Anodic overoxidation of polythiophenes in wet acetonitrile electrolytes

Electrochimica Acta

Volumn 41, Issue 11-12, 1996, Pages 1761-1771

  Barsch, Ulrich ^a   Beck, Fritz ^a  

^a UNIVERSITY OF DUISBURG ESSEN   (Germany)

Author keywords

Conducting polymers; Overoxidation; Poly(3)methylthiophene; Polybithiophene; Polythiophene; Polythiophenedioxide

Indexed keywords

ANODIC OXIDATION; COMPOSITION EFFECTS; ELECTROPOLYMERIZATION; MOLECULAR STRUCTURE; MONOMERS; ORGANIC POLYMERS; STOICHIOMETRY; SULFUR DIOXIDE; WATER;

ANODIC OVEROXIDATION; CONDUCTING POLYMERS; POLY(3 METHYLTHIOPHENE); POLYBITHIOPHENE; POLYTHIOPHENE; POLYTHIOPHENEDIOXIDE;

CONDUCTIVE PLASTICS;

EID: 0030194860     PISSN: 00134686     EISSN: None     Source Type: Journal    
DOI: 10.1016/0013-4686(95)00493-9     Document Type: Article

References (57)

1. H. Shirakawa and S. Ikeda, Polym. J. 2, 231 (1971).
2. A. Angeli and L. Alessandri, Gazz. Chim. Ital. 46, II, 283 (1916).
3. A. Dall'Olio, Y. Dascota, V. Vaaracca and V. Bocci, C.R. Acad. Sci., Ser. C 267, 433 (1968).
4. A. F. Diaz, K. K. Kanazawa and G. P. Gardini, J.C.S. Chem Commun. 635 (1979).
5. J. Heinze, Topics in Curr. Chem.191, 1 (1990).
6. C. K. Chiang, M. A. Druy, S. C. Gan, A. J. Heeger, A. G. McDiarmid, Y. W. Park and H. Shirakawa, J. Am. Chem. Soc. 100, 1013 (1978).
7. A. F. Diaz and J. I. Castillo, J.C.S. Chem. Commun. 397 (1980).
8. W. Rüdorff and U. Hofmann, Z. Anorg. Allg. Chem. 238, 1 (1938).
9. A. Métrot, Makromol. Chem., Macromol. Symp. 8, 39 (1987).
10. F. Beck and R. Michaelis, Werkstoffe und Korrosion, 42, 341 (1991).
11. F. Beck, U. Barsch and R. Michaelis, J. Electroanal. Chem. 351, 169 (1993).
12. F. Beck and U. Barsch, Synth. Metals 55-57, 1299 (1993).
13. F. Beck, P. Braun and M. Oberst, Ber. Bunsenges. Phys. Chem. 91, 967 (1987).
14. K. H. Dietz and F. Beck, J. Appl Electrochem. 15, 159 (1985).
15. F. Beck and A. Pruß, J. Electroanal. Chem. 216, 157 (1987).
16. V. V. Krasko, A. A. Yakovleva and Ya. M. Kolotyrkin, Elektrokhimija 22, 1432 (1986).
17. J. B. Schlenoff, Y. Fong and H. Xu, Polym. Mat. Sci. Engng. 63, 411 (1990).
18. J. B. Schlenoff and Hong, Xu, J. Electrochem. Soc. 139, 2397 (1992).
19. D.-S. Park, Y.-B. Shim and S.-M. Park, J. Electrochem. Soc. 140, 609 (1993).
20. T. Kobayashi, H. Yoneyama and H. Tamura, J. Electroanal. Chem. 177, 293 (1984).
21. D. E. Stilwell and S.-M. Park, J. Electrochem. Soc. 135, 2497 (1988).
22. D. E. Stilwell and S.-M. Park, J. Electrochem. Soc. 136, 688 (1989).
23. Y.-B. Shim, M.-S. Won and S.-M. Park, J. Electrochem. Soc. 137, 538 (1990).
