Solubility of potassium ferrate in 12 m alkaline solutions between 20°C and 60°C

Journal of Chemical Technology and Biotechnology

Volumn 66, Issue 1, 1996, Pages 35-40

  Bailie, A Glover ^a   Bouzek, Karel ^a   Lukášek, Petr ^a   Roušar, Ivo ^a   Wragg, Anthony A ^a  

^a UNIVERSITY OF EXETER   (United Kingdom)

Author keywords

12 M solutions; KOH NaOH solutions; Potassium ferrate; Solubility

Indexed keywords

ARSENIC COMPOUNDS; CALCULATIONS; DECOMPOSITION; DISSOCIATION; DISSOLUTION; IONS; SODIUM COMPOUNDS; SOLUBILITY; SOLUTIONS; TEMPERATURE; THERMAL EFFECTS; TITRATION;

POTASSIUM FERRATE; POTASSIUM HYDROXIDE; POTENTIOMETRIC TITRATION; SODIUM HYDROXIDE;

POTASSIUM COMPOUNDS;

FERRATE POTASSIUM; IRON DERIVATIVE; POTASSIUM HYDROXIDE; POTASSIUM ION; SODIUM HYDROXIDE; UNCLASSIFIED DRUG;

ANALYTIC METHOD; AQUEOUS SOLUTION; ARTICLE; DECOMPOSITION; DISSOLUTION; INTERMETHOD COMPARISON; POTENTIOMETRIC TITRATION; SOLUBILITY; TEMPERATURE DEPENDENCE;

EID: 0030152416     PISSN: 02682575     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1097-4660(199605)66:1<35::AID-JCTB457>3.0.CO;2-M     Document Type: Article

References (30)

1. Mellor, J. W., A Comprehensive Treatise on Inorganic and Theoretical Chemistry. Longmans, London, 1924, pp. 929-37.
2. Kazama, F., Respiratory inihibition of Sphaerotilus by potassium ferrate. J. Ferment. Bioeng., 67(6) (1989) 369.
3. Kato, K. & Kazama, F., Respiratory inhibition of Sphaerotilus by iron compounds and the distribution of the sorbed iron. Water Sci. Technol 23 (4-6) (1991) 947.
4. Waite, T. D. & Gilbert, M., Iron(VI) ferrate as a general oxidant for water and wastewater treatment. Chem Abst, 89: 135578c (1978).
5. Gilbert, M., Waite, T. D. & Hare, C., Analytical notes. An investigation of the applicability of ferrate(VI) ion for disinfection. J. Am. Water Works Assoc., 68 (9) (1976) 495.
6. Waite, T. D. & Gilbert, M., Oxidative destruction of phenol and other organic water residuals by iron(VI) ferrate. J. Water Pollut. Control Fed., 50 (3) (1978) 543.
7. Waite, T. D., Feasibility of wastewater treatment with ferrate. J. Environ. Eng. Div. (Am. Soc. Civ. Eng.), 105 (EE6) (1979) 1023.
8. Carr, J. D., Ferrate ion : potential uses in advanced waste-water treatment. Chem Abst, 98: 77605g (1983).
9. DeLuca, S. J., Chao, A. C. & Smallwood, C. Jr, Ames test of ferrate-treated water. J. Environ. Eng., 109 (5) (1983) 1159.
10. Ericson, J. E., The oxidation of water and inorganic nitrogen compounds by potassium ferrate(VI). Diss. Abstr. Int. B, 50 (2) (1989) 558.
11. 2) chemical technology. Chem Abst, 114: 216503m (1991).
12. Petira, O., Oxidative destruction of organic water residuals by iron (VI) ferrate. PhD thesis, Institute of Chemical Technology, Prague, Czech Republic, 1985.
13. Stahl, G. E., Gmelins Handbuch, Nr. 59, 1932, p. 912.
14. 2) and ferrous sulphate. Thermochim. Acta, 97 (1986) 243.
15. Kiselev, Yu. M., Kopelev, N. S., Zavyalova, N. A., Perfilev, Yu. D. & Kazin, P. E., Preparation of alkali metal ferrates(VI). Zh. Neorg. Khim., 34 (9) (1989) 2199.
16. Thompson, G. W., Ockerman, L. T. & Schreyer, J. M., Preparation and purification of potassium ferrate(VI). J. Am. Chem. Soc., 73 (1951) 1379.
17. Hrostowski, H. J. & Scott, A. B., The magnetic susceptibility of potassium ferrate. J. Chem. Phys., 18 (1950) 105.
18. Helferich, B. & Lang, K., Salts of ferric acid. Z. anorg. u. allgem. Chem., 263 (1950) 169.
19. Ockerman, L. T. & Schreyer, J. M., Preparation of sodium ferrate(VI). J. Am. Chem. Soc., 73 (1951) 5478.
20. Toušek, J., Electrochemische Darstellung des Natriumferrats(VI). Coll. Czech. Chem. Comm., 27 (1962) 914.
21. Bouzek, K. & Roušar, I., The study of electrochemical preparation of ferrate(VI) using alternate current superimposed on the direct current. Frequency dependence of current yields. Electrochim. Acta, 38 (1993) 1717.
22. Bouzek, K. & Roušar, I., Current efficiency during anodic dissolution of iron to ferrate(VI) in concentrated alkali hydroxide solutions. J. Applied Electrochem., 23 (1993) 1317.
23. Kalcík, D., The study of solubility of potassium ferrate(VI). MSc thesis, Institute of Chemical Technology, Prague, Czech Republic, 1993.
24. Schreyer, J. M., Thompson, G. V. & Ockerman, L. T., Oxidation of chromium(III) with potassium ferrate(VI). Anal. Chem., 22 (1950) 1426.
25. Wronska, M., Studies on the kinetics of decomposition of aqueous solutions of ferrate(VI) ions. Bull. Acad. Polon. Sci., Série Sci. Chim., Géol. et Geograph, 7 (1959) 137.
26. Toušek, J., Untersuchung der Zersetzung von Natriumferratlösungen. Coll. Czech. Chem. Comm., 27 (1962) 908.
27. Audette, R. J. & Quail, J. W. Potassium, rubidium, caesium and barium ferrate(VI). Preparations, infrared spectra, and magnetic susceptibilities. Inorg. Chem., 11 (1972) 1904.
28. Schreyer, J. M., Thompson, G. W. & Ockerman, L. T., Ferrate oxidimetry. Oxidation of arsenite with potassium ferrate(VI). Anal Chem., 22 (1950) 691.
29. Akerlöf, G. C. & Kegeles, G., Thermodynamics of concentrated aqueous solutions of sodium hydroxide. J. Am. Chem. Soc., 62 (1940) 620.
30. Akerlöf, G. C. & Bender, P., Thermodynamics of aqueous solutions of potassium hydroxide. J. Am. Chem. Soc., 70 (1948) 2366.