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Volumn 12, Issue 15, 1996, Pages 3688-3694

Electrochemistry of surface-confined mixed monolayers of 4-aminothiophenol and thiophenol on Au

Author keywords

[No Author keywords available]

Indexed keywords

AUGER ELECTRON SPECTROSCOPY; CYCLIC VOLTAMMETRY; ELECTROCHEMISTRY; FOURIER TRANSFORM INFRARED SPECTROSCOPY; GOLD; PHENOLS;

EID: 0030197389     PISSN: 07437463     EISSN: None     Source Type: Journal    
DOI: 10.1021/la9507390     Document Type: Article
Times cited : (124)

References (80)
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    • Polymeric Reagents and Catalysts; Fort, W. T., Ed.; American Chemical Society: Washington, DC
    • (f) Wulff, G. In Polymeric Reagents and Catalysts; Fort, W. T., Ed.; ACS Symposium Series 308; American Chemical Society: Washington, DC, 1986; p 186.
    • (1986) ACS Symposium Series 308 , pp. 186
    • Wulff, G.1
  • 51
    • 5844328506 scopus 로고
    • In press. As referenced in: Ulman, A.
    • King, D. E. In press. As referenced in: Ulman, A. MRS Bull. 1995, 20, 46.
    • (1995) MRS Bull. , vol.20 , pp. 46
    • King, D.E.1
  • 69
    • 5844317893 scopus 로고
    • Oae, S., Ed.; Plenum: New York, Chapter 5
    • Ohno, A. In Organic Chemistry of Sulfur; Oae, S., Ed.; Plenum: New York, 1977; Chapter 5, p 201.
    • (1977) Organic Chemistry of Sulfur , pp. 201
    • Ohno, A.1
  • 70
    • 0003867806 scopus 로고
    • The intensity of the N Auger transition at 379 eV was not analytically useful due to its relatively low crosssection, which is a factor of 3 less than that of the S 152 eV transition. We took the following precautions to minimize the effects of beam damage to the films (see: Dubois, L. H.; Zegarski, B. R.; Nuzzo, R. G. J. Chem. Phys. 1993, 98, 678). Experiments were carried out so that the beam current densities were as small as possible and so that the Spectra were collected in the minimum possible time. Auger coverage data are based on averaging intensities obtained from several spots on a given sample and at least three repeat runs. There was no evidence of significant beam damage.
    • (1993) J. Chem. Phys. , vol.98 , pp. 678
    • Dubois, L.H.1    Zegarski, B.R.2    Nuzzo, R.G.3
  • 71
    • 5844346153 scopus 로고    scopus 로고
    • note
    • In the case of both molecules, electrochemical blocking experiments indicate that, for single-component films, nearly a complete monolayer is formed. See also ref 9.
  • 72
    • 5844224822 scopus 로고    scopus 로고
    • note
    • The presence of TP on the surface was verified by Auger spectroscopy.
  • 78
    • 0008263318 scopus 로고
    • Infrared band assignments were based on ref 20 and the following: (a) Lin-Vien, D.; Colthup, N. B.; Fateley, W. G.; Grasselli, J. G. The Handbook of Infrared and Roman Characteristic Frequencies of Organic Molecules; Academic Press, Boston, 1991; Chapters 10 and 17. (b) Green, J. H. S. Spectrochim. Acta 1968, 24A, 1627.
    • (1968) Spectrochim. Acta , vol.24 A , pp. 1627
    • Green, J.H.S.1
  • 79
    • 5844235976 scopus 로고    scopus 로고
    • note
    • The same result is obtained if one plots the integrated peak areas.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.