Molecular interactions in tri-n-butyl phosphate - Diluent mixtures

Industrial and Engineering Chemistry Research

Volumn 35, Issue 6, 1996, Pages 2048-2059

  Choi, K ^a   Tedder, D W ^b  

^a Georgia Institute of Technology   (United States)

^b NONE

Author keywords

[No Author keywords available]

Indexed keywords

GIBBS FREE ENERGY; MATHEMATICAL MODELS; MOLECULAR STRUCTURE; NUCLEAR MAGNETIC RESONANCE; PARAMETER ESTIMATION; PHASE EQUILIBRIA; PHOSPHATES;

DILUENT BINARY MIXTURES; MOLAR VOLUMES; VAPOR LIQUID EQUILIBRIUM; VOLUME ADJUSTMENT FACTOR;

BINARY MIXTURES;

EID: 0030169813     PISSN: 08885885     EISSN: None     Source Type: Journal    
DOI: 10.1021/ie950626b     Document Type: Article

References (46)

1. Abbott, M.; Van Ness, H. Thermodynamics of solutions containing reactive species. A guide to fundamentals and applications. Fluid Phase Equilib. 1992, 77, 53-119.
2. Abrams, D. S.; Prausnitz, J. M. Statistical thermodynamics of liquid mixtures: a new expression for the excess Gibbs energy of partly or completely miscible systems. AIChE J. 1975, 21 (1), 116-128.
3. Acree, W. E. Thermodynamic Properties of Nonelectrolyte Solutions; Academic Press: New York, 1984.
4. Blaylock, C. R.; Tedder, D. W. Competitive equilibria in the system: water, nitric acid, tri-n-butyl phosphate and Amsco 125-82. Solvent Extr. Ion Exch. 1989, 7(2), 249-271.
5. Campbell, S. W. Chemical theory for mixtures containing any number of alcohols. Fluid Phase Equilib, 1994, 102, 61-84.
6. Chavret, M. Excess enthalpy for tributyl phosphate and heptane. In International Data Series, Selected Data Mixtures; Kehiaian, H., Ed.; Thermodynamics Research Center, Texas A&M University System: College Station, TX 1990; p 292.
7. Choi, K. Molecular Interactions in Polar Solvents. Ph.D. Thesis, School of Mechanical Engineering, Georgia Institute of Technology, Atlanta, GA, 1995.
8. Choi, K.; Tedder, D. Nuclear magnetic resonances of TBP-diluent mixtures. Spectrochim. Acta, Part A 1995, 51, 2301-2305.
9. Davis, W., Jr. Thermodynamics of extraction of nitric acid by tri-n-butyl phosphate-hydrocarbon-diluent solutions: I, distribution studies with TBP in Amsco 125-82 at intermediate and low acidities. Nucl. Sci. Eng. 1962a, 14 (2), 159-168.
10. Davis, W., Jr. Thermodynamics of extraction of nitric acid by tri-n-butyl phosphate-hydrocarbon-diluent solutions: II. densities, molar volumes, and water solubilities of TBP-Amsco 125-82-ntrici acid-water solutions. Nucl. Sci. Eng. 1962b, 14 (2), 169-173.
11. de St. Romain, P.; Tra Van, H.; Patterson, D. Effects of molecular shape on the excess enthalpies and heat capacities of alkane systems. J. Chem. Soc., Faraday Trans. I 1979a, 75, 1700.
12. de St. Romain, P.; Tra Van, H.; Patterson, D. Effects of molecular shape on the excess enthalpies and heat capacities of cycloalkane systems. J. Chem. Soc., Faraday Trans. I 1979b, 75, 1708.
13. Dolezalek, F. Zur Theorie der Binaren Gemische und Korzentrierten Loungen. Z. Phys. Chem. 1908, 64, 727.
14. Eckert, C.; McNiel, M.; Scott, B.; Halas, L. NMR measurements of chemical theory equilibrium constants for hydrogen-bonded solutions. AIChE J. 1986, 32, 820.
15. Economou, I. G.; Donohue, M. D. Chemical, quasi-chemical and perturbation theories for associating fluids. AIChE J. 1991, 37 (12), 1875-1894.
16. Fenby, D.; Khurma, J.; Kooner, Z.; Block, T.; Knobler, C.; Reeder, J.; Scott, R. Isomer effects in mixtures of hydrocarbons: some experimental excess volumes and enthalpies. Aust. J. Chem. 1980, 33, 1927-41.
17. Fomin, V. V.; Rudenko, T. I. Investigation of the properties of tributyl phosphate solutions in benzene, carbon tetrachloride, and n-decane. Radiokhim. 1965, 7 (1), 33-39.
18. Guggenheim, E. Mixtures; Clarendon: New York, 1952.
19. Gutowsky, H.; Saike, A. Dissociation, chemical exchange and the proton magnetic resonance in some aqueous electrolytes. J. Chem. Phys. 1953, 21, 1688.
20. Harris, H.; Prausnitz, J. Thermodynamics of solutions with physical and chemical interactions. Ind. Eng. Chem. Fundam. 1969, 8, 180.
21. Kaiser, R. Solvent shift of the chloroform nuclear magnetic resonance line. Can. J. Chem. 1963, 41, 430.
