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note
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2. If total saturation of all transitions is not achieved, how well the MSFL performs during the TE, RE, or VE cooling steps will depend on actual sideband intensities. Of major concern are weak unsaturated transitions that could degrade TE cooling efficiency (molecules getting left behind in the chirp). Repumping, explained in the appendices, is a possible solution. Numerical simulations of these effects are currently underway. We also note that the problem of driving the weakest transitions with the weakest sidebands is somewhat mitigated by the fact that broadband amplifiers (e.g., alexandrite and semiconductor power amplifiers) characteristically saturate at some intensity (for a given frequency). This results in the highest gain for the weakest sidebands.
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note
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2, starting with the P(6) line this limit is estimated to be ∼670 GHz/ms. In practice (especially for large J, or rotational heating), it would be faster and more efficient to perform a "stepped" P chirp whereby the chirp proceeds by rapidly slewing between sequential even or odd J resonances [P(J), P(J - 2),⋯, etc.]. Although technically more difficult to perform than a continuous chirp, a stepped chirp could selectively cool (or heat) ortho or para molecules independently.
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85033071482
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2)=A-Bv″. The largest possible slope (B) is desirable in this case. The slopes (B) for the alkali metal dimer B-X bands have been found to lie in the order Li>K>Cs>Rb>Na.
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46
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