Photochemical and non-photochemical formation and destruction of carbonyl sulfide and methyl mercaptan in ocean waters

Marine Chemistry

Volumn 54, Issue 1-2, 1996, Pages 11-26

  Flöck, Otmar R ^a   Andreae, Meinrat O ^a  

^a MAX PLANCK INSTITUTE FOR CHEMISTRY   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

CARBONYL SULPHIDE; METHYL MERCAPTAN; PHOTOCHEMICAL REACTIONS; SULPHUR COMPOUNDS;

EID: 0030222843     PISSN: 03044203     EISSN: None     Source Type: Journal    
DOI: 10.1016/0304-4203(96)00027-8     Document Type: Article

References (57)

1. Andreae, M.O., 1993. The influence of tropical biomass burning on climate and the atmospheric environment. In: R.S. Oremland (Editor), Biogeochemistry of Global Change: Relatively Active Trace Gases. Chapman and Hall, New York, NY, pp. 113-150.
2. Andreae, M.O. and Ferek, R.J., 1992. Photochemical production of carbonyl sulfide in seawater and its emission to the atmosphere. Global Biochem. Cycles, 6: 175-183.
3. Barnes, I., Becker, K.H. and Patroescu, I., 1994. The tropospheric oxidation of dimethyl sulfide: A new source of carbonyl sulfide. Geophys. Res. Lett., 21: 2389-2392.
4. Bingemer, H.G., Andreae, M.O., Andreae, T.W., Artaxo, P., Helas, G., Jacob, D.J., Mihalopoulos, N. and Nguyen, B.C., 1992. Sulfur gases and aerosols in and above the equatorial African rain forest. J. Geophys. Res., 97: 6207-6217.
5. Blezinger, S., Wilhelm, C. and Kesselmeier, J., 1994. Exchange of reduced sulfur compounds between marine phytoplankton and the ocean. In: P.M. Borrell, P. Borrell, T. Cvitas and W. Seiler (Editors), Transport and Transformation of Pollutants in the Troposphere, Proceedings of EUROTRAC Symposium 1994, Garmisch-Partenkirchen, Federal Republic of Germany. SPB Academic Publishing, The Hague, pp. 559-562.
6. 2 and their distribution. Global Biogeochem. Cycles, 7: 321-337.
7. Conrad, R., Seiler, W., Bunse, G. and Giel, H., 1982. Carbon monoxide in seawater (Atlantic Ocean). J. Geophys. Res., 87: 8839-8852.
8. Cooper, A.J.L., 1983. Biochemistry of sulfur-containing amino acids. Ann. Rev. Biochem., 52: 187
9. Crutzen, P.J., 1976. The possible importance of CSO for the sulfate layer of the stratosphere. Geophys. Res. Lett., 3: 73-76.
10. 3Cl, and COS. Nature (London), 282: 253-256.
11. Cutter, G.A. and Radford-Knoery, J., 1993. Carbonyl sulfide in two estuaries and shelf waters of the western North Atlantic Ocean. Mar. Chem., 43: 225-233.
12. De Bruyn, W.J., Swartz, E., Hu, J.H., Shorter, J.A., Davidovits, P., Worsnop, D.R., Zahniser, M.S. and Kolb, C.E., 1995. Henry's law solubilities and Setchenow coefficients for reduced sulfur species obtained from gas-liquid uptake measurements. J. Geophys. Res., 100(D4): 7245-7251.
13. Doney, S., Najjar, R.G. and Steward, S., 1995. Photochemistry, mixing and diurnal cycles in the upper ocean. J. Mar. Res., 53: 341-369.
14. Elliott, S., Lu, E. and Rowland, S.F., 1987. Carbonyl sulfide hydrolysis as a source of hydrogen sulfide in open ocean seawater. Geophys. Res. Lett., 14: 131-134.
15. Elliott, S., Lu, E. and Rowland, S.F., 1989. Rates and mechanisms for the hydrolysis of carbonyl sulfide in natural waters. Environ. Sci. Technol., 23: 458-461.
16. Fall, R., Albritton, D.L., Fehsenfeld, F.C. and Kuster, W.C., 1988. Laboratory studies of some environmental variables controlling sulfur emissions from plants. J. Atmos. Chem., 6: 341-362.
17. Ferek, R.J. and Andreae, M.O., 1983. The supersaturation of carbonyl sulfide in surface waters of the Pacific Ocean off Peru. Geophys. Res. Lett., 10: 393-396.
