catalyst equilibration for transformation of methanol into hydrocarbons by reaction-regeneration cycles

Industrial and Engineering Chemistry Research

Volumn 35, Issue 7, 1996, Pages 2177-2182

  Benito, Pedro L ^a   Aguayo, Andrés T ^a   Gayubo, Ana G ^a   Bilbao, Javier ^a  

^a UNIVERSITY OF THE BASQUE COUNTRY UPV EHU   (Spain)

Author keywords

[No Author keywords available]

Indexed keywords

CALCINATION; CATALYST DEACTIVATION; COMPOSITION EFFECTS; GASOLINE; METHANOL; REACTION KINETICS; THERMAL EFFECTS; ZEOLITES;

CATALYST ACID STRUCTURE; CATALYST STABILITY; IRREVERSIBLE DEACTIVATION; OPTIMUM CATALYST EQUILIBRATION; REACTION REGENERATION CYCLES;

CATALYST ACTIVITY;

EID: 0030189940     PISSN: 08885885     EISSN: None     Source Type: Journal    
DOI: 10.1021/ie950493u     Document Type: Article

References (24)

1. Aguayo, A. T.; Benito, P. L.; Gayubo, A. G.; Olazar, M.; Bilbao, J. Acidity Deterioration and Coke Deposition in a H-ZSM-5 Zeolite in the MTG Process. Stud. Surf. Sci. Catal. 1994a, 88, 567-572.
2. Aguayo, A. T.; Arandes, J. M.; Gayubo, A. G.; Olazar, M.; Ereña, J.; Bilbao, J. Isotherms of Chemical Adsorption of Bases or Solid Catalysts for Acidity Measurement. J. Chem. Technol. Biotechnol. 1994b, 60, 141-146.
3. Allum, K. G.; Williams, A. R. Operation of the World's First Gas-To-Gasoline Plant. Stud. Surf. Sci. Catal. 1988, 36, 691-711.
4. Arandes, J. M.; Aguayo, A. T.; Gayubo, A. G.; Olazar, M.; Bilbao, J. Design of an Automated Reactor for Catalytic Reactions. Technol. Today 1990, 3, 144-149.
5. Argauer, R. J.; Landolt, G. R. Crystalline Zeolite HZSM-5 and Method of Preparing the Same. U.S. Patent 3,702,886, Nov 14, 1972.
6. Benito, P. L. Modelado Cinético de la Transformación de Metanol a Gasolina sobre Zeolites ZSM5. Ph.D. Thesis, University of the Basque Country, Bilbao, Spain, 1995.
7. Benito, P. L.; Gayubo, A. G.; Aguayo, A. T.; Bilbao, J. Evolution of the Acidic Structure of a H-ZSM-5 Zeolite with the Thermal Treatment Steps in its Preparation. Afinidad 1994, 51, 375-378.
8. Benito, P. L.; Gayubo, A. G.; Aguayo, A. T.; Bilbao. J. Deposition and Characteristics of Coke over a HZSM5 Zeolite Based Catalyst in the MTG Process. Ind. Eng. Chem. Res. 1996, submitted.
9. Bibby, D. M.; Howe, R. F.; McLellan, G. D. Coke Formation in High-Silica Zeolites. Appl. Catal. 1992, 93, 1-34.
10. Chen, N. Y.; Miale, J. N.; Reagan, W. J. Preparation of Zeolite, Example 5, U.S. Patent 4,112,056, September 5, 1973.
11. Copperthwaite, R. G.; Hutchings, G. J.; Johnston, P.; Orchard, S. W. Regeneration of Pentasil Zeolite Catalysts Using Ozone and Oxigene. J. Chem. Soc., Faraday Trans. 1 1986, 82, 1007-1017.
12. Datka, J., Tuznik, E. Infrared Spectroscopic Studies of Acidic Properties of NaHZSM-5 Zeolites. J. Catal. 1986, 102, 43-51.
13. Datka, J.; Piwowarska, Z. Acid Properties of NaHZSM-5 Zeolites of Various Si/Ai Ratios and of NaHZSM-11 Zeolite Studied by I. R. Spectroscopy. Zeolites 1988, 8, 30-34.
14. Gayubo, A. G. Innovations in the Kinetic Study of Deactivation and Reactivation of Catalysts. Application to Reactor Design. Ph.D. Thesis, University of the Basque Country, Bilbao, Spain, 1992.
15. Gayubo, A. G.; Arandes, J. M.; Aguayo, A. T.; Olazar, M.; Bilbao, J. Calculation of the Kinetics of Deactivation by Coke in Integral Reactor for a Triangular Scheme Reaction. Chem. Eng. Sci. 1993, 48, 1077-1087.
16. Gayubo, A. G.; Benito, P. L.; Aguayo, A. T.; Olazar, M.; Bilbao, J. Relationship between Surface Acidity and Activity of HZSM5 Zeolite Based Catalysts in the MTG Process. J. Chem. Technol. Biotechnol. 1996, 65, 186-192.
17. Guisnet, M.; Magnoux, P. Fundamental Description of Deactivation and Regeneration of Acid Zeolites. Stud. Surf. Sci. Catal. 1994, 88, 53-68.
18. Liederman, D.; Jacob, S. M.; Voltz, S. E.; Wise, J. J. Process Variable Effects in the Conversion of Methanol to Gasoline in a Fluid Bed Reactor. Ind. Eng. Chem. Process Des. Dev. 1978, 17, 340-346.
19. Nayak, V. S.; Choudhary, V. R. Effect of Hydrothermal Treatments on Acid Strength Distribution and Catalytic Properties of HZSM5. Appl. Catal. 1984, 10, 137-145.
20. Ortega, J. M.; Gayubo, A. G.; Aguayo, A. T.; Benito, P. L.; Bilbao, J. The Role of Coke Characteristics in the Regeneration of the Catalyst of the MTG Process. Ind. Eng. Chem. Res. 1996, submitted.
21. Schipper, P. H.; Krambeck, F. J. A Reactor Design Simulation with Reversible and Irreversible Catalyst Deactivation. Chem. Eng. Sci. 1986, 41, 1013-1019.
22. Vedrine, J. C.; Auroux, A.; Bolis, V.; Dejaifve, P.; Naccache, C.; Wierzchowski, E. G.; Nagy, J. B.; Gilson, J. P.; van Hooff, J. H. C.; Van der Berg, J. B.; Wolhuizen, J. Infrared, Microcalorimetric and Electron Spin Resonance Investigations of the Acidic Properties of HZSM-5 Zeolites. J. Catal. 1979, 59, 248-262.
23. Yurchak, S. Development of Mobil's Fixed-Bed Methanol-To-Gasoline (MTG) Process. Stud. Surf. Sci. Catal. 1988, 36, 251-272.
24. Yurchak, S.; Voltz, S. E.; Warner, J. P. Process Aging Studies in the Conversion of Methanol to Gasoline in a Fixed Bed Reactor. Ind. Eng. Chem. Process Des. Dev. 1979, 18, 527-534.