Symmetry-breaking perturbations in the ν2+3ν3 rovibrational manifold of acetylene: Spectroscopic and energy-transfer effects

Journal of Chemical Physics

Volumn 104, Issue 17, 1996, Pages 6423-6434

  Milce, Angela P ^a   Orr, Brian J ^a  

^a MACQUARIE UNIVERSITY   (Australia)

Author keywords

[No Author keywords available]

Indexed keywords

CORIOLIS COUPLING; EIGENSTATES; FRANCK CONDON FACTORS; INFRARED ULTRAVIOLET DOUBLE RESONANCE SPECTROSCOPY; INTRAMOLECULAR STATE MIXING; NUCLEAR KYPERFINE INTERACTION; QUANTUM NUMBERS; ROVIBRATIONAL LEVELS; SUM FREQUENCY GENERATION;

ACETYLENE; APPROXIMATION THEORY; DYE LASERS; ELECTRON ENERGY LEVELS; ENERGY TRANSFER; FREQUENCIES; MOLECULAR STRUCTURE; MOLECULAR VIBRATIONS; RAMAN SCATTERING; ULTRAVIOLET RADIATION;

INFRARED SPECTROSCOPY;

EID: 0030151227     PISSN: 00219606     EISSN: None     Source Type: Journal    
DOI: 10.1063/1.471363     Document Type: Article

References (26)

1. B. C. Smith and J. S. Winn, J. Chem. Phys. 89, 4638 (1988);
2. (b) B. C. Smith and J. S. Winn, J. Chem. Phys. 94, 4120 (1991).
3. M. Herman, T. R. Huet, and M. Vervloet, Mol. Phys. 66, 333 (1989).
4. X. Zhan, O. Vaittinen, and L. Halonen, J. Mol. Spectrosc. 160, 172 (1993);
5. L. Halonen (private communications, 1993).
6. (a) D. M. Jonas, S. A. B. Solina, B. Rajaram, R. J. Silbey. R. W. Field, K. Yamanouchi, and S. Tsuchiya, J. Chem. Phys. 97, 2813 (1992);
7. (b) D. M. Jonas, S. A. B. Solina, B. Rajaram, R. J. Silbey. R. W. Field, K. Yamanouchi, and S. Tsuchiya, J. Chem. Phys. 99, 7350 (1993);
8. (c) S. A. B. Solina, J. P. O'Brien, R. W. Field, and W. F. Polik, Ber. Bunsenges. Phys. Chem. 99, 555 (1995).
9. A. L. Utz, J. D. Tobiason, E. Carrasquillo M., M. D. Fritz, and F. F. Crim, J. Chem. Phys. 97, 389 (1992);
10. J. D. Tobiason, A. L. Utz, and F. F. Crim, J. Chem. Phys. ibid. 97, 7437 (1992);
11. J. D. Tobiason, A. L. Utz, and F. F. Crim, J. Chem. Phys. 101, 1108 (1994).
12. M. J. Frost and I. W. M. Smith, Chem. Phys. Lett. 191, 574 (1992);
13. M. J. Frost, J. Chem. Phys. 98, 8572 (1993);
14. M. J. Frost and I. W. M. Smith, J. Phys. Chem. 99, 1094 (1995).
15. A. P. Milce, H.-D. Barth, and B. J. Orr, J. Chem. Phys. 100, 2398 (1994).
16. B. L. Chadwick, A. P. Milce, and B. J. Orr, Can. J. Phys. 72, 939 (1994).
17. M. Fujii, S. Tanabe, Y. Okuzawa, and M. Ito, Laser Chem. 14, 161 (1994).
18. ± states. This normal-mode notation is common to many of the preceding references. An equivalent local-mode description is also widely used (e.g., see Ref. 5).
19. A. L. Utz, E. Carrasquillo M., J. D. Tobiason, and F. F. Crim, Chem. Phys. 190, 311 (1995).
20. (a) A. L. Utz, J. D. Tobiason, E. Carrasquillo M., L. J. Sanders, and F. F. Crim, J. Chem. Phys. 98, 2742 (1993);
21. (b) J. D. Tobiason, A. L. Utz, and F. F. Crim, J. Chem. Phys. ibid. 99, 928 (1993);
22. (c) J. D. Tobiason, A. L. Utz, E. L. Sibert, and F. F. Crim, J. Chem. Phys. ibid. 99, 5762 (1993).
23. M. Abboutti Temsamani and M. Herman (private communications, 1994);
24. J. Chem. Phys. 102, 6371 (1995).
25. M. Herman, T. R. Huet, Y. Kabbadj, and J. Vander Auwera, Mol. Phys. 72, 75 (1991);
26. T. R. Huet, M. Herman, and J. W. C. Johns, J. Chem. Phys. 94, 3407 (1991).