18. Ferek, R.J. and Andreae, M.O., 1984. Photochemical production of carbonyl sulfide in marine surface waters. Nature (London), 307: 148-150.
19. Garratt, J.R., 1977. Review of drag coefficients over oceans and continents. Mon. Weather Rev., 10: 915-929
20. Goldan, P.D., Kuster, W.C., Albritton, D.L. and Fehsenfeld, F.C., 1987. The measurement of natural sulfur emission from soils and vegetation: Three sites in the eastern United States revised. J. Atmos. Chem., 5: 439-468.
21. Goldan, P.D., Fall, R., Kuster, W.C. and Fehsenfeld, F.C., 1988. Uptake of COS by growing vegetation: A major tropospheric sink. J. Geophys. Res., 93: 14, 186-14, 192.
22. Himmelblau, D.M., 1964. Diffusion of dissolved gases in liquids. Chem. Rev., 64: 527-550
23. Inn, E.C.Y., Vedder, J.F. and Tyson, B.J., 1979. COS in the stratosphere. Geophys. Res. Lett., 6: 191-193.
24. Johnson, J.E., 1981. The lifetime of carbonyl sulfide in the troposphere. Geophys. Res. Lett., 8: 934-940.
25. Johnson, J.E. and Harrison, H., 1986. Carbonyl sulfide concentrations in the surface waters and above the Pacific Ocean. J. Geophys. Res., 91: 7883-7888.
26. Johnson, J.E., Bandy, A.R., Thornton, D.C. and Bates, T.S., 1993. Measurements of atmospheric carbonyl sulfide during the NASA Chemical Instrumentation Test and Evaluation Project: Implications for the global COS budget. J. Geophys. Res., 98(D12): 23,443-23,448.
27. 2. Chem. Phys. Lett., 88: 372-376.
28. Katayama, Y., Narahara, Y., Inoue, Y., Amano, F., Kanagawa, T. and Kuraishi, H., 1992. A thiocyanate hydrolase of Thiobacillus thioparus. J. Biol. Chem., 267: 9170-9175.
29. Keller, M.D., Bellows, W.K. and Guillard, R.L., 1989. Dimethyl sulfide production in marine phytoplankton. In: E.S. Saltzman and Cooper D.J. (Editors), Biogenic Sulfur in the Environment. Am. Chem. Soc., Washington, DC, pp. 169-179.
30. Kesselmeier, J. and Merk, L., 1993. Exchange of carbonyl sulfide (COS) between agricultural plants and the atmosphere: Studies on the deposition of COS to peas, corn and rapeseed. Biogeochemistry, 23: 47-59.
31. Kiene, P.R. and Taylor, B.F., 1988a. Biotransformation of organosulphur compounds in sediments via 3-mercaptopropionate. Nature (London), 332: 148-150.
32. Kiene, R.P. and Taylor, B.F., 1988b. Demethylation of dimethylsulfoniopropionate and production of thiols in anoxic marine sediments. Appl. Environ. Microbiol., 54: 2208-2212.
33. Liss, P.S. and Merlivat, L., 1986. Air-sea gas exchange rates: introduction and synthesis. In: P. Buat-Ménard (Editor), The Role of Air-Sea Exchange in Geochemical Cycling. D. Reidel, Hingham, MA, pp. 113-127.
34. Liss, P.S. and Slater, P.G., 1974. Flux of gases across the air-sea interface. Nature (London), 247: 181-184
35. 2. Nature (London), 281: 185-188.
36. McCartney, M.S. and Talley, L.D., 1982. The subpolar mode of the North Atlantic Ocean. J. Phys. Oceanogr., 12: 1169-1188.
37. Mihalopoulos, N., Putaud, J.P., Nguyen, B.C. and Belviso, S., 1991. Annual variation of carbonyl sulfide in the marine atmosphere in the southern Indian Ocean. J. Atmos. Chem., 13: 73-82.
38. Najjar, R.G., Erickson III, D.J. and Madronich, S., 1995. Modeling the air-sea fluxes of gases from the decomposition of dissolved organic matter: Carbonyl sulfide and carbon monoxide. In: R. Zepp and C. Sonntag (Editors), The Role of Non-Living Organic Matter in the Earth's Carbon Cycle. Wiley, New York, NY, pp. 107-132.
