High-pressure PVT behavior of natural fats and oils, trilaurin, triolein, and n-tridecane from 303 K to 353 K from atmospheric pressure to 150 MPa

Journal of Chemical and Engineering Data

Volumn 41, Issue 5, 1996, Pages 961-969

  Acosta, G M ^a,b   Smith Jr , R L ^a   Arai, K ^a  

^a TOHOKU UNIVERSITY   (Japan)

^b Charleston Research Company LLC   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

COMPOSITION EFFECTS; CORRELATION METHODS; CRYSTALLINE MATERIALS; DEGREES OF FREEDOM (MECHANICS); HIGH PRESSURE EFFECTS; IODINE; MATHEMATICAL MODELS; THERMAL EFFECTS;

FLORY EQUATIONS; IODINE VALUE; SIMPLIFIED PERTURBED HARD CHAIN THEORY (SPHCT); TAIT EQUATIONS; TRIDECANE; TRILAURIN; TRIOLEIN;

OILS AND FATS;

EID: 0030230631     PISSN: 00219568     EISSN: None     Source Type: Journal    
DOI: 10.1021/je960006x     Document Type: Article

References (23)

1. Acosta, G. M. Solubility, High Pressure Phase Behavior, and Solid-Liquid Equilibria of Fats and Oils. Experimental Measurements and Model Development for Triglyceride Systems. Ph.D. Thesis, University of South Carolina, Columbia, South Carolina, 1995.
2. Acosta, G. M.; Smith, Jr., R. L.; Walsh, J. E.; Boni, K. A. Beef Shank Fat Solubility in Supercritical Carbon Dioxide-Propane Mixtures and in Liquid Propane. J. Food Sci. 1995, 60 (5), 983-987.
3. Ashour, I.; Hammam, H. Equilibrium Solubility of Pure Mono-, Di-, and Trilaurin in Supercritical Carbon Dioxide- Experimental Measurements and Model Prediction. J. Supercrit. Fluids 1993, 6, 3-8.
4. Bamberger, T.; Erickson, J. C.; Cooney, C. L. Measurement and Model Prediction of Solubilities of Pure Fatty Acids, Pure Triglycerides, and Mixtures of Triglycerides in Supercritical Carbon Dioxide. J. Chem. Eng. Data 1988, 33 (3), 327-333.
5. Bharath, R.; Inomata, H.; Adschiri, T.; Arai, K. Phase Equilibrium Study for the Separation and Fractionation of Fatty Oil Components using Supercritical Carbon Dioxide. Fluid Phase Equilib. 1992, 81, 307-320.
6. Fakhreddine, Y. A.; Zoller, P. Thermophysical Properties of Azomethine Ether Main-Chain Liquid Crystalline Polymers at Pressures to 200 MPa. J. Polym. Sci., Polym. Phys. Ed. 1994, 32 (15), 2445-2459.
7. Flory, P. J.; Orwoll, R. A.; Vrij, A. Statistical Thermodynamics of Chain Molecule Liquids. I. An Equation of State for Normal Paraffin Hydrocarbons. J. Am. Chem. Soc. 1964, 86, 3507-3520.
8. Halvorsen, J. D.; Mammel, W. C.; Clements, L. D. Density Estimation for Fatty Acids and Vegetable Oils Based on their Fatty Acid Composition. J. Am. Oil Chem. Soc. 1993, 70, 875-880.
9. Hederer, H.; Peter, S.; Wenzel, H. Calculation of Thermodynamic Properties from a Modified Redlich-Kwong Equation of State. Chem. Eng. J. 1976, 11, 183-190.
10. Kim, C.; Vimalchand, P.; Donohue, M. D.; Sandler, S. I. Local Composition Model for Chainlike Molecules: A New Simplified Version of the Perturbed Hard Chain Theory. AIChE J. 1986, 32 (1), 1726-1734.
11. King, J. W.; Johnson, J. H.; Friedrich, J. P. Extraction of Fat Tissue from Meat Products with Supercritical Carbon Dioxide. J. Agric. Food Chem. 1989, 37, 951-954.
12. Krogh, F. T. Efficient Algorithms for Polynomial Interpolation and Numerical Differentiation. Math. Comp. 1970, 24, 185-190.
13. Kumar, S. K.; Suter, U. W.; Reid, R. C. A Statistical Mechanics Based Lattice Model Equation of State. Ind. Eng. Chem. Res. 1987, 26, 2532-2542.
14. Ohgaki, K.; Tsukahara, I.; Semba, K.; Katayama, T. A Fundamental Study of Extraction with a Supercritical Fluid. Solubilities of α-Tocopherol, Palmitic Acid, and Tripalmitin in Compressed Carbon Dioxide at 25 C and 40 C. Int. Chem. Eng. 1989, 29 (2), 302-308.
15. Ollivon, M.; Perron, R. Measurement of Enthalpies and Entropies of Unstable Crystalline Forms of Saturated Even Monoacid Triglycerides. Thermochim. Acta 1982, 53, 183-194.
16. Peng, D.-Y.; Robinson, D. B. A New Two-Constant Equation of State. Ind. Eng. Chem. Fundam. 1976, 15, 59-64.
17. SAS Institute Inc. SAS/STAT software, Version 6.08, Cary, North Carolina, 1993.
18. Stahl, E.; Quirin, K. W.; Gerard, D. Dense Gases for Extraction and Refining; Springer-Verlag: Berlin, 1988.
19. Swern, D. Bailey's Industrial Oils and Fats Products, 4th ed.; John Wiley & Sons: New York, 1979; Vol. 1.
20. Tilly, K. D.; Chaplin, R. P.; Foster, N. R. Supercritical Fluid Extraction of the Triglycerides Present in Vegetable Oils. Sep. Sci. Technol. 1990, 25, 357-367.
21. Vargaftik, N. B. Handbook of Physical Properties of Liquids and Gases; Hemisphere Publishing Corp.: New York, 1975.
22. Wesdorp, L. H. Liquid - Multiple Solid Phase Equilibria in Fats - theory and experiments. Ph.D. Thesis, University of Technology, Delft, Netherlands, 1990.
23. 2. Rev. Sci. Instrum. 1976, 47 (8), 948-952.