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Volumn 355, Issue 1-3, 1996, Pages

Facile homolytic C-S bond breaking: The reaction of 2-propene-l-thiol on Mo(110)

Author keywords

Catalysis; Chemisorption; Isotopic exchange traces; Molybdenum; Photoelectron spectroscopy; Thermal desorption; Thiols; X ray photoelectron spectroscopy

Indexed keywords

ADSORPTION; BOND STRENGTH (CHEMICAL); CATALYSIS; CHEMICAL BONDS; CHEMISORPTION; DESULFURIZATION; PROPYLENE; TEMPERATURE PROGRAMMED DESORPTION; X RAY PHOTOELECTRON SPECTROSCOPY;

EID: 0030169896     PISSN: 00396028     EISSN: None     Source Type: Journal    
DOI: 10.1016/0039-6028(96)00516-X     Document Type: Article
Times cited : (9)

References (36)
  • 10
    • 30244560475 scopus 로고    scopus 로고
    • note
    • Propene primarily decomposes to H2 and surface carbon on clean Mo(110). A minor amount of desorption also occurs below 200 K at saturation coverages. Propene desorption occurs to a greater extent on S-covered Mo(110) below 200 K.
  • 12
    • 30244459518 scopus 로고    scopus 로고
    • note
    • The heating rate used in the temperature-dependent spectroscopic studies was the same as that used in the temperature-programmed reaction experiments.
  • 15
    • 30244550099 scopus 로고    scopus 로고
    • note
    • S/Mo = [Mo(LMM, 148 eV)] + [S(KLL, 152 eV)]/[Mo(LMM, 186 eV)] + [Mo(LMM, 221 eV)]
  • 17
    • 30244530321 scopus 로고    scopus 로고
    • note
    • Modes involving hydrogen motion (e.g. C-H and O-H stretches) typically have a large impact-scattering component. While this has not been specifically established for S-H, the similarity to C-H and O-H modes supports the argument that impact scattering will be important in the S-H stretch modes.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.