Surface activity and premicellar aggregation of some novel diquaternary gemini surfactants

JAOCS, Journal of the American Oil Chemists' Society

Volumn 73, Issue 7, 1996, Pages 885-890

  Rosen, Milton J ^a   Liu, Letian ^a  

^a CITY UNIVERSITY OF NEW YORK   (United States)

Author keywords

Amin; Cationic surfactants; CMC; Gemini surfactants; PC20; Premicellar aggregates; Quaternary ammonium; Surface tension; CMC

Indexed keywords

AGGLOMERATION; CRITICAL MICELLE CONCENTRATION; MOLECULAR STRUCTURE; OLIGOMERS; PHASE EQUILIBRIA; PHASE INTERFACES; SOLUTIONS; SURFACE PROPERTIES; SURFACE TENSION; SYNTHESIS (CHEMICAL);

ALKYL CHAINS; CATIONIC GEMINI SURFACTANTS; PREMICELLAR AGGREGATION;

SURFACE ACTIVE AGENTS;

EID: 0030194651     PISSN: 0003021X     EISSN: None     Source Type: Journal    
DOI: 10.1007/BF02517990     Document Type: Article

References (29)

1. Karabini, S., K. Esselink, P.A.J. Hilbers, B. Smit, J. Karthaukser, N.M. van Os, and R. Zana, Simulating the Self-Assembly of Gemini (Dimeric) Surfactants, Science 266:254-256 (1994).
2. Kern, F., F. Lequeux, R. Zana, and S.J. Candace, Dynamical Properties of Salt-Free Viscoelastic Micellar Solutions, Langmuir 10:1714-1723 (1994).
3. Diamant, H., and D. Andelman, Dimeric Surfactants: Spacer Chain Conformation and Specific Area at the Air/water Interface, Ibid. 10:2910-2916 (1994).
4. Gao, T., and M.J. Rosen, Dynamic Surface Tension of Aqueous Surfactant Solutions. 6. Compounds Containing Two Hydrophilic Head Groups and Two or Three Hydrophobic Groups and Their Mixtures with Other Surfactants, J. Am. Oil Chem. Soc. 71:771-776 (1994).
5. Rosen, M.J., T. Gao, Y. Nakatsuji, and A. Masuyama, Synergism in Binary Mixtures of Surfactants. 12. Mixtures Containing Surfactants with Two Hydrophilic and Two or Three Hydrophobic Groups, Colloids and Surfaces A. 88:1-11 (1994).
6. Masuyama, A., T. Kawano, Y.-P. Zhu, T. Kida, and Y. Nakatsuji, "Elasticity Index" for the Connecting Groups of Double-Chain Amphiphiles Bearing Two Hydrophilic Groups, Chem. Letters (Chem. Soc. Japan):2053-2056 (1993).
7. Rosen, M.J., Z.H. Zhu, and T. Gao, Synergism in Binary Mixture of Surfactants. 11. Mixtures Containing Mono- and Disulfonated Alkyl- and Dialkyldiphenylethers, J. Colloid Interface Sci. 157:254 (1993).
8. Zana, R., and Y. Talmon, Dependence of Aggregate Morphology on Structure of Dimeric Surfactants, Nature 362:228-229 (1993).
9. Zhu, Y.-P., A. Masuyama, Y. Kobata, Y. Nakatsuji, M. Okahara, and M.J. Rosen, Double-Chain Surfactants with Two Carboxylate Groups and Their Relation to Similar Double-Chain Compounds, J. Colloid Interface Scie. 158:40-45 (1993).
10. Zhu, Y.-P., A. Masuyama, Y. Nakatsuji, and M. Okahara, Synthesis and Properties of Bis(sulfonate) Types of Double-Chain Surfactants Bearing a Sulfur Atom in the Connecting Part, J. Jpn. Oil Chem. Soc. (Yukagaku) 42:86-94 (1993).
11. Menger, F., and C.A. Littau, Gemini Surfactants: A New Class of Self-Assembling Molecules, J. Am. Chem. Soc. 115:10083-10090 (1993).
