Evidence for ester-exchange reactions and cyclic oligomer formation in the ring-opening polymerization of lactide with aluminum complex initiators

Macromolecules

Volumn 29, Issue 20, 1996, Pages 6461-6465

  Montaudo, Giorgio ^a   Montaudo, Maurizio S ^b   Puglisi, Concetto ^b   Samperi, Filippo ^b   Spassky, N ^c   LeBorgne, Alain ^c   Wisniewski, Muriel ^c  

^a UNIVERSITY OF CATANIA   (Italy)

^b CNR   (Italy)

^c SORBONNE UNIVERSITÉ   (France)

Author keywords

[No Author keywords available]

Indexed keywords

ALUMINUM COMPOUNDS; CHEMICAL REACTIONS; INITIATORS (CHEMICAL); IONIZATION; MASS SPECTROMETRY; MOLECULAR WEIGHT DISTRIBUTION; OLIGOMERS; RING OPENING POLYMERIZATION; SYNTHESIS (CHEMICAL);

ALUMINUM ALKOXIDE INITIATOR; CYCLIC OLIGOMER; ESTER EXCHANGE REACTIONS; INTRAMOLECULAR ENDBITTING REACTIONS; POLYLACTIDES;

AROMATIC POLYMERS;

EID: 0030243629     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma960538i     Document Type: Article

References (31)

1. Kharas, G. B.; Sanchez-Riera, F.; Sevenson, D. K. In Plastics from microbes; Mobley, D. P., Ed.; Hanser Publishers: Munich, 1994; Chapter 4, p 93.
2. Vert, M.; Li, S. M.; Spenlehauer, G.; Guerin, P. J. Mater. Sci., Mater. Med. 1992, 3, 432.
3. Kricheldorf, M. R.; Berl, M.; Scharnagl, N. Macromolecules 1988, 21, 286.
4. Dubois, P.; Jacobs, C.; Jerome, R.; Teyssié, P. Macromolecules 1991, 24, 2266.
5. Song, C. X.; Feng, X. D. Macromolecules 1984, 17, 2764.
6. Trofimoff, L.; Aida, T.; Inoue, S. Chem. Lett. 1987, 991.
7. Chabot, F.; Vert, M.; Chapelle, S.; Granger, P. Polymer 1983, 24, 53.
8. Bero, M.; Kasperczyk, J.; Jedlinski, Z. Makromol. Chem. 1988, 191, 2287.
9. Penczek, S.; Duda, A.; Szymanski, R. Polym. Prepr., Div. Polym. Sci. Am. Chem. Soc. 1996, 37, 219.
10. LeBorgne, A.; Wisniewski, M.; Spassky, N. Polym. Prepr., Div. Polym. Sci. Am. Chem. Soc. 1995, 36, 217.
11. LeBorgne, A.; Wisniewski, M. Macromolecules, in press.
12. Wisniewski, M. Doctoral Thesis, Paris, 1995.
13. LeBorgne, A.; Vincens, V.; Jouglard, M.; Spassky, N. Makromol. Chem., Macromol. Symp. 1993, 173, 37.
14. Karas, M.; Hillenkamp, F. Anal. Chem. 1988, 60, 2299.
15. Bahr, U.; Deppe, A.; Karas, M.; Hillenkamp, F.; Giessman, U. Anal. Chem. 1992, 64, 2866.
16. Danis, P. O.; Karr, D. E.; Mayer, F.; Holle, A.; Watson, C. H. Org. Mass Spectrosc. 1992, 27, 843. Danis, P. O.; Karr, D. E. Org. Mass Spectrom. 1993, 28, 923.
17. Danis, P. O.; Karr, D. E.; Mayer, F.; Holle, A.; Watson, C. H. Org. Mass Spectrosc. 1992, 27, 843. Danis, P. O.; Karr, D. E. Org. Mass Spectrom. 1993, 28, 923.
18. Montaudo, G.; Montaudo, M. S.; Puglisi, C.; Samperi, F. Anal. Chem. 1994, 66, 4366; Rapid Commun. Mass Spectrom. 1994, 8, 981; 1994, 8, 1011; 1995, 9, 453; Macromolecules 1995, 28, 4562.
19. Montaudo, G.; Montaudo, M. S.; Puglisi, C.; Samperi, F. Anal. Chem. 1994, 66, 4366; Rapid Commun. Mass Spectrom. 1994, 8, 981; 1994, 8, 1011; 1995, 9, 453; Macromolecules 1995, 28, 4562.
20. Montaudo, G.; Montaudo, M. S.; Puglisi, C.; Samperi, F. Anal. Chem. 1994, 66, 4366; Rapid Commun. Mass Spectrom. 1994, 8, 981; 1994, 8, 1011; 1995, 9, 453; Macromolecules 1995, 28, 4562.
21. Montaudo, G.; Montaudo, M. S.; Puglisi, C.; Samperi, F. Anal. Chem. 1994, 66, 4366; Rapid Commun. Mass Spectrom. 1994, 8, 981; 1994, 8, 1011; 1995, 9, 453; Macromolecules 1995, 28, 4562.
22. Montaudo, G.; Montaudo, M. S.; Puglisi, C.; Samperi, F. Anal. Chem. 1994, 66, 4366; Rapid Commun. Mass Spectrom. 1994, 8, 981; 1994, 8, 1011; 1995, 9, 453; Macromolecules 1995, 28, 4562.
23. Montaudo, G.; Montaudo, M. S.; Puglisi, C.; Samperi, F. Rapid Commun. Mass Spectrom. 1995, 9, 1158; Macromolecules 1995, 28, 7983; J. Polym. Sci., Polym. Chem. Ed. 1996, 34, 439.
24. Montaudo, G.; Montaudo, M. S.; Puglisi, C.; Samperi, F. Rapid Commun. Mass Spectrom. 1995, 9, 1158; Macromolecules 1995, 28, 7983; J. Polym. Sci., Polym. Chem. Ed. 1996, 34, 439.
25. Montaudo, G.; Montaudo, M. S.; Puglisi, C.; Samperi, F. Rapid Commun. Mass Spectrom. 1995, 9, 1158; Macromolecules 1995, 28, 7983; J. Polym. Sci., Polym. Chem. Ed. 1996, 34, 439.
26. Montaudo, G. Trends Polym. Sci. 1996, 4, 81.
27. Dubois Ph.; Jerome R.; Teyssié Ph. Polym. Prepr. Div. Polym. Sci., Am. Chem. Soc. 1994, 35, 596.
28. Montaudo, G.; Montaudo, M. S.; Scamporrino, E.; Vitalini, D. Macromolecules 1992, 25, 5099.
29. Montaudo, G. Macromolecules 1991, 24, 5829.
30. Semlyen, J. A In Cyclic Polymers; Elsevier: New York, 1986.
31. Maravigna, P.; Montaudo, G. In Comprehensive Polymer Science; Allen, G.; Bevington, J. C., Eds.; Pergamon Press: New York, 1989; Vol. 5.