Diels-Alder reactions of [(S)R]-(1E,3E)-1-p-tolylsulfinyl-1,3-pentadiene: The unexpected evolution of maleic anhydride adducts

Tetrahedron Asymmetry

Volumn 7, Issue 7, 1996, Pages 2151-2158

  Carreño, M Carmen ^a   Cid, M Belén ^a   García Ruano, José L ^a  

^a UNIVERSIDAD AUTÓNOMA DE MADRID   (Spain)

Author keywords

[No Author keywords available]

Indexed keywords

BENZOFURAN DERIVATIVE; CARBOXYLIC ACID DERIVATIVE; CYCLOALKENE;

ARTICLE; CHIRALITY; DRUG PURITY; DRUG SYNTHESIS; NUCLEAR MAGNETIC RESONANCE; PRIORITY JOURNAL; REACTION ANALYSIS; STEREOCHEMISTRY;

EID: 0030201016     PISSN: 09574166     EISSN: None     Source Type: Journal    
DOI: 10.1016/0957-4166(96)00258-3     Document Type: Article

References (22)

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21. 12.-Intermediate C could also arise from the hydrolytic attack at sulfur, opening the acyloxysulfonium intermediate (S)R-A.
22. 13.-The diene recovered from reactions interrupted before completion was enantiomerically pure.