Oxidative coupling of methane with ac and dc corona discharges

Industrial and Engineering Chemistry Research

Volumn 35, Issue 10, 1996, Pages 3295-3301

  Liu, Changjun ^a,b   Marafee, Abdulathim ^a   Hill, Bobby ^a   Xu, Genhui ^a,b   Mallinson, Richard ^a   Lobban, Lance ^a  

^a University of Oklahoma   (United States)

^b TIANJIN UNIVERSITY   (China)

Author keywords

[No Author keywords available]

Indexed keywords

ATMOSPHERIC PRESSURE; CATALYST SELECTIVITY; DEHYDROGENATION; ELECTRIC DISCHARGES; ETHANE; ETHYLENE; HYDROCARBONS; METHANE; PHASE TRANSITIONS; PLASMAS;

CORONA DISCHARGES; ELECTRODE POLARITY; NONTHERMAL PLASMA; OXIDATIVE CONVERSION; OXIDATIVE COUPLING;

OXIDATION;

EID: 0030257692     PISSN: 08885885     EISSN: None     Source Type: Journal    
DOI: 10.1021/ie960138j     Document Type: Article

References (23)

1. - Ions with Saturated Hydrocarbon Molecules. Can. J. Chem. 1969, 47, 2717.
2. Bohme, D. K.; Young, L. B. Gas-phase Reactions of Oxide Radical Ion and Hydroxide Ion with Simple Olefins and of Carbanions with Oxygen. J. Am. Chem. Soc. 1970, 92, 3301.
3. 3 Catalysts for Methane Coupling. Influence of the Structure of Surface Sm-Al-O Phases on the Reactivity. J. Phys. Chem. 1993, 97, 9233.
4. Chang, J.; Lawless, P. A.; Yamamoto, T. Corona Discharge Processes. IEEE Trans. Plasma Sci. 1991, 19, 1152.
5. Chantry, P. J. Dissociative Attachment in Carbon Dioxide. J. Chem. Phys. 1972, 57, 3180.
6. 3. J. Catal. 1988, 113, 517.
7. Eliasson, B.; Kogelschatz, U. Nonequilibrium Volume Plasma Chemical Processing. IEEE Trans. Plasma Sci. 1991 19, 1063.
8. Eng, D.; Stoukides, M. Catalytic and Electrocatalytic Methane Oxidation with Solid Oxide Membranes. Catal. Rev., Sci. Eng. 1991a, 33, 375.
9. Eng, D.; Stoukides, M. Catalytic and Electrochemical Oxidation of Methane on Platinum. J. Catal. 1991b, 130, 306.
10. Gaffney, A. M.; Jones, C. A.; Leonard, J. J.; Sofranko, J. A. Oxidative Coupling of Methane over Sodium Promoted Praseodymium Oxide. J. Catal. 1988, 114, 422.
11. Grill, A. Cold Plasma in Materials Fabrication: From fundamentals to applications; IEEE Press: New York, 1994.
12. Imai, H.; Tagawa, T. Oxidative Coupling of Methane over Lanthanum Aluminum Trioxide. J. Chem. Soc., Chem. Commun. 1986, 52.
13. Lee, J. S.; Oyama, S. T. Oxidative Coupling of Methane to Higher Hydrocarbons. Catal. Rev., Sci. Eng. 1988, 30, 249.
14. Lee, J.; Grabowski, J. J. Reactions of the Atomic Oxygen Radical Anion and the Synthesis of Organic Reactive Intermediates. Chem. Rev. 1992, 92, 1611.
15. 2 from 300K to Relative Kinetic Energies of ∼2eV. J. Chem. Phys. 1975, 63, 3238.
16. 3 Catalyst. To be published.
17. 2 by Dissociative Electron Attachment. Chem. Phys. Lett. 1983, 96, 681.
18. Otsuka, K.; Shimizu, Y.; Komatsu, T. Ba Doped Cerium Oxides Active for Oxidative Coupling of Methane. Chem. Lett. 1987, 1835.
19. 4. Chem. Phys. Lett. 1995, 232, 554 and references therein.
20. Tiernan, T. O. In Interactions between Ions and Molecules; Ausloos, P., Ed.; Plenum Press: New York 1975; p 353.
21. Viggiano, A. A.; Morris, R. A.; Paulson, J. F. Rotational Temperature Dependences of Gas Phase Ion-molecule Reactions. J. Chem. Phys. 1988, 89, 4848.
22. n (n = 0-2). J. Phys. Chem. 1990, 94, 8193.
23. 4 and its Catalytic Performance for the Oxidative Coupling of Methane. Bull. Chem. Soc. Jpn. 1993, 66, 1799.