Preparation of sorbitol fatty acid polyesters, potential fat substitutes: Optimization of reaction conditions by response surface methodology

JAOCS, Journal of the American Oil Chemists' Society

Volumn 73, Issue 5, 1996, Pages 637-643

  Chung, Ha Yull ^a   Park, Jiyong ^b   Kim, Jung Han ^b   Kong, Un Yong ^a  

^a CJ Corporation   (South Korea)

^b Yonsei University   (South Korea)

Author keywords

Fat substitute; Optimum reaction condition; Response surface methodology; Sorbitol fatty acid polyester

Indexed keywords

ALCOHOLS; CALCULATIONS; FATTY ACIDS; MATHEMATICAL MODELS; POLYESTERS; POLYNOMIALS;

FAT SUBSTITUTE; FATTY ACID SODIUM SOAPS; MOLE RATIO; RESPONSE SURFACE METHODOLOGY; SORBITOL;

OILS AND FATS;

EID: 0030146475     PISSN: 0003021X     EISSN: None     Source Type: Journal    
DOI: 10.1007/BF02518120     Document Type: Article

References (17)

1. Toma, R.B., D.J. Curtis, and C. Sobotor, Sucrose Polyester: Its Metabolic Role and Possible Future Applications, Food Technol. 42:93-95 (1988).
2. Rizzi, G.P., and H.M. Taylor, Synthesis of Higher Polyol Fatty Acid Polyesters, U.S. Patent 3,963,699 (1976).
3. Volpenhein, R.A., Synthesis of Higher Polyol Fatty Acid Polyesters Using High Soap/Polyol Ratios, U.S. Patent 4,518,722 (1985).
4. Jandacek, R.J., and M.R. Webb, Physical Properties of Pure Sucrose Octaesters, Chem. Phys. Lipids 22:163-176 (1978).
5. Mieth, G., A. Elsner, and A. Weiss, Zur Synthase und Charakterisierung von Saccharose-Fettsaure Polyestern, 1. Mitt Uber Neues Synthese Ver Falgren, Die Nahrung 27:747-753 (1983).
6. Mattson, F.H., and R.A. Volpenhein, Hydrolysis of Fully Esterified Alcohols Containing from One to Eight Hydroxyl Groups by the Lipolytic Enzymes of Rat Pancreatic Juice, J. Lipid Res. 13:325-328 (1972).
7. Mattson, F.H., and G.A. Nolen, Rate and Extent of Absorption of the Fatty Acids of Fully Esterified Glycerol, Erythritol, Xylitol and Sucrose as Measured in Thoracic Duct Cannulated Rats, J. Nutr. 102:1177-1180 (1972).
8. Fallat, R.W., C.J. Glueck, R. Lutmer, and F.H. Mattson, Short Term Study of Sucrose Polyester, a Nonabsorbable, Fat-Like Material as a Dietary Agent for Lowering of Plasma Cholesterol, Am. J. Clin. Nutr. 29:1204-1215 (1976).
9. Akoh, C.C., and B.G. Swanson, Preparation of Trehalose and Sorbitol Fatty Acid Polyesters by Interesterification, J. Am. Oil Chem. Soc. 66:1581-1587 (1989).
10. Mattson, F.H., M. Healthy, and R.A. Volpenhein, Low Calorie Fat Containing Food Compositions, U.S. Patent 3,600,186 (1971).
11. Feuge, R.O., H.J. Zeringue, T.J. Weiss, and M. Brown, Preparation of Sucrose Esters by Interesterification, J. Am. Oil Chem. Soc. 47:56-62 (1970).
12. Weiss, T.J., M. Brown, H.J. Zeringue, and O.R. Feuge, Influence of Solvent on Degree of Acylation in the Formation of Sucrose Esters, Ibid. 49:524-529 (1972).
13. Chung, H.Y., Sorbitol Fatty Acid Polyesters as a Potential Fat Substitute, Ph.D. Dissertation, Yonsei University, Korea, 1995.
14. Official Methods and Recommended Practices of the American Oil Chemists' Society, edited by David Firestone, American Oil Chemists' Society, Champaign, 1990, Method Cd 13-16.
15. Cochran, W.G., and G.M. Cox, in Experimental Designs, 2nd edn. John Wiley & Sons, New York, 1957.
16. SAS User's Guide: Statistics, SAS Institute, Inc., Cary, NC, 1985.
17. SAS/GRAPH User's Guide, SAS Institute, Inc., Cary, NC, 1988.