24. A. G. McDiarmid et al., Europ. Pat. 36118 (University Pat. Inc., Norwalk, Conn., 1980).
25. R. Bittihn, G. Ely, F. Woeffler, H. Münstedt, H. Naarmann and D. Naegele, Makromol. Chem., Macromol. Symp. 8, 51 (1987).
26. A. Merz, Topics in Curr. Chem. 152, 49 (1990).
27. D. Curran, J. Grimshaw and S. D. Perera, Chem. Soc. Rev. 20, 391 (1991).
28. A. A. Pud, Synth. Metals 66, 1 (1994).
29. B. Krische and M. Zagorska, Mat. Sci. Forum 42, 79 (1989).
30. B. Krische and M. Zagorska, Synth Metals 28, C 262 (1989).
31. F. Beck and U. Barsch, Makromol. Chem. 194, 2725 (1993).
32. F. Beck and M. Oberst, Makromol. Chem. Macromol. Symp. 8, 97 (1987).
33. B. Wermeckes and F. Beck, Electrochim. Acta 34, 1595 (1989).
34. F. Beck, P. Braun and F. Schloten, J. Electroanal. Chem. 267, 141 (1989).
35. Sadtler Catalogue, 1979, No 55455 K/56.
36. K. E. Schulte, A. Kreutzberger and G. Bohn, Chem. Ber. 97, 3263.
37. G. Zotti and G. Schiavon, J. Electroanal. Chem. 163, 385 (1984).
38. B. Krische and M. Zagorska, Synth. Metals 28, C 257 (1989).
39. "CRC Atlas of Spectral Data and Physical Constants for Organic Compounds", 2nd edition (Edited by J. G. Grasselli and W. M. Ritchey), CRC Press, Inc., Cleveland, Ohio (1975).
40. F. Beck and U. Barsch, unpublished work.
41. F. Beck and M. Dahlhaus, J. Electroanal. Chem. 357, 289 (1993).
42. R. J. Waltman, J. Bargon and A. F. Diaz, J. Phys. Chem. 87, 1459 (1983).
43. C. Deslouis, M. M. Musiani and B. Tribollet, J. Phys. Chem. 98, 2936 (1994).
44. C. Deslouis, M. M. Musiani, B. Tribollet and M. A. Vorotyntsev, J. Electrochem. Soc. 142, 1902 (1995).
45. H. Krohn, Carbon 23, 449 (1985).
46. U. Tormin and F. Beck, Electrochim. Acta 40, 1955 (1995).
47. D. S. Houghton and A. A. Humffray, Electrochim. Acta 17, 2145 (1972).
48. M. Janda, Collection Czechoslov. Chem. Commun. 28, 2524 (1963).
49. J. Srogl, M. Janda and M. Valentová, Collection Czechoslov. Chem. Commun. 35, 148 (1970).
50. M. Janda, J. Srogl, M. Nemec and A. Janousová, Collection Czechoslov. Chem. Commun. 37, 1221 (1972).
51. I. Izumi and I. Yamamoto Denki Kagaku Oyobi Kogyo Butsuri Kagaku 51(3), 333 (1983).
52. G. Heydecke, Ph.D.-Thesis University of Duisburg (1990).
53. W. Davies, N. W. Gamble and W. E. Savige, J. Chem. Soc. 4678 (1952).
54. W. Davies and F. C. James, J. Chem. Soc. 15 (1953).
55. H. Fees and H. Wendt, in "Techniques of Electro-organic Synthesis" (Edited by N. L. Weinberg and B. V. Tilak) Part, V/III, J. Wiley & Sons, New York 1982.
56. F. Fichter, "Organische Elektrochemie", Steinkopff, Leipzig and Dresden 1942.
57. F. Beck, T. Boinowitz, G. tom Suden and E. Abdelmula, GDCh-Monographie 2, 223 (1995).