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The laser system uses Lumonics EX-510 and EX-530 for excitation wavelengths of 248 and 308 nm, Surelite lasers from Continuum for the Nd-YAG wavelengths of 266, 355, and 532 nm and a Molectron UV-24 nitrogen laser for 337 nm. All pulse durations are <10 ns, and typical pulse energies, between 5 and 50 mJ. The signals from the monochromator/photomultiplier system were initially captured by a Tektronix 2440 digitizer and transferred to a PowerMacintosh computer that controlled the experiment with software developed in the LabVIEW 3.1.1 environment from National Instruments. Other aspects of the system are similar to those described earlier: Scaiano, J. C. J. Am. Chem. Soc. 1980, 102, 7747. Scaiano, J. C.; Tanner, M.; Weir, D. J. Am. Chem. Soc. 1985, 107, 4396.
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33845376872
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The laser system uses Lumonics EX-510 and EX-530 for excitation wavelengths of 248 and 308 nm, Surelite lasers from Continuum for the Nd-YAG wavelengths of 266, 355, and 532 nm and a Molectron UV-24 nitrogen laser for 337 nm. All pulse durations are <10 ns, and typical pulse energies, between 5 and 50 mJ. The signals from the monochromator/photomultiplier system were initially captured by a Tektronix 2440 digitizer and transferred to a PowerMacintosh computer that controlled the experiment with software developed in the LabVIEW 3.1.1 environment from National Instruments. Other aspects of the system are similar to those described earlier: Scaiano, J. C. J. Am. Chem. Soc. 1980, 102, 7747. Scaiano, J. C.; Tanner, M.; Weir, D. J. Am. Chem. Soc. 1985, 107, 4396.
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Scaiano, J. C., Ed.; CRC Press: Boca Raton, FL
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Chatgilialoglu, C.1
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18
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85033869090
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note
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It will eventually be desirable to obtain kinetic data at typical polymerization temperatures (90-130°C), for example in toluene, a solvent frequently chosen for nitroxidemediated polymerizations.
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19
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85033863430
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note
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CSA causes a decrease in the quantum yield of photodecomposition of I; the observation was not pursued further, since in practice cleavage of the C-TEMPO bond is done thermally.
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20
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0009731533
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Scaiano, J. C., Ed.; CRC Press: Boca Raton, FL
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Lusztyk, J.; Kanabus Kaminska, J. M. In Handbook of Organic Photochemistry; Scaiano, J. C., Ed.; CRC Press: Boca Raton, FL, 1989; Vol. II, p 177.
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Lusztyk, J.1
Kanabus Kaminska, J.M.2
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23
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0003336875
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Li, I.1
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Shigemoto, T.4
Smith, P.B.5
Priddy, D.B.6
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