Direct vinylation and ethynylation of nitrones. Stereodivergent synthesis of allyl and propargyl amines

Tetrahedron Asymmetry

Volumn 7, Issue 7, 1996, Pages 1887-1890

  Merino, Pedro ^a   Anoro, Sonia ^a   Castillo, Elena ^a   Merchan, Francisco ^a   Tejero, Tomas ^a  

^a UNIVERSITY OF ZARAGOZA   (Spain)

Author keywords

[No Author keywords available]

Indexed keywords

ALLYLAMINE DERIVATIVE; AMINE;

ARTICLE; DRUG SYNTHESIS; PRIORITY JOURNAL; REACTION ANALYSIS; STEREOCHEMISTRY; TECHNIQUE;

EID: 0030200997     PISSN: 09574166     EISSN: None     Source Type: Journal    
DOI: 10.1016/0957-4166(96)00222-4     Document Type: Article

References (31)

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18. -)R (nitrone)
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28. 3) δ 0.95 (s, 9H), 3.62 (dd, 1H, J = 3.4, 11.6 Hz), 3.83 (dd, 1H, J = 3.7, 11.6 Hz), 3.98 (d, 1H, J = 15.0 Hz), 4.03 (dd, 1H, J = 6.9, 8.7 Hz), 4.15 (ddd, 1H, J = 3.4, 3.7, 6.9 Hz), 4.81 (d, 1H, J = 15.0 Hz), 5.14 (d, 1H, J = 17.0 Hz), 5.30 (d, 1H, J = 9.9 Hz), 5.65 (ddd, 1H, J= 8.7, 9.9, 17.0 Hz), 7.28-7.64 (m, 15H).
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30. 5 for 4b, no nOe was detected between the same protons for 4 a.
31. 3).