12. Rosen, M.J., Geminis: A New Generation of Surfactants, CHEMTECH 30:23-33 (1993).
13. Devinsky, F., I. Lacko, F. Bittcrerova, and L. Tomeckova, Relationship Between Structure, Surface Activity, and Micelle For-mation of Some New Bisquaternary Isosteres of 1,5-Pentanediammonium Dibromides, J. Colloid Interface Sci. 114:314-322 (1986).
14. Zana, R., M. Benrraou, and R. Rueff, Alkanediyl-α,ω-bis(dimethylalkylammonium bromide) Surfactants 1. Effect of the Spacer Chain Length on the Critical Micelle Concentration and Micelle Ionization Degree, Langmukir 7:1072-1075 (1991).
15. Menger, P.M., and C.A. Littau, Gemini Surfactants: Synthesis and Properties, J. Am. Chem. Soc. 113:1451-1452 (1991).
16. Okahara, M., A. Masuyama, Y. Sumida, and Y.-P. Zhu, Surface-Active Properties of New Types of Amphipathic Compounds with Two Hydrophilic Ionic Groups and Two Lipophilic Alkyl Chains, J. Jpn. Oil Chem. Soc. (Yukagaku) 37:746-748 (1988).
17. Zhu, Y.-P., A. Masuyama, and M. Okahara, Preparation and Surface-Active Properties of Amphipathic Compounds with Two Sulfate Groups and Two Lipophilic Alkyl Chains, J. Am. Oil Chem. Soc. 67:459-463 (1990).
18. Zhu, Y.-P., A. Masuyama, T. Nagata, and M. Okahara, Preparation and Properties of Double-Chain Surfactants Bearing Two Sulfonate Groups, J. Jpn. Oil Chem. Soc. (Yukagaku) 40:473-477 (1991).
19. Zhu, Y.-P., A. Masuyama, Y. Kirito, and M. Okahara, Preparation and Properties of Double- or Triple-Chain Surfactants with Two Sulfonate Groups Derived from N-Acyldiethanolamines, J. Am. Oil Chem. Soc. 68:539-543 (1991).
20. Zhu, Y.-P., A. Masuyama, and M. Okahara, Preparation and Surface-Active Properties of New Amphipathic Compounds with Two Phosphate Groups and Two Long-Chain Alkyl Groups, Ibid. 68:268-271 (1991).
21. Zhu, Y.-P., A. Masuyama, Y.-C. Kirito, M. Okahara, and M.J. Rosen, Preparation and Properties of Glycerol-Based Double-or Triple-Chain Surfactants with Two Hydrophilic Ionic Groups, Ibid. 69:626-632 (1992).
22. Masuyama, A., T. Hirono, Y.-P. Zhu, MK. Okahara, and M.J. Rosen, Synthesis and Properties of Bis(taurine) Types of Double-Chain Surfactants, J. Jpn. Oil Chem. Soc. (Yukagaku) 41:301-305 (1992).
23. Reid, V.W., G.F. Longman, and E. Heinerth, Determination of Anionic-Active Detergents by Two-phase Titration, Tenside 4:292-304 (1967).
24. Rosen, M.J., and H.A. Goldsmith, Systematic Analysis of Surface-Active Agents, 2nd edn., Wiley-Interscience, New York, 1972, p. 427.
25. Rosen, M.J., Purification of Surfactants for Studies of Their Fundamental Surface Properties, J. Colloid Interface Sci. 79:587 (1981); Reply to Purification of Surfactants by Solid Adsorbents, 56:587 (1982).
26. Rosen, M.J., Purification of Surfactants for Studies of Their Fundamental Surface Properties, J. Colloid Interface Sci. 79:587 (1981); Reply to Purification of Surfactants by Solid Adsorbents, 56:587 (1982).
27. Rosen, M.J. Surfactants and Interfacial Phenomena, 2nd edn., Wiley, New York, 1989, pp. 66-69.
28. Ibid., pp. 84-90.
29. Ibid., p. 217.