Effect of porosity of carbogenic molecular sieve catalysts on ethylbenzene oxidative dehydrogenation

Industrial and Engineering Chemistry Research

Volumn 35, Issue 10, 1996, Pages 3319-3331

  Kane, Michael S ^a   Kao, Lien C ^a   Mariwala, Ravindra K ^a   Hilscher, David F ^a   Foley, Henry C ^a  

^a University of Delaware   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVATION ENERGY; CARBON; CATALYST DEACTIVATION; CATALYSTS; DEHYDROGENATION; DIFFUSION; MOLECULAR SIEVES; OXIDATION; POROSITY; STYRENE; TRANSPORT PROPERTIES;

CARBOGENIC MOLECULAR SIEVE; COKE DEPOSITION; ETHYLBENZENE OXIDATIVE DEHYDROGENATION; TRANSPORT POROSITY;

AROMATIC COMPOUNDS;

EID: 0030258155     PISSN: 08885885     EISSN: None     Source Type: Journal    
DOI: 10.1021/ie950762g     Document Type: Article

References (39)

1. Alkhazov, T. G.; Lisovskii, A. E. The Role of Condensation Products in the Oxidative Dehydrogenation Process of Ethylbenzene on Aluminum Oxide Catalyst. Kinet. Katal. 1976, 17, 434.
2. Alkhazov, T. G.; Lisovskii, E. A.; Ismailov, Yu. A.; Kozharov, A. I. Oxidative Dehydrogenation of Ethylbenzene on Activated Carbons. I. General Characteristics of the Process. Kinet. Katal. 1978, 19, 611.
3. Batist, P. H. A.; Lippens, B. C.; Schuit, G. C. A. The Catalytic Oxidation of 1-Butene Over Bismuth Molybdate Catalysts. J. Catal. 1966, 5, 55.
4. Berger, P. A.; Roth, J. F. Electron Spin Resonance Studies of Carbon Dispersed on Alumina. J. Phys. Chem. 1968, 72, 3186.
5. Cadus, L. E.; Arrua, L. A.; Gorriz, O. F.; Rivarola, J. B. Action of Activated Coke as a Catalyst: Oxydehydrogenation of Ethylbenzene to Styrene. Ind. Eng. Chem. Res. 1988, 27, 2241.
6. Cadus, L. E.; Gorriz, O. F.; Rivarola, J. B. Nature of Active Coke in the Oxydehydrogenation of Ethylbenzene to Styrene. Ind. Eng. Chem. Res. 1990, 29, 1143.
7. Clearfield, A.; Thakur, D. S. Zirconium and Titanium Phosphates as Catalysts: A Review. Appl. Catal. 1986, 26, 1.
8. Drago, R. S.; Jurczyk, K. Oxidative Dehydrogenation of Ethylbenzene to Styrene over Carbonaceous Catalysts. Appl. Catal. A 1994, 112, 117.
9. Emig, G.; Hofmann, H. Action of Zirconium Phosphate as a Catalyst for the Oxydehydrogenation of Ethylbenzene to Styrene. J. Catal. 1983, 84, 15.
10. Emig, G.; Hofmann, H.; Schraut, A. Active Coke as an Organic Catalyst in the Oxydehydrogenation of Ethylbenzene. In Recent Trends in Chemical Reaction Engineering, Kulkarni, B. D., Mashlekar, R. A., Sharma, M. M., Eds.; Wiley:New York, 1987.
11. Fiedorow, R.; Kania, W.; Nowinska, K.; Sopa, M.; Wojciechowska, M. Activity of Alumina Promoted by Inorganic Acids in the Process of Oxidative Dehydrogenation of Ethylbenzene. Bull. Acad. Pol. Sci., Ser. Sci. Chim. 1978, 26, 641.
12. Fiedorow, R.; Przystajko, W.; Sopa, M. The Nature and Catalytic Influence of Coke Formed on Alumina: Oxidative Dehydrogenation of Ethylbenzene. J. Catal. 1981, 68, 33.
13. Foley, H. C. In Perspectives in Molecular Sieve Science; Flank, W. H., Whyte, T. E., Jr., Eds.; American Chemical Society: Washington, DC, 1988.
14. 3 Composite Catalyst. Chem. Eng. Sci. 1995, in press.
15. Grunewald, J.; Drago, R. S. Oxidative Dehydrogenation of Ethylbenzene to Styrene over Carbon-Based Catalysts. J. Mol. Catal. 1990, 58, 227.
16. Guerrero-Ruiz, A.; Rodriguez-Ramos, I. Oxydehydrogenation of Ethylbenzene to Styrene Catalyzed by Graphites and Activated Carbons. Carbon 1994, 32, 23.
17. Hong, A.; Mariwala, R. K.; Kane, M. S.; Foley, H. C. Adsorbate Shape Selectivity: Separation of the HF/134a Azeotrope over Carbogenic Molecular Sieve. Ind. Eng. Chem. Res. 1995, 34 in press.
