Morphological characteristics of lamellar aba triblock copolymers: A self-consistent field treatment

Chemical Engineering Science

Volumn 51, Issue 9, 1996, Pages 1365-1375

  Jones, Ronald L ^a   Kane, Lisaleigh ^a   Spontak, Richard J ^a  

^a Campus Box 7908   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

FREE ENERGY; GRAFTING (CHEMICAL); MATHEMATICAL MODELS; MECHANICAL PROPERTIES; MOLECULAR STRUCTURE; MONOMERS; MORPHOLOGY; ORDER DISORDER TRANSITIONS;

HAIRPIN CONFORMATION; LAMELLAR ABA TRIBLOCK COPOLYMERS; MICROPHASE ORDERING; MIDBLOCK BRIDGING;

COPOLYMERS;

EID: 0030151096     PISSN: 00092509     EISSN: None     Source Type: Journal    
DOI: 10.1016/0009-2509(95)00310-X     Document Type: Article

References (21)

1. Albalak, R. J. and Thomas, E. L., 1993, Microphase separation of block copolymer solutions in a flow field. J. Polym. Sci. Polym. Phys. Ed. 31, 37-46.
2. Albalak, R. J. and Thomas, E. L., 1994, Rolling-casting of block copolymers and of block copolymer-homopolymer blends. J. Polym. Sci. Polym. Phys. Ed. 32, 341-350.
3. Alexander, S., 1977, Polymer adsorption on small spheres. A scaling approach. J. Phys. (Fr.) 38, 977-981.
4. Bard, J. K. and Chung, C. I., 1987, in Thermoplastic Elastomers: A Comprehensive Review (Edited by N.R. Legge, G. Holden and H. E. Schroeder), pp. 303-324. Hanser, New York.
5. Bates, F. S., 1991, Polymer-polymer phase behavior. Science 251, 898-905.
6. Bates, F. S. and Fredrickson, G. H., 1990, Block copolymer thermodynamics - theory and experiment. Ann. Rev. Phys. Chem. 41, 525-557.
7. Bonner, J. G. and Hope, P. S., 1993, in Polymer Blends and Alloys (Edited by M. J. Folkes and P. S. Hope), pp. 49-63. Blackie, London.
8. Eisa, T. and Sefton, M. V., 1993, Towards the preparation of a MMA-PEO block copolymer for the microencapsulation of mammalian cells. Biomater. 14, 755-761.
9. Fleer, G. J., Cohen Stuart, M. A., Scheutjens, J. M. M. H., Cosgrove, T. and Vincent, B., 1993, Polymers at Interfaces, pp. 114-120. Chapman and Hall, London.
10. Fredrickson, G. H., 1992, in Physics of Polymer Surfaces and Interfaces (Edited by I. C. Sanchez), pp. 1-28. Butterworth-Heinemann, Boston.
11. Fredrickson, G. H. and Helfand, E., 1987, Fluctuation effects in the theory of microphase separation in block copolymers. J. chem. Phys. 87, 697-705.
12. Gehlsen, M. D., Almdal, K. and Bates, F. S., 1992, Order-disorder transition: diblock versus triblock copolymers. Macromolecules 25, 939-943.
13. Gingell, D. and Owens, N., 1994, Inhibition of platelet spreading from plasma onto glass by an absorbed layer of a novel fluorescent-labeled poly(ethylene oxide)/ poly(butylene oxide) block copolymer - characteristics of the exclusion zone probed by means of polystyrene beads and macromolecules. J. Biomed. Mater. Res. 28, 491-503.
14. Hashimoto, T., Shibayama, M. and Kawai, H., 1980, Domain-boundary structure of styrene-isoprene films cast from solution. 4. molecular-weight dependence of lamellar microdomain. Macromolecules 13, 1237-1247.
15. Hashimoto, T., Shibayama, M., Kawai, H. and Meier, D. J., 1985, Confined-chain statistics of block polymers and estimation of optical anisotropy and domain size. Macromolecules 18, 1855-1864.
16. Helfand, E. and Wasserman, Z. R., 1976, Block copolymer theory. 4. narrow interphase approximation. Macromolecules 9, 879-888.
17. Helfand, E. and Wasserman, Z. R., 1978, Block copolymer theory. 5. spherical domains. Macromolecules 11, 960-966.
18. Henderson, C. P. and Williams, M. C., 1985, Influence of the interphase on block copolymer thermodynamics: extension of the Leary model. J. Polym. Sci. Polym. Phys. Ed. 23, 1001-1029.
19. Holden, G., 1987, in Thermoplastic Elastomers: A Comprehensive Review (Edited by N. R. Legge, G. Holden and H. E. Schroeder), pp. 481-506. Hanser, New York.
20. Jones, R. L. and Spontak, R. J., 1995, Effect of chain length and surface density on looped polymers grafted to an impenetrable surface. J. chem. Phys. 103, 5137-5143.
21. Kane, L. and Spontak, R. J., 1994, Microstructural characteristics of strongly segregated AXB triblock terpolymers possessing the lamellar morphology. Macromolecules 27, 1267-1273.