Pulse radiolysis investigations of solvation effects on arylmethyl cation reactivity in supercritical fluids

Journal of Physical Chemistry

Volumn 100, Issue 30, 1996, Pages 12394-12402

  Zhang, Jianwei ^a   Connery, Karen A ^a   Brennecke, Joan F ^a   Chateauneuf, John E ^a  

^a UNIVERSITY OF NOTRE DAME   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ETHANE; FLUOROCARBONS; ORGANIC COMPOUNDS; PRESSURE EFFECTS; RADIATION EFFECTS; REACTION KINETICS;

ARYLMETHYL CATIONS; DIELECTRIC CONSTANTS; FLUOROFORMS; NUCLEOPHILIC REACTIONS; PULSE RADIOLYSIS; REACTIVITY; SOLVATION EFFECTS; SUPERCRITICAL FLUIDS;

IONS;

EID: 0030197441     PISSN: 00223654     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp961033x     Document Type: Article

References (41)

1. Savage, P. E.; Gopalan, S.; Mizan, T. I.; Martino, C. J.; Brock, E. E. AIChE J. 1995, 41, 1723.
2. Roberts, C. B.; Zhang, J.; Brennecke, J. F.; Chateauneuf, J. E. J. Phys. Chem. 1993, 97, 5618.
3. Roberts, C. B.; Zhang, J.; Chateauneuf, J. E.; Brennecke, J. F. J. Am. Chem. Soc. 1993, 115, 9576.
4. Roberts, C. B.; Chateauneuf, J. E.; Brennecke, J. F. J. Am. Chem. Soc. 1992, 114, 8455.
5. Ellington, J. B.; Park, K. M.; Brennecke, J. F. Ind. Eng. Chem. Res. 1994, 33, 965.
6. Roberts, C. B.; Brennecke, J. F.; Chateauneuf, J. E. AIChE J. 1995, 41, 1306.
7. Roberts, C. B.; Zhang, J.; Chateauneuf, J. E.; Brennecke, J. F. J. Am. Chem. Soc. 1995, 117, 6553.
8. Zhang, J.; Connery, K. A.; Chateauneuf, J. E.; Brennecke, J. F. "Pulse Radiolysis to Study Intermolecular Interactions and Reactivity in Supercritical Fluids. In Innovations in Supercritical Fluids; ACS Symposium Series 608; Hutchenson, K., Foster, N., Eds.; American Chemical Society: Washington, DC, 1995; pp 156-165.
9. Janata, E.; Schuler, R. H. J. Phys. Chem. 1982, 86, 2078.
10. Zhang, J.; Connery, K. A.; Strebinger, R. B.; Brennecke, J. F.; Chateauneuf, J. E. Rev. Sci. Instrum. 1995, 66, 3555.
11. Hori, K.; Okazaki, S.; Uematsu, M.; Watanabe, K. Proc. Symp. Therm. Prop. 1982, 8, 380.
12. Cram, D. J. Fundamentals of Carbanion Chemistry; Academic Press: New York, 1965.
13. Olah, G. A.; Schleyer, P. V. R. Carbonium Ions; Interscience: New York, 1968; Vol. I and II.
14. Das, P. K. Chem. Rev. 1993, 93, 119.
15. Dorfman, L. M.; Sujdak, R. J.; Bockrath, B. Acc. Chem. Res. 1976, 9, 352.
16. DePalma, V. M.; Wang, Y.; Dorfman, L. M. J. Am. Chem. Soc. 1978, 100, 5416.
17. Roberts, C. B.; Brennecke, J. F.; Chateauneuf, J. E. J. Chem. Soc., Chem. Commun. 1993, 868.
18. Steenken, S.; McClelland, R. A. J. Am. Chem. Soc. 1989, 111, 4967.
19. Reichardt, C. Solvent and Solvent Effects in Organic Chemistry, 2nd ed.; VCH Verlagsgesellschaft mbH: D-6940 Weinheim, FRG, 1988.
20. Bottcher, C. J. F.; Van Belle, O. C.; Bordewilk, P.; Rip, A. Theory of Electric Polarization, 2nd ed.; Elsevier: Amsterdam, 1973.
21. Drude, P.; Nernst, W. Z. Phys. Chem. 1894, 1, 79.
22. Peng, D. Y.; Robinson, D. B. Ind. Eng. Chem. Fundam. 1976, 15, 59.
23. Wood, R. H.; Quint, J. R.; Groller, J.-P. E. J. Phys. Chem. 1981, 85, 3944.
24. Quint, J. R.; Wood, R. H. J. Phys. Chem. 1985, 89, 380.
25. Makita, R.; Jubota, H.; Tanaka, Y.; Kashiwagi, H. Refrigeration 1977, 52, 543.
26. Charton, M. J. Am. Chem. Soc. 1975, 97, 1552.
27. Evans. M. G.; Polanyi, M. Trans. Faraday Soc. 1935, 31, 875.
28. Hamann, S. D.; Bradley, R. S. High Pressure Physics and Chemistry; Academic Press: London, 1963; Vol. 2, p 163.
29. Eckert, C. A.; Ziger, D. H.; Johnston, K. P.; Kim, S. J. Phys. Chem. 1986, 86, 2738.
30. Reid, R. C.; Prausnitz, J. M.; Poling, B. E. The Properties of Gases and Liquids, 4th ed.; McGraw-Hill: New York, 1987.
31. Bondi, A. Physical Properties of Molecular Crystals, Liquids, and Glasses; John Wiley & Sons, Inc.: New York, 1968; p 453.
32. Exner, O. Correlation Analysis of Chemical Data; Plenum: New York, 1988; p 152.
33. Zhang, J. Spectroscopic and Integral Equation Studies of Reactivity and Preferential Solvation in Supercritical Fluids, Ph.D. Thesis, University of Notre Dame, 1995.
34. Younglove, B. A.; Ely, J. F. J. Phys. Chem. Ref. Data 1987, 16, 577.
35. Downing, R. C. Fluorocarbon Refrigerants Handbook; Prentice Hall: Englewood Cliffs, NJ, 1988.
36. Amis, E. S. Solvent Effects on Reaction Rates and Mechanisms; Academic Press: New York, 1966.
37. Amis, E. S.; Hinton, J. F. Solvent Effects on Chemical Phenomena; Academic Press: New York, 1973; Vol. 1.
38. Kim, S.; Johnston, K. P. AIChE J. 1987, 33, 1603.
39. Kim, S.; Johnston, K. P. Ind. Eng. Chem. Res. 1987, 26, 1206.
40. Yonker, C. R.; Smith, R. D. J. Phys. Chem. 1988, 92, 2374.
41. Brennecke, J. F.; Eckert, C. A. AIChE J. 1989, 35, 1409.