Microgel formation in emulsion copolymerization. I. Polymerization without seed latex

Journal of Polymer Science, Part B: Polymer Physics

Volumn 34, Issue 8, 1996, Pages 1403-1413

  Tobita, Hidetaka ^a   Uemura, Yutaka ^a  

^a UNIVERSITY OF FUKUI   (Japan)

Author keywords

Crosslinking; Emulsion polymers; Microgels; Molecular weight distribution; Monte Carlo method

Indexed keywords

COPOLYMERIZATION; CROSSLINKING; EMULSIONS; GELATION; GELS; MATHEMATICAL MODELS; MOLECULAR WEIGHT; MOLECULAR WEIGHT DISTRIBUTION; MONOMERS; MONTE CARLO METHODS; PARTICLE SIZE ANALYSIS; POLYMETHYL METHACRYLATES;

EMULSION POLYMERS; ETHYLENE GLYCOL DIMETHACRYLATE; HOMOGENEOUS POLYMERIZATION; METHYL METHACRYLATE; POLYMERIZATION LOCUS; SEED LATEX;

EMULSION POLYMERIZATION;

EID: 0030171214     PISSN: 08876266     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1099-0488(199606)34:8<1403::AID-POLB2>3.0.CO;2-T     Document Type: Article

References (41)

1. M. Gordon, Proc. R. Soc. London, Ser. A, 268, 240 (1963).
2. C. W. Macosko and D. R. Miller, Macromolecules, 9, 199 (1976).
3. D. Durand and C. M. Bruneau, Makromol. Chem., 183, 1007, 1021 (1982).
4. P. J. Flory, Principles of Polymer Chemistry, Cornell University Press, Ithaca, NY, 1953, Chap. 9.
5. H. Tobita, Macromolecules, 25, 2671 (1992).
6. H. Tobita, Polym. React. Eng., 1, 357 (1993).
7. H. Tobita, Polymer, 35, 3023 and 3032 (1994).
8. H. Tobita and K. Yamamoto, Macromolecules, 27, 3389 (1994).
9. H. Tobita, Acta Polym., 46, 185 (1995).
10. H. Tobita, Y. Takada, and M. Nomura, Macromolecules, 27, 3804 (1994).
11. H. Tobita, Y. Takada, and M. Nomura, J. Polym. Sci. Part A: Polym. Chem., 33, 441 (1995).
12. H. Tobita and A. E. Hamielec, Macromolecules, 22, 3098 (1989).
13. H. Tobita and A. E. Hamielec, in Polymer Reaction Engineering, K.-H. Reichert and W. Geiseler, Eds., VCH, Weinheim, Germany, 1989, pp. 43.
14. H. Tobita and A. E. Hamielec, Polymer, 33, 3647 (1992).
15. H. Jacobson and W. H. Stockmayer, J. Chem. Phys., 18, 1600 (1950).
16. R. W. Kilb, J. Phys. Chem., 62, 969 (1958).
17. J. A. Semlyen, Adv. Polym. Sci., 21, 41 (1976).
18. N. A. Dotson, C. W. Macosko, M. Tirrell, in Synthesis, Characterization, and Theory of Polymer Networks and Gels, S. M. Aharoni, Ed., Plenum, New York, 1992, pp. 319.
19. B. Friedman and B. O'Shaughnessy, Macromolecules, 26, 4888 (1993).
20. P. J. Flory, J. Am. Chem. Soc., 69, 2893 (1947).
21. H. Tobita and K. Ito, Polym. Gels Net., 2, 191 (1994).
22. W. H. Stockmayer, J. Chem. Phys., 13, 199 (1945).
23. F. W. Cheng, Microchem. J., 3, 537 (1959).
24. M. Nomura, K. Yamamoto, I. Horie, and K. Fujita, J. Appl. Polym. Sci., 27, 2483 (1982).
25. A. E. Hamielec, Chem. Eng. Commun., 24, 1 (1983).
26. I. Mita and K. Horie, J. Macromol. Sci., Rev. Macromol. Chem. Phys., C27, 91 (1987).
27. M. Nomura and K. Fujita, Polym. Int., 30, 483 (1993).
28. D. T. Landin and C. W. Macosko, Macromolecules, 21, 846 (1988).
29. R. S. Whitney and W. Burchard, Makromol. Chem., 181, 869 (1980).
30. H. Tobita, K. Kimura, K. Fujita, and M. Nomura, Polymer, 34, 2569 (1993).
31. K. Nakamura, A. Imoto, H. Aota, and A. Matsumoto, in Preprints for the 8th Polymeric Microsphere Symposium, Nov. 9-11, 1994, Fukui, Japan, p. 37.
32. Y. Kobayashi, H. Aota, and M. Matsumoto, Polymer Preprints, Jpn., 42, 2961 (1993).
33. H. W. Starkweather and M. C. Ran, J. Polym. Sci. Part A: Polym. Chem., 30, 2709 (1992).
34. M. Morton and P. P. Salatiello, J. Polym. Sci., 6, 225 (1950).
35. G. M. Burnett, G. G. Cameron, and P. L. Thorat, J. Polym. Sci., Part A-1, 8, 3435, 3443, 3455 (1970).
36. N. Friis, D. Goosney, J. D. Wright, and A. E. Hamielec, J. Appl. Polym. Sci., 18, 1247 (1974).
37. T. O. Broadhead, A. E. Hamielec, and J. F. MacGregor, Makromol. Chem., Suppl, 10/11, 105 (1985).
38. D. Charmot and J. Guillot, Polymer, 33, 352 (1992).
39. M. Mazzatti, G. Storti, S. Fiorentino, A. Ghielmi, and M. Morbidelli, in Polymer Reaction Engineering ( DECHEMA Monographs Vol. 131), K.-H. Reichert and H.-U. Moritz, Eds., VCH, Weinheim, Germany, 1995, p. 19.
40. G. Arzamendi and J. M. Asua, Macromolecules, 28, 7479 (1995).
41. K. Yamamoto and H. Tobita, unpublished simulation results.