Electrosynthesis of sulfur-containing organic compounds from allene derivatives using a sacrificial mixed sulfur/graphite electrode

Electrochimica Acta

Volumn 41, Issue 13, 1996, Pages 1987-1991

  Kunugi, Akira ^a   Kuwamura, Kimiko ^a   Inoue, Masao ^a   Kawamura, Yasuhiko ^a   Abe, Kyo ^b  

^a UNIVERSITY OF TOKUSHIMA   (Japan)

^b Osaka Prefecture University   (Japan)

Author keywords

Allene; Electrosynthesis; Organosulfur compound; Sulfur graphite electrode

Indexed keywords

ADDITION REACTIONS; ATOMS; DERIVATIVES; ELECTROCHEMICAL ELECTRODES; ELECTROCHEMISTRY; IONS; ORGANIC COMPOUNDS; POLYSULFIDES; PROTONS; REDUCTION; SOLUBILITY; SULFUR;

ALLENE DERIVATIVES; ELECTROREDUCTION; ELECTROSYNTHESIS; ORGANOSULFUR COMPOUNDS; PROTON DONORS; SACRIFICIAL MIXED SULFUR GRAPHITE ELECTRODE;

SYNTHESIS (CHEMICAL);

EID: 0030216560     PISSN: 00134686     EISSN: None     Source Type: Journal    
DOI: 10.1016/0013-4686(96)00002-3     Document Type: Article

References (14)

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13. 1H-NMR spectrum is also supportive to the validity of the proposed structure. For example, there has no observation of magnetic nonequivalence, although ethyl 2-bromo-n-butyrate has the similar ester methylene protons in the vicinity of a chiral center. The present peculiarity of the geminal protons seems to be caused mainly by a steric congestion between one perimeter phenyl group and the ester group constrained by the proposed 1,2,3-tri-thiolane skeleton.
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