Kinetics of front-end acetylene hydrogenation in ethylene production

Industrial and Engineering Chemistry Research

Volumn 35, Issue 5, 1996, Pages 1496-1505

  Schbib, Noemí S ^a   García, Miguel A ^a   Gígola, Carlos E ^a   Errazu, Alberto F ^a  

^a UNS CONICET ^*  (Argentina)

Author keywords

[No Author keywords available]

Indexed keywords

ACETYLENE; ADSORPTION; ALUMINA; ATOMS; CHEMICAL REACTORS; ETHYLENE; HYDROGEN; MATHEMATICAL MODELS; PALLADIUM; REACTION KINETICS; STATISTICAL METHODS;

FRONT END ACETYLENE HYDROGENATION; INTEGRAL ADIABATIC FLOW REACTOR; KINETIC EQUATIONS; LABORATORY FLOW REACTOR; NONISOTHERMAL REACTOR MODEL;

HYDROGENATION;

EID: 0030150583     PISSN: 08885885     EISSN: None     Source Type: Journal    
DOI: 10.1021/ie950600k     Document Type: Article

References (24)

1. 3 for Ethyne Hydrogenation in a Large Excess of Ethene and Hydrogen. Appl. Catal. 1990, 58, 227.
2. All-Ammar Asad S.; Webb, G. Hydrogenation of Acetylene over Supported Metal Catalysts, Part 1. J. Chem. Soc., Faraday Trans. 1978, 74, 195.
3. Battiston, G. C.; Dallaro, L.; Tauszik, G. R. Performance and Aging of Catalysts for the Selective Hydrogenation of Acetylene: A Micro pilot-plant study. Appl. Catal. 1982, 2, 1.
4. Bos, A. N. R.; Westerterp, K. R. Mechanism and kinetics of the selective hydrogenation of ethyne and ethene. Chem. Eng. Process. 1993a, 32, 1.
5. 3 catalyst. Chem. Eng. Process. 1993b, 32, 53.
6. Carberry, J. J. Chemical and Catalytic Reaction Engineering; McGraw-Hill: New York, 1976.
7. Crider, J. E.; Foss, A. S. Effective Wall Heat Transfer Coefficients and Thermal Resistances in Mathematical Models of packed Beds. AIChE J. 1965, 11 (6), 1012.
8. Derrien, M. L. In Catalytic Hydrogenation; Cerveny, Ed.; Studies in Surface Science and Catalysis, 27; Elsevier: Amsterdam, 1986.
9. Dixon, A. G.; Cresswell, D. L. Theoretical Prediction of Effective Heat Transfer Parameters in Packed Beds. AIChE J. 1979, 25 (4), 663.
10. Doraiswamy, L. K.; Sharma, M. M. Heterogeneous Reactions: Analysis, Examples and Reactor Design; John Wiley & Sons: New York, 1984.
11. Froment, G. F.; Bischoff, K. B. Chemical Reactor Analysis and Design; Wiley & Sons, Inc.: New York, 1990.
12. Gva, L. Z.; Kho, K. E. Kinetics of acetylene hydrogenation on palladium deposited on alumina. Kinet. Catal. 1988, 29 (2), 381.
13. Lam, W. L; Lloyd, L.; Catalyst aids Selective Hydrogenation of Acetylene. Oil Gas J. 1972, March 27, 66.
14. 3 Catalysts. J. Mol. Catal. 1984, 25, 131.
15. Margitfalvi, J.; Guczi L.; Weiss, A. H. Reaction of Acetylene during Hydrogenation on Pd Black Catalyst. J. Catal. 1981, 72, 185.
16. McGown, W. T.; Kemball, C.; Whan, D. A. Hydrogenation of Acetylene in Excess of Ethylene on an Alumina-Supported Palladium Catalyst at Atmospheric Pressure in a Spinning Basket Reactor. J. Catal. 1978, 51, 173.
17. Men'shchikov, V. A.; Fal'kovich, Yu.G.; Aérov, M. E. Hydrogenation Kinetics of Acetylene on a Palladium Catalyst in the Presence of Ethylene. Kinet. Catal. 1975, 16, 1335.
18. Moses, J. M.; Weiss, A. H.; Matusek, K.; Guczi, L. The effect of Catalyst Treatment on the Selective Hydrogenation of Acetylene over Palladium/Alumina. J. Catal. 1984, 86, 417.
19. Paloschi, J. R.; Perkins, J. D. An Implementation of Quasi Newtonian Methods for Solving Sets of Nonlinear Equations. Comp. Chem. Eng. 1988, 12 (8), 767.
20. 3. Ind. Eng. Chem. Res. 1991, 30, 1693.
21. Sarkany, A., Weiss, A. H.; Guczi, L. Structure Sensitivity of Acetylene-Ethylene Hydrogenation over Pd Catalysts. J. Catal. 1986, 98, 550.
22. Schbib, N. S.; Errazu, A. F.; Romagnoli, J. A.; Porras, J. A. Dynamics and Control of an Industrial Front-End Acetylene Converter. Comput. Chem. Eng. 1994, 18, S355.
23. Schuit, G. A.; Van Reijen, L. L. The Structure and activity of metalon-silica Catalysts. Adv. Catal. 1958, 10, 242.
24. Weiss, A. H.; Le Viness, S.; Nair, V.; Guczi, L.; Sarkany, A.; Schay, A. The Effect of Pd Dispersion in Acetylene Selective Hydrogenation. Proc. Int. Congr. Catal. Dechema 1984, 8th, 591.