22. Karachewski, A. M.; McNiel, M. M.; Eckert, C. A. Study of hydrogen bonding in alcohol solutions using NMR spectroscopy. Ind. Eng. Chem. Res. 1989, 28, 315-324.
23. Kharchenko, S.; Mikhailov, V.; Afanas'ev, Y.; Ponomareva, L. Thermodynamic study of binary systems formed by tributyl phosphate with n-heptane, benzene, carbon tetrachloride and chloroform. Izv. Sib. Otd. Akad. Nauk SSSR, Ser. Khim. Nauk 1964, 3 (11), 30.
24. Kumar, S.; Suter, U.; Reid, R. A. statistical mechanics based lattice model equation of state. Ind. Eng. Chem. Res. 1987, 26, 2532.
25. Marquardt, D. W. An algorithm for least-squares estimation of nonlinear parameters. Soc. Ind. Appl. Math. J. 1963, 11 (2), 431-441.
26. Martinez, G. M. Lattice statistics for size, clustering and dissociation with example applications in vapor-liquid equilibria. Chem. Eng Sci. 1994, 49 (15), 2423-2435.
27. Panayiotou, C.; Vera, J. The quasi-chemical approach for nonrandomness in liquid mixtures: expression for local surfaces and local compositions with an applications to polymer solutions. Fluid Phase Equilib. 1980, 5, 55.
28. Panayiotou, C.; Vera, J. Statistical thermodynamics of r-mer fluids and their mixtures. Polym. J. 1982, 14, 681.
29. Petković, D. M. Some correlations of trialkyl phosphates dimerization constants. J. Inorg. Nucl. Chem. 1968, 30, 603.
30. Petković, D. M. Dielectric constant investigation of the TBP (tri-n-butyl phosphate) - hexane system; Wiley-Interscience: New York, 1969; p 93.
31. Petković, D. M.; Kezele, B. A. Determination of tributyl phosphate association constants and an approach to the problem of solvent effect. In Proceedings of the Int. Solvent Extraction Conference, Society of Chemical Industry: London, 1971; pp 1137-1141.
32. Petković, D. M.; Maksimovic, Z. B. On association of trialkyl phosphates. J. Inorg. Nucl. Chem. 1976, 38, 297.
33. Prausnitz, J. M.; Lichtenthaler, R. N.; Avzevedo, E. Gd. Molecular Thermodynamics of Fluid-Phase Equilibria, 2nd ed.; Prentice-Hall: Englewoods Cliffs, NJ, 1986.
34. Prigogine, I.; Defay, R. Chemical Thermodynamics; Longmans Green & Co.: London, 1954.
35. Rabie, H.; Vera, J. Chemical theory for ion distribution equilibria in reverse micellar systems. New experimental data for aerosol-OT-isooctane-water-salt systems. Langmuir 1995, 11, 1162-1169.
36. Renon, H.; Prausnitz, J. M. Local compositions in thermodynamic excess functions for liquid mixtures. AIChE J. 1968, 14, 135.
37. Rozen, A.; Khorhorina, L.; Yurkin, V.; Novikova, N. The reaction of tributyl phosphate (TBP) and TBP-solvate with diluents. Proc. Acad. Sci. USSR (Transl.) 1963, 153, 1387.
38. Rytting, J. H.; Goldkamp, A.; Lindenbaum, S. Heats of dilution of trialkyl phosphates in isooctane and carbon tetrachloride: interpretation in terms of self-association. J. Solution Chem. 1975, 4, 1005.
39. Sayegh, S.; Vera, J. Lattice-model expressions for the combinatorial entropy of liquid mixtures: a critical discussion. Chem. Eng. J. 1980, 19, 1.
40. Schulz, W., Navratil, J., Eds. Science and Technology of Tri-n-Butyl Phosphate; CRC Press: Boca Raton, FL, 1986a; Vol. 3.
41. Schulz, W., Navratil, J., Eds. Science and Technology of Tri-n-Butyl Phosphate; CRC Press: Boca Raton, FL, 1986a; Vol. 4.
42. Tancrède, P.; Bothorel. P.; de St. Romain, P.; Patterson, D. Interactions in alkane systems by depolarized Rayleigh scattering and calorimetry. J. Chem. Soc., Faraday Trans. 2 1977, 73, 15.
43. Tedder, D. W.; Davis, W., Jr. Alternative models for predicting the extraction of water and uranyl nitrate in the two-phase system: water uranyl nitrate-TBP-Amsco 125-82. Solvent Ext. Ion Exch. 1983, 1 (1), 43-75.
44. Tsimering, L.; Kertes, A. Enthalpies of mixing tributyl phosphate with hydrogen-bonding solvents. J. Chem. Eng. Data 1977, 22 (2), 163.
45. Vera, J.; Sayegh, S.; Ratcliff, G. A quasi lattice-local composition model for the excess Gibbs free energy of liquid mixtures. Fluid Phase Equilib. 1977, 1, 113.
46. Wilson, G. M. Vapor-liquid equilibrium. XI. A new expression for the excess free energy of mixing. J. Am. Chem. Soc. 1964, 86, 127-130.