Steric effects upon transition states of radical addition polymerizations

Journal of Polymer Science, Part A: Polymer Chemistry

Volumn 34, Issue 8, 1996, Pages 1407-1414

  Azuma, Hidemasa ^a   Katagiri, Yuzuru ^a   Yamabe, Shinichi ^b  

^a MITSUBISHI CHEMICAL CORPORATION   (Japan)

^b NARA UNIVERSITY OF EDUCATION   (Japan)

Author keywords

Addition polymerization; Differential photocalorimetry; Dimethyl itaconate; DPC; Ethylene; Methyl acrylate; Methyl methacrylate; Molecular orbital method; MOPAC; N methyl itaconimide; Transition state

Indexed keywords

ACTIVATION ENERGY; ADDITION REACTIONS; CHEMICAL BONDS; ENTROPY; FREE RADICALS; MATHEMATICAL MODELS; MOLECULAR STRUCTURE; MONOMERS; PERTURBATION TECHNIQUES; POLYMETHYL METHACRYLATES; THERMODYNAMIC PROPERTIES;

DIFFERENTIAL PHOTOCALORIMETRY; DIMETHYL ITACONATE; METHYL ITACONIMIDE; MOLECULAR ORBITAL METHOD; RADICAL ADDITION POLYMERIZATION; STERIC EFFECTS; TRANSITION STATES;

FREE RADICAL POLYMERIZATION;

EID: 0030164598     PISSN: 0887624X     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1099-0518(199606)34:8<1407::AID-POLA3>3.0.CO;2-X     Document Type: Article

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