39. Preisendorfer, R.W., 1976. Hydrologic Optics, Vol. 5. U.S. Dep. Commer., NOAA (Natl. Ocean. Atmos. Adm.) Environ. Res. Lab., Washington, DC, pp. 255-259.
40. Protoschill-Krebs, G. and Kesselmeier, J., 1992. Enzymatic pathways for the consumption of carbonyl sulphide (COS) by higher plants. Bot. Acta, 105: 206-212.
41. 2 growing regimes. Bot. Acta, 5: 403-466.
42. Radford-Knoery, J. and Cutter, G.A., 1993. Determination of carbonyl sulfide and hydrogen sulfide species in natural waters using specialized collection procedures and chromatography with flame photometric detection. Anal. Chem., 65: 976-982.
43. Radford-Knoery, J. and Cutter, G.A., 1994. Biogeochemistry of dissolved hydrogen sulfide species and carbonyl sulfide in the western North Atlantic Ocean. Geochim. Cosmochim. Acta, 58: 5421-5431.
44. Rowland, F.S., 1979. The atmospheric and oceanic sinks for carbonyl sulfide. 4th Int. Conf., Comm. Atmos. Chem. Global Pollut., Boulder, CO, Aug. 1979, Abstr. IV-6.
45. Sharma, M.M., 1965. Kinetics of reactions of carbonyl sulphide and carbon dioxide with amines and catalysis by Brønsted bases of the hydrolysis of COS. Trans. Faraday Soc., 61: 681-688.
46. Siedler, G. and Peters, H. 1986. Properties of sea water. In: J. Sündermann (Editor), Oceanography, Landolt-Börnstein, New Series, Group V, Vol. 3a. Springer, Berlin, pp. 233-264
47. Smith, R.C. and Baker, K.S., 1981. Optical properties of the clearest natural waters (200-800 nm). Appl. Opt., 20: 177-184.
48. 2 from various soils in Germany. Tellus, 41B: 305-313.
49. Torres, A.L., Maroulis, P.J., Goldberg, A.B. and Bandy, A.R., 1980. Atmospheric OCS measurements on project GAMETAG. J. Geophys. Res., 85: 7357-7360.
50. Turco, R.P., Whitten, R.C., Toon, O.B., Pollack, J.B. and Hamill, P., 1980. OCS, stratospheric aerosols and climate. Nature (London), 283: 238-286.
51. Uher, G., 1994. Photochemische Produktion von Carbonyl Sulfid (COS) im Oberflächenwasser der Ozeane: Prozeßstudien und ein empirisches Modell. Ph.D. Dissertation, Johannes-Gutenberg-Universität, Mainz.
52. Uher, G. and Andreae, M.O., 1994. The diurnal cycle of carbonyl sulfide in seawater: A simple empirical model. In: P.M. Borrell, P. Borrell, T. Cvitas and W. Seiler (Editors), Transport and Transformation of Pollutants in the Troposphere, Proceedings of EUROTRAC Symposium 1994, Garmisch-Partenkirchen, Federal Republic of Germany. SPB Academic Publishing, The Hague, pp. 563-567.
53. Ulshöfer, V.S., Flöck, O.R., Uher, G., Rapsomanikis, S, and Andreae, M.O., 1994. Variability of carbonyl sulfide (COS) concentrations in the Mediterranean Sea and in the Northeast Atlantic. In: P.M. Borrell, P. Borrell, T. Cvitas and W. Seiler (Editors), Transport and Transformation of Pollutants in the Troposphere, Proceedings of EUROTRAC Symposium 1994, Garmisch-Partenkirchen, Federal Republic of Germany. SPB Academic Publishing, The Hague, pp. 568-572.
54. Ulshöfer, V.S., Flöck, O.R., Uher, G. and Andreae, M.O., 1996. Photochemical production and air-sea exchange of carbonyl sulfide in the Eastern Mediterranean Sea. Mar. Chem., 53: 25-39.
55. Weiss, P.S., Andrews, S.S., Johnson, J.E. and Zafiriou, O.C., 1995. Photoproduction of carbonyl sulfide in South Pacific Ocean waters as a function of irradiation wavelength. Geophys. Res. Lett., in press.
56. 2 photooxidation in tropospheric sulfur chemistry. Geophys. Res. Lett., 8: 543-546.
57. Zepp, R.G. and Andreae, M.O., 1994. Factors affecting the photochemical production of carbonyl sulfide in seawater. Geophys. Res. Lett., 21: 2813-2816.