18. House, H. O. Modern Synthetic Reactions, 2nd ed.; Benjamin: Menlo Park, CA, 1972; p35.
19. Iwasawa, Y.; Soma, M.; Onishi, T.; Tamaru, K. Catalytic Activities of Polynaphthoquinone Containing Various Metal Halides. J. Chem. Soc., Faraday Trans. 1 1972, 68.
20. Iwasawa, Y.; Nobe, H.; Ogasawara, S. Reaction Mechanism for Styrene Synthesis over Polynaphthoquinone. J. Catal. 1973, 31, 444.
21. Juntgen, H.; Knoblauch, K.; Harder, K. Carbon Molecular Sieves: Production from Coal and Application in Gas Separation. Fuel 1981, 60, 817.
22. Lafyatis, D. S.; Foley, H. C. Molecular Modeling of Shape Selectivity for the Fischer Tropsch Reaction Using a Trifunctional Carbon Molecular Sieving Catalyst. Chem. Eng. Sci. 1990, 45, 2567.
23. Lafyatis, D. S.; Tung, J.; Foley, H. C. Poly(Furfuryl alcohol)-Derived Carbon Molecular Sieves: Dependence of Adsorptive Properties on Carbonization Temperature, Time and Poly(ethylene glycol) Additives. Ind. Eng. Chem. Res. 1991, 30, 865.
24. Lafyatis, D. S.; Mariwala, R. K.; Lowenthal, E. E.; Foley, H. C. Design and Synthesis of Carbon Molecular Sieves for Separation and Catalysis. In Synthesis of Microporous Materials: Expanded Clays and Other Microporous Solids; Occelli, M. L., Robson, H., Eds.; Van Nostrand: New York, Vol. II, p 318.
25. Lee, C. S. (Mobil Oil). U.S. Patent No. 4 652 690, 1987.
26. Lewis, P. J.; Hagopian, C.; Koch, P. Styrene. Kirk-Othmer Encyclopedia of Chemical Technology, 3rd ed.; Wiley: New York, 1983; Vol. 21, pp 770-801.
27. Manassen, J.; Wallach, J. Organic Polymers. Correlation between their Structure and Catalytic Activity in Heterogeneous Systems. I. Pyrolyzed Polyacrylonitrile and Poly(cyanoacetylene). J. Am. Chem. Soc. 1965, 87, 2671.
28. Manassen, J.; Khalif, S. H. Organic Polymers: Correlation between Their Structure and Catalytic Activity in Heterogeneous Systems. II. Oxidative Dehydrogenation: A Comparison between the Catalytic Activity of an Organic Polymer and that of Some Molybdate Catalysts. J. Catal. 1969, 13, 290.
29. Mariwala, R. K.; Foley, H. C. Calculation of Micropore Sizes in Carbogenic Materials from the Methyl Chloride Adsorption Isotherm. Ind. Eng. Chem. Res. 1994a, 33, 2314.
30. Mariwala, R. K.; Foley, H. C. Evolution of Ultramicroporous Adsorptive Structure in Poly(furfuryl alcohol)-Derived Carbogenic Molecular Sieves. Ind. Eng. Chem. Res. 1994b, 33, 607.
31. 5. J. Catal. 1981, 71, 257.
32. Murakami, Y.; Iwayama, K.; Uchida, H.; Hattori, T.; Tagawa, T. Screening of Catalysts for the Oxidative Dehydrogenation of Ethylbenzene. Appl. Catal. 1982, 2, 67.
33. Roth, J. F.; Schaefer, A. R. Belgian Patent 682 863, 1966.
34. Roth, J. F.; Schaefer, A. R. U.S. Patent 3 446 865, 1969.
35. Roth, J. F.; Abell, J. B.; Fannin, L. W.; Schaeffer, A. R. Catalytic Dehydrogenation of Higher Normal Paraffins to Linear Olefins. Symposium on Refining Petroleum for Chemicals, Presented before the Division of Petroleum Chemistry and the Division of Industrial and Engineering Chemistry, American Chemical Society, New York City Meeting, 1969; Paper No. D 146.
36. Satterfield, C. N. Heterogeneous Catalysis in Industrial Practice, 2nd ed.; McGraw Hill: New York, 1991; p 479.
37. Schraut, A.; Emig, G.; Sockel, H.-G. Composition and Structure of Active Coke in the Oxydehydrogenation of Ethylbenzene. Appl. Catal. 1987, 29, 311.
38. Vrieland, G. E. Oxydehydrogenation of Ethylbenzene to Styrene over Metal Pyrophosphates. 1. Catalyst Composition and Reaction Variables. J. Catal. 1988a, 111, 1.
39. Vrieland, G. E. Oxydehydrogenation of Ethylbenzene to Styrene over Metal Pyrophosphates. 2. Microbalance Studies of Carbon Deposition and Burnoff. J. Catal. 1988b, 111, 14.