaling theory of high elasticity. Sov. Phys. JETP, 71 (1990) 372.
16. Obukhov, S.P., Rubinstein, M. & Colby, R.H., Network modulus and superelasticity. Macromolecules, 21 (1994) 3191.
17. Hasa, J., Ilavsky, M. & Dusek, K., Deformational, swelling and potentiometric behavior of ionized poly(methacrylic acid) gels. Part 1: Theory. J. Polym. Sci., Polym. Phys. Ed., 13 (1975) 253.
18. Flory, P.J., The Principles of Polymer Chemistry. Cornell University Press, Ithaca, NY, 1953.
19. Joanny, J.F. & Pincus, P., Electrolyte and polyelectrolyte solutions: limitations of scaling laws, osmotic compressibility and thermoelectric power. Polymer, 21 (1980) 274.
20. Borue, V.Y. & Erukhimovich, I.Y., A statistical theory of weakly charged polyelectrolytes: fluctuations, equations of state, and microphase separation. Macromolecules, 21 (1988) 3240.
21. Nagasawa, M. & Takahashi, A., Light Scattering From Polyelectrolyte Solutions (Huglin, M.B., ed.). Academic Press, London, 1972, p. 720.
22. Silberberg-Bouhnik, M., Ramon, O., Ladyzhinski, I., Mizhai, S. & Cohen, Y., Osmotic deswelling of weakly charged poly(acrylic acid) solutions and gels. J. Polym. Sci. B, 33 (1995) 2269.
23. Skouri, R., Etude de propriétés structurales de gels de polyelectrolytes. Doctoral dissertation, ULP, Strasbourg, 1994.
24. Silberberg, A., Eliassaf, J. & Katchalsky, A., Temperature-dependence of light scattering and intrinsic viscosity of hydrogen bonding polymers. J. Polym. Sci. A., 2 (1957) 259.
25. Bastide, J., Candau, S.J. & Leibler, L., Osmotic deswelling of gels by polymer solutions. Macromolecules, 14 (1980) 719.
26. Treloar, L.R.G., The Physics of Rubber Elasticity. Clarendon Press, Oxford, 1975.
27. Schröder, U.P. & Opperman, W., Mechanical and stress-optical properties of strongly swollen hydrogels. Makromol. Chem., Macromol. Symp., 73 (1993) 63.
28. Pincus, P., Excluded volume effects and stretched polymer chains. Macromolecules, 9 (1976) 386.
29. Grosberg, A., Two types of topological constraints in polymer networks. Macromolecules, 26 (1993) 3200.
30. Dobrynin, A.V., Colby, R.H. & Rubinstein, M., Scaling theory of polyelectrolyte solutions. Macromolecules, 28 (1995) 1859.
31. de Gennes, P.G., Scaling Concepts in Polymer Physics. Cornell University Press, Ithaca, NY, 1979.